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HRID1643412

反应详情

EQUATION

反应方程式

HRID 1643412 的结构方程式

REACTANTS

反应物

3
结构：O=[N+]([O-])O[C@@H]1CO[C@H]2[C@@H]1OC[C@H]2O
HCID182267

D-Mannitol, 1,4:3,6-dianhydro-, 2-nitrate

C6H9NO6

结构：O=C(CCC[C@@H](CO[N+](=O)[O-])O[N+](=O)[O-])O[C@@H]1CO[C@H]2[C@@H]1OC[C@H]2O
HCID58209439

未命名化合物

结构：Cl.O=[N+]([O-])OC1CCNCC1
HCID66753481

未命名化合物

PRODUCTS

生成物

1
结构：O=C(Oc1ccc([N+](=O)[O-])cc1)O[C@@H]1CO[C@H]2[C@@H]1OC[C@H]2O[N+](=O)[O-]
HCID59178160

未命名化合物

PROCEDURE

实验过程

The title compound was prepared by following the procedure for INTERMEDIATE 13 Step H, except that the reagent (S)-((3R,3aR,6R,6aR)-6-hydroxyhexahydrofuro[3,2-b]furan-3-yl)5,6bis(nitrooxy)hexanoate was replaced by (3R,3aS,6R,6aR)-6-hydroxyhexahydrofuro[3,2-b]furan-3-yl nitrate. 1H-NMR (300 MHz, CDCl3); δ 8.37-8.21 (2H, m), 7.46-7.33 (2H, m), 5.41-5.29 (1H, m), 5.20-5.05 (1H, m), 4.97-4.75 (2H, m), 4.25-3.91 (4H, m).