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HRID1637392

反应详情

EQUATION

反应方程式

HRID 1637392 的结构方程式

REACTANTS

反应物

2
结构：O=[N+]([O-])c1cc(Cl)ccc1CO
HCID89956

4-Chloro-2-nitrobenzyl alcohol

C7H6ClNO3

结构：CS(=O)(=O)N(CCCl)N(C(=O)OCc1ccccc1[N+](=O)[O-])S(C)(=O)=O
HCID19348412

未命名化合物

PRODUCTS

生成物

1
结构：CS(=O)(=O)N(CCCl)N(C(=O)OCc1ccc(Cl)cc1[N+](=O)[O-])S(C)(=O)=O
HCID19348413

未命名化合物

PROCEDURE

实验过程

1,2-Bis(methylsulfonyl)-1-(2-chloroethyl)-2-[(4-chloro-2-nitrobenzyloxy)carbonyl]hydrazine (compound 13b) was prepared from 4-chloro-2-nitrobenzyl alcohol using a procedure similar to that described for compound 13a. The Mp was about 120-121° C., and the yield was approximately 40.0% by weight after recrystallization from ethanol. 1H NMR (acetone-d6): δ 8.2 and 7.7-8.0 (3H, s, m, aromatic H), 5.8 (2H, d, ArCH2), 3.6-4.1 (4H, m, CH2CH2Cl), 3.5 and 3.2 (6H, 2s, 2 CH3SO2).

WORKUP

后处理

  1. customThe Mp was about 120-121° C., and the yield was approximately 40.0% by weight after recrystallization from ethanol