硝酸铜(含2.5个结晶水)

Copper(II) nitrate hemipentahydrate

HCID 167780CAS 19004-19-4

子结构检索查找相似结构

基本信息

标准SMILES: O.O.O.O.O.O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].O=[N+]([O-])[O-].[Cu+2].[Cu+2]
InChIKey: IZDJJEMZQZQQQQ-UHFFFAOYSA-N
分子式: Cu2H10N4O17
平均分子量: 465.19 g/mol
单同位素质量: 463.86328986

名称与标识

首选名称: Copper(II) nitrate hemipentahydrate
IUPAC: dicopper;tetranitrate;pentahydrate
中文名: 硝酸铜(含2.5个结晶水)
英文名: CUPRIC NITRATE, HYDRATE
分子式: CuH3NO4
分子量: 144.57

名称与别名

19004-19-4Copper II nitrate hemipentahydrateCopper(II) nitrate hemi(pentahydrate)copper(II) nitrate hemipentahydrateCopper nitrate pentahydrateCopper nitrate hemipentahydrateDTXSID90172467Cupric nitrate hemipentahydrateRefChem:578903DTXCID4094958dicopper;tetranitrate;pentahydrateSCHEMBL67093

展开更多名称

2.5水硝酸铜三水合硝酸铜(II)硝酸铜二倍半水合物硝酸铜水合物/AR硝酸铜(II)2.5水硝酸铜容量分析用标准溶液硝酸铜(Ⅱ)半(五水合物)硝酸铜(含2.5个结晶水)铜(II)硝酸盐偏环水合物硝酸铜(II)2.5水合物COPPER (II) NITRATECupric Nitrate, ReagentCUPRIC NITRATE, HYDRATECOPPER NITRATE, HYDRATEPROTEINASE K 20MG/ML SOL.Copper (II) Nitrate, flakeCopper Nitrate 2.5-hydrateCUPRIC NITRATE, 2.5-HYDRATECOPPER (II) NITRATE, HYDRATECOPPER(II) NITRATE-2,5-HYDRATE

copper (II) nitrate hemipentahydrateCopper(II)nitrate hemi(pentahydrate)AKOS015915858dicopper(2+) pentahydrate tetranitrateNitric acid copper salt hydrate (2:5)Copper(2+) nitrate--water (2/4/5)FN145361NS00129558

数据库标识

CAS: 19004-19-4
PubChem CID: 167780
DTXSID: DTXSID90172467
EC Number: 606-197-5

性质

结构计算性质

极性表面积: 257 Å²
氢键供体: 5
氢键受体: 17
可旋转键: 0
重原子: 23
形式电荷: 0
复杂度: 18.8

实验与物化性质

Chemical ClassesMetals -> Metals, Inorganic Compounds

Melting Point115 °C

Physical DescriptionBlue odorless crystals; Hygroscopic; [Alfa Aesar MSDS]

物理化学性质

熔点: 114.5 °C · 114.5 °C (dec.)(lit.)
沸点: 170 °C · 170°C
密度: 2.32 · 2.32
闪点: 170 °C · 170°C
形态: Powder/Solid
颜色: Blue
比重: 2.05 · 2.05
水溶解性: Soluble in water, ammonia and ethanol
敏感性: Hygroscopic
Merck: 14 · 14,2643
暴露限值: 1 mg/m3NIOSH: · ACGIH: TWA 1 mg/m3NIOSH: IDLH 100 mg/m3; TWA 1 mg/m3
主要应用: electroplatingmaterial synthesis precursor
InChI: 1S/2Cu.4NO3.5H2O/c;;4*2-1(3)4;;;;;/h;;;;;;5*1H2/q2*+2;4*-1;;;;;
InChIKey: IZDJJEMZQZQQQQ-UHFFFAOYSA-N
SMILES: O.O.O.O.O.[Cu++].[Cu++].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O
CAS 数据库: 19004 · 19004-19-4(CAS DataBase Reference)

安全与法规

GHS分类

GHS Classification · 5 条

This chemical does not meet GHS hazard criteria for 5.7% (5 of 87) of reports.

Danger

H272 (93.1%): May intensify fire; oxidizer [Danger Oxidizing liquids; Oxidizing solids]

P210, P220, P264, P264+P265, P270, P273, P280, P301+P317, P302+P352, P305+P351+P338, P305+P354+P338, P317, P321, P330, P332+P317, P337+P317, P362+P364, P370+P378, P391, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 87 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危害信息

Regulatory Information · 2 条

Chemical: Nitric acid, copper(2+) salt, hydrate (2:5)

Nitric acid, copper(2+) salt, hydrate (2:5): Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 条

Acute copper poisoning after ingestion can cause liver injury, methemoglobinemia, and hemolytic anemia. Acute renal failure may result, secondary to massive hemoglobinuria. [Goldfrank, p. 1259] oxidizer that may cause fire on contact with combustible materials; Causes burns; Harmful by ingestion; [Alfa Aesar MSDS] See Copper. See NITRATES and NITRITES.

Hazard Classes and CategoriesOx. Sol. 2 (93.1%)

安全与防护

Exposure Control and Personal Protection0.01 [mg/m3], respirable fraction (Cu, inorganic cmpnds)[German Research Foundation (DFG)]

Threshold Limit Values (TLV)1.0 [mg/m3], as Cu

Permissible Exposure Limit (PEL)1.0 [mg/m3], as Cu

Protective Action Criteria (PAC) · 3 条

0.15 [mg/m3]

65 [mg/m3]

390 [mg/m3]

Immediately Dangerous to Life or Health (IDLH)100.0 [mg/m3], as Cu

毒理信息

Adverse EffectsOccupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.

安全数据

wgk: 2
tsca: Yes
RTECS号: QU7400000
包装类别: III
危险等级: 5.1
存储类别: 5.1A - Strongly oxidizing hazardous materials
安全说明: 17-26-36/37/39-45-61-60-39
海关编码: 28342990
危险品标志: O,C,N,Xn
危险性类别: Acute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Eye Dam. 1Met. Corr. 1Ox. Sol. 1Skin Corr. 1B
危险类别码: 8-22-34-50/53-41-38
危险品运输编号: UN 3085 5.1/PG 2

化学与工业

用途与制造

Household ProductsInformation on 1 consumer products that contain Copper II nitrate hemipentahydrate in the following categories is provided:

应用领域

用途催化2,6-二甲基苯酚的氧化偶合，生成可用作重要工程材料的聚合物。

试剂价格

A14004 · 250g: 三水合硝酸铜(II), 98% Copper(II) nitrate hemi(pentahydrate), 98% — 545元
012523 · 50g: 2.5水合硝酸铜(II), ACS, 98.0-102.0%Copper(II) nitrate hemi(pentahydrate), ACS, 98.0-102.0%, Thermo Scientific Chemicals — 276元