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HRID41152

反应详情

EQUATION

反应方程式

HRID 41152 的结构方程式

REACTANTS

反应物

2
结构：COC(=O)[C@@H]1C[C@H](OC)[C@@H](O[N+](=O)[O-])C1
HCID66753156

未命名化合物

结构：COC(=O)C1CC(OC)C(O[N+](=O)[O-])C1
HCID67396922

未命名化合物

PRODUCTS

生成物

1
结构：COC1CC(C(=O)O)CC1O[N+](=O)[O-]
HCID46220317

未命名化合物

PROCEDURE

实验过程

The title compound was prepared by following step D for example 1, except that the reagent (+)-methyl (1R,3S,4S)-3-methoxy-4-(nitrooxy)cyclopentanecarboxylate was replaced by methyl (1RS,3SR,4RS)-3-methoxy-4-(nitrooxy)cyclopentanecarboxylate. 1H NMR (500 MHz, CDCl3) δ 2.17-2.30 (m, 2H), 2.32-2.43 (m, 2H), 2.90 (m, 1H), 3.39 (s, 3H), 3.89 (m, 1H), 5.30 (dd, J=6.1, 10.6 Hz, 1H).