反应详情

10 Parts of the 6,13-dihydroquinacridone obtained in Example 9 and 80 parts of methanol were charged into a 200-ml flask having a refluxer, and stirred. 12 Parts of a 50% NaOH aqueous solution was added, and the mixture was stirred at 40° C. for 30 minutes to form a salt. 26 Parts of 10% sulfuric acid was added dropwise to hydrolyze the salt, and the reaction mixture was refluxed under heat for 1 hour. 10 Parts of sodium m-nitrobenzenesulfonate was added, and immediately therafter, 3 parts of a 50%. NaOH aqeuous solution was added. Then, the mixture was refluxed for 4 hours to give 9.82 parts (98.8% of the theoretical yield) of an unsubstituted quinacridone having an excellent particle diameter as a pigment.

1. stirringthe mixture was stirred at 40° C. for 30 minutes
2. customto form a salt
3. temperaturethe reaction mixture was refluxed
4. temperatureunder heat for 1 hour
5. temperatureThen, the mixture was refluxed for 4 hours
6. customto give 9.82 parts (98.8% of the