棉籽油

Methane

HCID 178721367CAS 8001-29-4

基本信息

标准SMILES
C
InChIKey
VNWKTOKETHGBQD-UHFFFAOYSA-N
分子式
CH4
平均分子量
16.043 g/mol

概述

Methane is a colorless odorless gas. It is also known as marsh gas or methyl hydride. It is easily ignited. The vapors are lighter than air. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket. It is used in making other chemicals and as a constituent of the fuel, natural gas.

名称与标识

首选名称
Methane
IUPAC
methane
中文名
棉籽油
英文名
COTTONSEED OIL
分子式
CH4
分子量
16.04246

名称与别名

methaneMarsh gasMethyl hydrideFire DampBiogas74-82-8R 50 (refrigerant)metanotetrahydridocarbonHSDB 167Methane in gaseus stateUN1972
展开更多名称
棉花棉籽油棉花油棉子油棉花籽油酸精制棉籽油精致棉籽油棉籽油。未氢化棉籽油 2.5LT棉籽油 USP标准品cottonLIPEX 109cottonoilnci-c50168cottondoilCOTTONSEED OILOils, cottonseedCOTTONSEEDOIL,NFBaumwollsamenoelcottonseedoilacid
BRN 1718732OP0UW79H66UN1971CH4DTXSID8025545UNII-OP0UW79H66CHEBI:16183R 50

数据库标识

CAS
8001-29-4
ChEMBL
CHEMBL17564
ChEBI
CHEBI:16183
UNII
OP0UW79H66
EC Number
200-812-7、927-905-1
Nikkaji
J2.228.533E、J2.380I、J3.470.363I、J593B、J68.119I

性质

结构计算性质

XLogP
0.6
极性表面积
0 Ų
氢键供体
0
氢键受体
0
可旋转键
0
重原子
1

实验与物化性质

Chemical Classes · 2 条

Toxic Gases & Vapors -> Simple Asphyxiants

Flammable agents - 4th degree

SpringerMaterials PropertiesDunham energy parameter
LogP · 3 条

log Kow = 1.09

1.09

1.09

Odor · 2 条

Odorless

Weak odor

TasteTasteless
Density · 4 条

0.415 to 0.45 at -259.6 °F (USCG, 1999)

0.422 at -256 °F (USCG, 1999) - Less dense than water; will float

0.554 at 0 °C/4 °C (air = 1 ) or 0.7168 g/liter

0.4228 @ -162°C

物理化学性质

密度
0.91 · 0.91
折射率
20 · n20/D 1.471
闪点
113 °C · 113 °C
储存条件
2 · 2-8°C
溶解度
Slightly soluble in ethanol (95%); miscible with carbon disulfide, chloroform, ether, hexane, and petroleum ether.
形态
Oil

化学性质

暗红褐色油。有轻微坚果香味。21-27℃时液体,21℃时发生浑浊,低于10~16℃下贮藏可有部分固化。23~27℃时应无有关的杂质。

安全与法规

GHS分类

GHS Classification · 6 条

Danger

H220: Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P280, P377, P381, and P403 (click each P-code to see the statement)

Danger

H220 (100%): Extremely flammable gas [Danger Flammable gases]

P203, P210, P222, P280, P282, P336+P317, P377, P381, P403, and P410+P403 (click each P-code to see the statement)

危害信息

Regulatory Information · 5 条

Chemical: Methane

Methane is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Methane are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 23-03-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/14250

Methane or natural gas but excluding refrigerated liquid methane or natural gas: HSNO Approval: HSR001005 Approved with controls

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Other Safety InformationIMAP assessments - Methane: Human health tier I assessment
DOT Label · 4 条

Flammable Gas

Flammable Gas

Flammable Gas

Flammable Gas

Fire Hazards · 6 条

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Special Hazards of Combustion Products: None (USCG, 1999)

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· EXTREMELY FLAMMABLE.

· EXTREMELY FLAMMABLE.

Fire Potential · 2 条

Very dangerous fire and explosion hazard when exposed to heat or flame.

Flammable in the presence of an oxidizing gas (eg air), a source of ignition, and when the concentration of the gas is between the lower and upper explosive limits. Keep away from heat/sparks/open flame/hotsurface/oxidizing gas. No smoking.

Health Hazards · 6 条

If concentration of gas is high enough, may cause asphyxiation. No detectable systemic effects, even at 5% concentration in air. (USCG, 1999)

High concentrations may cause asphyxiation. No systemic effects, even at 5% concentration in air. (USCG, 1999)

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

· Vapors may cause dizziness or asphyxiation without warning, especially when in closed or confined areas.

安全与防护

Fire Fighting · 5 条

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Shut off supply; if not possible and no risk to surroundings, let the fire burn itself out. In other cases extinguish with water spray, powder, carbon dioxide. In case of fire: keep cylinder cool by spraying with water. Combat fire from a sheltered position.

First Aid Measures · 3 条

Fresh air, rest. Artificial respiration may be needed. Refer for medical attention.

ON FROSTBITE: rinse with plenty of water, do NOT remove clothes. Refer for medical attention .

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Accidental Release Measures · 4 条

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.

First Aid · 6 条

Remove victim to open air. If he is overcome by gas, apply artificial resuscitation. (USCG, 1999)

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

Excerpt from ERG Guide 115 [Gases - Flammable (Including Refrigerated Liquids)]:

General First Aid:

General First Aid:

Safe StorageFireproof. Cool. Ventilation along the floor and ceiling.
Exposure Control and Personal Protection · 2 条

· Wear positive pressure self-contained breathing apparatus (SCBA).

· Wear positive pressure self-contained breathing apparatus (SCBA).

毒理信息

TreatmentAsphyxiation should be treated by moving the affected person to an uncontaminated area, then giving artificial respiration and administering oxygen, if necessary. (L173)
Health EffectsMethane is an asphyxiant and displaces oxygen in enclosed spaces. At high enough concentrations, oxygen depletion may cause asphyxiation, resulting in generalized hypoxia and possibly death. (L171, L172)
Environmental Fate · 3 条

TERRESTRIAL FATE: Based on a classification scheme(1), an estimated Koc value of 9(SRC), determined from a log Kow of 1.09(2) and a regression-derived equation(3), indicates that methane is expected to have very high mobility in soil(SRC). Volatilization of methane from moist soil surfaces is expected to be an important fate process(SRC) given an estimated Henry's Law constant of 0.66 atm-cu m/mole(SRC), derived from its vapor pressure, 4.66X10+5 mm Hg(4), and water solubility, 22 mg/L(5). Methane is expected to volatilize from dry soil surfaces(SRC) based upon its vapor pressure(4). An average utilization of 55% for methane by anaerobic soil microorganisms(6) suggests that biodegradation may be an environmental fate process in soil(SRC).

AQUATIC FATE: Based on a classification scheme(1), an estimated Koc value of 9(SRC), determined from a log Kow of 1.09(2) and a regression-derived equation(3), indicates that methane is not expected to adsorb to suspended solids and sediment(SRC). Volatilization from water surfaces is expected(4) based upon an estimated Henry's Law constant of 0.66 atm-cu m/mole(SRC), derived from its vapor pressure, 4.66X10+5 mm Hg(5), and water solubility, 22 mg/L(6). Using this Henry's Law constant and an estimation method(4), volatilization half-lives for a model river and model lake are 2 hours(SRC). According to a classification scheme(7), an estimated BCF of 2(SRC), from its log Kow(2) and a regression-derived equation(3), suggests the potential for bioconcentration in aquatic organisms is low(SRC). The biodegradation half-life of methane was estimated to range from 70 days to infinity in model anaerobic estuarine ecosystems(8), indicating that biodegradation is not an important environmental fate process in water(SRC).

ATMOSPHERIC FATE: According to a model of gas/particle partitioning of semivolatile organic compounds in the atmosphere(1), methane, which has a vapor pressure of 4.66X10+5 mm Hg at 25 °C(2), is expected to exist solely as a gas in the ambient atmosphere. Gas-phase methane is degraded in the atmosphere by reaction with photochemically-produced hydroxyl radicals(SRC); the half-life for this reaction in air is estimated to be 4 yrs(3), calculated from its rate constant of 6.85X10-15 cu cm/molecule-sec at 25 °C(4). Methane does not contain chromophores that absorb at wavelengths >290 nm(5) and, therefore, is not expected to be susceptible to direct photolysis by sunlight(SRC).

Adverse EffectsOther Poison - Simple Asphyxiant
Exposure Routes · 2 条

The substance can be absorbed into the body by inhalation.

Inhalation (L172)

Toxicity Summary · 1 条

Methane is an asphyxiant and displaces oxygen in enclosed spaces. At high enough concentrations, oxygen depletion may cause asphyxiation. Low concentrations of surrounding oxygen results in deficient oxygen to the organs, compounded by increased oxygen exhalation during respiration. This results in generalized hypoxia and possibly death. (L171, A120)

法规信息

DHS Chemicals of Interest (COI) · 4 条

Methane

1

10000

Flammable chemical that can be released at a facility.

安全数据

F
8
wgk
-
tsca
TSCA listed
RTECS号
GN2815000
存储类别
11 - Combustible Solids
安全说明
24/25

毒性防护

急性毒性口服- 大鼠 LD50: > 8000 毫克/ 公斤

包装储运 · 3 条

可燃性危险特性可燃, 火场排出辛辣刺激烟雾

储运特性库房低温, 通风, 干燥 ; 防火; 与氧化剂分开存放

灭火剂水, 二氧化碳, 干粉, 砂土

化学与工业

药理信息

Metabolism/Metabolites · 3 条

Methane is absorbed through the lungs in mammals. when inhaled, the majority of the absorbed dose is exhaled unchanged. A small amount of methane is converted to methanol and ultimately to carbon dioxide. Uptake in humans is less rapid than in the rat.

Small amt of methane undergoes metabolism to methanol and ultimately to carbon dioxide.

Methane is biologically inactive. (L172)

Absorption, Distribution and Excretion · 2 条

The pharmacokinetics of methane ... would probably be similar to that reported for ethane.

Methane has been demonstrated to be absorbed through the lungs in mammals.

Tissue LocationsAdipose Tissue
Cellular LocationsCytoplasm

用途与制造

Uses · 6 条

In the USA 85% of natural gas is methane. [Merck Index] Produced by decaying matter in swamps and marshes; [Hawley]

Mining [Category: Industry]

Smoking cigarettes [Category: Food & Drugs]

In the production of methanol

Constituent of illuminating and cooking gas; in manufacture of hydrogen, hydrogen cyanide, ammonia, acetylene, formaldehyde, in organic syntheses.

Chemical intermediate (excluding fuel use); constituent of natural gas (about 85% methane); ... halogenated methanes, carbon disulfide, sodium hydrosulfide, carbon black

ImpuritiesMethanol and carbon monoxide
U.S. Exports · 3 条

(1972) 7.8X10+10 CU FT (NATURAL GAS)

(1975) 7.0X10+10 CU FT (NATURAL GAS)

(1984) 1.70X10+11 g /NATURAL GAS, METHANE AND MIXTURES THERE OF INCLUDING SYNTHETIC NATURAL GAS/

U.S. Imports · 4 条

(1972) 1.02X10+12 CU FT (NATURAL GAS)

(1975) 9.7X10+11 CU FT (NATURAL GAS)

(1984) 3.80X10+11 g /NATURAL GAS, METHANE AND MIXTURES THEREOF INCLUDING SYNTHETIC NATURAL GAS/

(1986) 7.26X10+8 mcf /Natural gas, methane and mixtures thereof including synthetic natural gas/

U.S. Production · 6 条

2023: 4,000,000,000 - <5,500,000,000 lb

(1972) 2.25X10+13 CU FT (NATURAL GAS)

(1975) 2.01X10+13 CU FT (NATURAL GAS)

(1982) 509.1 MILLION BARRELS

Methane is listed as a High Production Volume (HPV) chemical (65FR81686). Chemicals listed as HPV were produced in or imported into the U.S. in >1 million pounds in 1990 and/or 1994. The HPV list is based on the 1990 Inventory Update Rule. (IUR) (40 CFR part 710 subpart B; 51FR21438).

For more U.S. Production (Complete) data for METHANE (7 total), please visit the HSDB record page.

Consumer UsesFuel
应用领域 · 3 条

简介棉籽油(cottonseed oil)是一种从棉花属植物种子提炼的食用油,主要来源为陆地棉和草棉,其植种用途在取得棉纤维、作动物饲料、以及榨油[1]。 棉籽与其他油籽(如葵花子)有类似的结构,由硬壳包覆着含油内核(种子)。棉籽油使用在沙拉油、沙拉酱、美乃滋[2]、或洋芋片等零食,因为它味道安定,不会掩盖原味,遇热不易起油烟。

应用棉籽油含有丰富的饱和脂肪酸,可用作煎炸油、起酥油、人造奶油,也可作为生产硬脂酸、软脂酸、甘油、丙二酸的工业原料。棉籽油不含反式脂肪酸,在目前含反式脂肪酸的氢化植物油被欧美等国限制使用的情况下,棉籽油成为一种天然的替代品。 棉籽油对一些疾病具有很好的预防作用,比如:对高血压、高血脂等疾病具有很好的预防作用,能够抑制胆固醇的上升。棉籽油在工业上一般用于生产肥皂、甘油、油墨、润滑油及农药溶剂。近年来,人们对环境保护日益重视,棉籽油作为可再生的油料作物之一,也被用于制备生物柴油;还可以用作皮革加脂剂的原料油脂,也可代替大豆油生产环氧化物,国外更多用作食用油脂。

用途涂层剂;乳化剂;成型剂;组织改进剂。

制备方法

生产方法由棉花作物(Gossypium hirsut“m:G.barbadense)的种子用机械压榨法或溶剂萃取法提取后,经精制、脱色、脱臭、以除去游离脂肪酸、磷脂、色素、臭味物质和其他非油脂类物质而成。

试剂价格

17711 · 500ml
棉籽油 2.5LTCottonseed oil, pure, Thermo Scientific Chemicals — 473元
HY-Y1887 · 100 mL
棉籽油Cottonseed oil — 165元

供应商50 家

国药集团化学试剂有限公司86-21-63210123 · [email protected]
湖北永阔科技有限公司027-59223108 15972152991 · [email protected]
湖南韵邦生物科技股份有限公司85561037 15386497078 · [email protected]
湖北万得化工有限公司15377098680 15377098680 · [email protected]
西安清言生物科技有限责任公司15339027915

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