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HRID1912716

反应详情

EQUATION

反应方程式

HRID 1912716 的结构方程式

REACTANTS

反应物

2
结构：C=C1C[C@@H]2[C@H](CC[C@@]3(C)[C@H]2CC24OCCOC23OCCO4)[C@@]2(C)CCCCC12
HCID67535939

未命名化合物

结构：C[C@]12CCCCC1CC(=O)[C@@H]1[C@@H]2CC[C@@]2(C)[C@H]1CC13OCCOC12OCCO3
HCID68950713

未命名化合物

PRODUCTS

生成物

1
结构：C=C1CC2CCCC[C@]2(C)[C@H]2CC[C@@]3(C)[C@@H](CC45OCCOC43OCCO5)[C@H]12
HCID86635586

未命名化合物

收率 85%

PROCEDURE

实验过程

17,17-Bis(ethylendioxy)-7-methyleneandrostane was prepared in 85% yield from 3,3:17,17-bis(ethylendioxy)androstane-7-one (Prepn. 42) by the procedure described above for the preparation of 3,3:17,17-bis(ethylendioxy)-6-methyleneandrostane (Prepn. 8). The combined organic extracts were washed with H2O, dried over Na2SO4 and evaporated to dryness. 1H-NMR (300 MHz, acetone-d6, ppm from TMS): δ 4.67 (m, 1H), 4.60 (m, 1H), 3.86 (m, 8H), 2.12-0.75 (m, 20H), 0.97 (s, 3H), 0.86 (s, 3H).

WORKUP

后处理

  1. washThe combined organic extracts were washed with H2O
  2. dry with materialdried over Na2SO4
  3. customevaporated to dryness