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HRID2118120

反应详情

EQUATION

反应方程式

HRID 2118120 的结构方程式

REACTANTS

反应物

2
结构：CC(C)(C)c1ccc(S(=O)(=O)Cl)cc1
HCID139882

4-t-Butylbenzenesulfonyl chloride

C10H13ClO2S

结构：CCOC(=O)c1c(-c2ccccc2)c2cc([N+](=O)[O-])ccc2n1C
HCID69231753

Ethyl 1-methyl-5-nitro-3-phenyl-1H-indole-2-carboxylate

C18H16N2O4

PRODUCTS

生成物

1
结构：Cn1c(C(=O)O)c(-c2ccccc2)c2cc(NS(=O)(=O)c3ccc(C(C)(C)C)cc3)ccc21
HCID11305770

未命名化合物

PROCEDURE

实验过程

The title compound was prepared from ethyl 1-methyl-5-nitro-3-phenyl-1H-indole-2-carboxylate and 4-tert-butylbenzene sulfonyl chloride followed the procedures of Example 1 Step 2 & Step 3 as a pale yellow solid: 1H NMR (DMSO-d6) δ 1.25 (s, 9H, 3.94 (s, 3H, 7.00-7.10 (m, 1H, 7.10-7.27 (m, 3H, 7.27-7.45 (m, 3H, 7.45-7.62 (m, 5H, 9.86 (s, 1H), 12.97 (br s, 1H; MS (ESI) m/z 461 [M-H]−; HRMS calcd for C26H27N2O4S: 463.1689; found (ESI+): 463.1681; Anal. calcd for C26H26N2O4S.0.15H2O: C, 67.12; H, 5.70; N, 6.02. Found: C, 67.05; H, 5.42; N, 5.88.