反应详情

A mixture consisting of 30.0 g (0.0474 mole) bisanthracene adduct/1,3-bis (hydroxymethyl) benzene bits (2-cyanoacrylate), 27.8 g (0.284 mole) maleic anhydride, 0.1 g hydroquinone, and 0.5 g phosphorous pentoxide in 125 ml. dry xylene is heated at 139°-141° C for 5 hours, cooled to room temperature, and suction-filled to give 26.1 g, mp 257°-259° C, of A/MA adduct. Solvent stripping of the filtrate and crystallization of the residue from benzene gives another 3.5 g, mp 258°-260° C, of A/MA adduct. The mother liquor is solvent stripped and the excess maleic anhydride sublimed off at 60°-65° C/0.1-0.2mm. The semi-crystalline residue (11.4g) is taken-up in 50 ml. hot benzene, the solution decanted from some insolubles (3.5 g, mp>300° C) and cooled to give another 1.3 g, mp 260°-262° C, of A/MA adduct. The filtrate is concentrated in vacuo to give 6.2 g (44% theory) of crude monomer as a pale orange liquid. IR and NMR analysis indicated the presence of considerable anhydride-containing and other unknown impurities.

1. additionsuction-filled
2. customto give 26.1 g, mp 257°-259° C
3. customSolvent stripping of the filtrate and crystallization of the residue from benzene
4. customgives another 3.5 g, mp 258°-260° C
5. customsublimed off at 60°-65° C
6. customhot benzene, the solution decanted from some insolubles (3.5 g, mp>300° C)
7. temperaturecooled
8. customto give another 1.3 g, mp 260°-262° C
9. concentrationThe filtrate is concentrated in vacuo
10. customto give 6.2 g (44% theory) of crude monomer as a pale orange liquid
11. additioncontaining