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HRID50923

反应详情

EQUATION

反应方程式

HRID 50923 的结构方程式

REACTANTS

反应物

3
结构：O=C(Cl)/C=C/c1ccccc1
HCID5354261

trans-Cinnamoyl chloride

C9H7ClO

结构：C(=C\c1nc2ccccc2n1-c1ccccn1)/c1ccccc1
HCID9796241

未命名化合物

结构：Nc1cc([N+](=O)[O-])ccc1Nc1ccccn1
HCID12672123

未命名化合物

PRODUCTS

生成物

1
结构：O=[N+]([O-])c1ccc2c(c1)nc(/C=C/c1ccccc1)n2-c1ccccn1
HCID22736675

未命名化合物

PROCEDURE

实验过程

The titled compound was prepared from 2-(2-amino-4-nitroanilino)pyridine (Runti, C. Ann. Chim. (Rome), 1956, 46, 406) and (E)-cinnamoyl chloride according to the preparation of (E)-1-(2-pyridyl)-2-styryl-1H-benzimidazole (Example 1, method A). MW: 342.36; mp: 200.5-201.5° C.; 1H NMR (CDCl3) δ: 8.82 (1H, ddd, J=4.8, 1.8, 0.7 Hz), 8.72 (1H, d, J=2.2 Hz), 8.20 (1H, dd, J=8.8, 2.2 Hz), 8.81 (1H, d, J=16.0 Hz), 8.66 (1H, ddd, J=8.1, 7.7, 1.8 Hz), 7.58-7.47 (5H, m), 7.45-7.32 (3H, m), 7.07 d, J=16.0 Hz).