HRID926194

反应详情

EQUATION

反应方程式

REACTANTS

反应物

结构：CCOC(=O)C(=O)c1c(OS(=O)(=O)C(F)(F)F)c2ccccc2c2ccccc12

HCID89676702

未命名化合物

结构：CCOC(=O)[C@@H](OC(C)(C)C)c1c(C)cc2cc(Br)ccc2c1OS(=O)(=O)C(F)(F)F

HCID89681724

未命名化合物

PRODUCTS

生成物

结构：CCOC(=O)[C@@H](OC(C)(C)C)c1c(OS(=O)(=O)C(F)(F)F)c2ccccc2c2ccccc12

HCID89681786

未命名化合物

PROCEDURE

实验过程

Prepared by the similar method to make (S)-ethyl 2-(6-bromo-3-methyl-1-(trifluoromethylsulfonyloxy)naphthalen-2-yl)-2-tert-butoxyacetate in Example 20, using ethyl 2-oxo-2-(10-(trifluoromethylsulfonyloxy)phenanthren-9-yl)acetate instead of ethyl 2-(6-bromo-3-methyl-1-(trifluoromethylsulfonyloxy)naphthalen-2-yl)-2-oxoacetate. 1H-NMR: 400 MHz, (CDCl3) δ: 8.74-8.69 (m, 2H), 8.41 (d, J=4.4 Hz, 1H), 8.19 (d, J=4.2 Hz, 1H), 7.79-7.61 (m, 4H), 6.00 (s, 1H), 4.189-4.14 (m, 1H), 4.05-4.00 (m, 1H), 1.25 (s, 9H), 1.03 (t, J=7 Hz, 3H).

WORKUP

后处理

customPrepared by the similar method