HRID2373414

反应详情

EQUATION

反应方程式

HRID 2373414 的结构方程式

PROCEDURE

实验过程

In a manner similar to that described for Method O, 9-chloro-2-(3-iodo-phenylamino)-5H,7H-benzo[b]pyrimido[4,5-d]azepin-6-one (I-58) and tert-butyl prop-2-ynylcarbamate was converted to {3-[3-(9-chloro-6-oxo-6,7-dihydro-5H-benzo[b]pyrimido[4,5-d]azepin-2-ylamino)-phenyl]-prop-2-ynyl}-carbamic acid tert-butyl ester, which was subsequently deprotected according to Method K to give I-67 (62%): HRMS Calcd. for C21H16ClN5O: 390.1121, Found 390.1117.

WORKUP

后处理

  1. customto give I-67 (62%)