HRID1719754

反应详情

EQUATION

反应方程式

REACTANTS

反应物

$结构：CC1(C)[C@H](C(=O)O)[C@@H]1/C=C\C(=O)OCC(F)(F)F$

HCID13390085

未命名化合物

HCID53829177

未命名化合物

PRODUCTS

生成物

$结构：C#C[C@@H](OC(=O)[C@@H]1[C@H](/C=C\C(=O)OCC(F)(F)F)C1(C)C)c1cccc(Oc2ccccc2)c1$

HCID131714332

未命名化合物

AUXILIARIES

试剂、催化剂与溶剂

溶剂HCID6212

Chloroform

CHCl3

PROCEDURE

实验过程

Using the orocedure of Step F of Example 9, the acid of Step D of Example 1 and (R)α-ethynyl-3-phenoxy-benzyl alcohol were reacted to obtain (R)α-ethynyl-3-phenoxy-benzyl (1R,cis) 2,2-dimethyl-3[(Z) 3-oxo-3(2,2,2-trifluoroethoxy)-1-propenyl]-cyclopropane-carboxylate with a specific rotation of [α]D20 =+42°±1.5° (c=1% in CHCl3).