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HRID1770308

反应详情

EQUATION

反应方程式

HRID 1770308 的结构方程式

REACTANTS

反应物

6
结构：CC(C)(C)[Si](C)(C)Cl
HCID28928

Chloro(1,1-dimethylethyl)dimethylsilane

C6H15ClSi

结构：COC(=O)c1ccc(CO)cc1
HCID81325

Benzoic acid, 4-(hydroxymethyl)-, methyl ester

C9H10O3

结构：C=C(OC(CO[Si](C)(C)C(C)(C)C)c1ccccc1)c1cccc(CO[Si](C)(C)C(C)(C)C)c1
HCID21224724

未命名化合物

结构：[Al+3].[H-].[H-].[H-].[H-].[Li+]
HCID21226445

未命名化合物

结构：C=C(OCc1ccccc1)c1cccc(COC(C)=O)c1
HCID21253611

未命名化合物

结构：C=C(OCc1ccc(CO[Si](C)(C)C(C)(C)C)cc1)c1ccc(CO[Si](C)(C)C(C)(C)C)cc1
HCID21253626

未命名化合物

PRODUCTS

生成物

1
结构：CC(C)(C)[Si](C)(C)OCc1ccc(CO)cc1
HCID10800836

Benzenemethanol, 4-[[[(1,1-dimethylethyl)dimethylsilyl]oxy]methyl]-

C14H24O2Si

PROCEDURE

实验过程

α-[4-(tert-Butyldimethylsilyloxymethyl)-benzyloxy][4-(tert-butyldimethylsilyloxymethyl)styrene] and α-[(tert-Butyldimethylsilyloxymethyl)-benzyloxy][3-(tert-butyldimethylsilyloxymethyl)styrene]. (Formula II, R1 =tert-butyldimethylsilyloxymethylphenyl, R2 =4-tert-butyldimethylsilyloxymethylbenzyl). Methyl 4-(hydroxymethyl)benzoate was treated with tert-butyldimethylsilyl chloride using the general procedure described in Journal of the American Chemical Society, 1972, 94, 6190. The resulting product was reduced with lithium aluminium hydride to afford 4-(tert-butyldimethylsilyloxymethyl)benzyl alcohol. This alcohol was converted into the required compound using Method C. 1H NMR (CCl4) δ 0.08 (12H, s), 0.91 (18H, s), 4.22 (1H, d, J 2 Hz), 4.68 (5H, br s), 4.90 (2H, s), 7.1-7.6 (8H, m); MS (CH4) 483 (M+ -CH3, 52%), 133 100%).