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Cosmetic ingredients (Ammonium Sulfite) -> CIR (Cosmetic Ingredient Review)

Preservative

greater than 1.1 at 68 °F (USCG, 1999)

1.41 @25 °C

Ammonium sulfite is a colorless crystalline solid. The primary hazard is the threat to the environment. Immediate steps should be taken to limit its spread to the environment. It is used in the manufacture of other chemicals, in medicine, and photography.

Large Crystals; Dry Powder; Liquid

White odorless solid; [HSDB] White odorless crystalline solid; [MSDSonline]

Acrid, sulfurous taste; hygroscopic; sublimes @ 150 °C with decomposition; specific gravity 1.41. /ammonium sulfate monohydrate/

HEAT OF SOLN: 20.5 BTU/LB= 11.4 CAL/G= 0.477X10+5 J/KG

SLIGHTLY SOL IN ALC; INSOL IN ACETONE; SOL IN WATER, 32.4 G/100 CC @ 0 °C, 60.4 G/100 CC @ 100 °C; COLORLESS MONOCLINIC CRYSTALS; MP: 60-70 °C WITH DECOMP; INDEX OF REFRACTION: 1.515. /AMMONIUM SULFATE MONOHYDRATE/

At 230-245 °C, ammonium sulfite decomposes.

Monohydrate, efflorescent crystals

This chemical does not meet GHS hazard criteria for 71.1% (133 of 187) of all reports.

Danger

H314 (13.4%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]

P260, P261, P264, P264+P265, P271, P280, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P319, P321, P332+P317, P337+P317, P362+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 187 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

Chemical: Sulfurous acid, diammonium salt

Sulfurous acid, ammonium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Sulfurous acid, ammonium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 14-06-2016 https://echa.europa.eu/registration-dossier/-/registered-dossier/12645

Ammonium sulfite: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.

The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.)

Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 5000 lb or 2270 kg. The toll free number of the NRC is (800) 424-8802; In the Washington D.C. metropolitan area (202) 426-2675. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b).

Ammonium sulfite is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply to discharges of this substance. This designation includes any isomers and hydrates, as well as any solutions and mixtures containing this substance.

Skin Corr. 1B (13.4%)

Acute toxicity - category 4

... SHOULD BE STORED IN A COOL, DRY PLACE, AS IN PRESENCE OF MOISTURE THERE IS CAKING & SLOW RELEASE OF SULFUR DIOXIDE. THESE SALTS, IF DRY, CAN BE HANDLED IN IRON OR STEEL EQUIPMENT. SOLN CAN BE HANDLED IN TYPE 316 & 347 SS, LEAD, RUBBER OR WOOD. /SULFITE SALTS/

KEEP TIGHTLY CLOSED & IN COOL PLACE. /AMMONIUM SULFATE MONOHYDRATE/

DURING TRANSPORT: STORAGE TEMP: AMBIENT; VENTING: OPEN; HAZARD ASSESSMENT CODE: SS.

SRP: At the time of review, criteria for land treatment or burial (sanitary landfill) disposal practices are subject to significant revision. Prior to implementing land disposal of waste residue (including waste sludge), consult with environmental regulatory agencies for guidance on acceptable disposal practices.

SRP: The scientific literature for the use of contact lenses in industry is conflicting. The benefit or detrimental effects of wearing contact lenses depend not only upon the substance, but also on factors including the form of the substance, characteristics and duration of the exposure, the uses of other eye protection equipment, and the hygiene of the lenses. However, there may be individual substances whose irritating or corrosive properties are such that the wearing of contact lenses would be harmful to the eye. In those specific cases, contact lenses should not be worn. In any event, the usual eye protection equipment should be worn even when contact lenses are in place.

30 [mg/m3]

330 [mg/m3]

2000 [mg/m3]

Dust mask; goggles or face shield; rubber gloves (USCG, 1999)

/NIOSH CERTIFIED RESPIRATOR/; GOGGLES OR FACE SHIELD; RUBBER GLOVES.

TLm Gambusia affinis (mosquito fish) 240 ppm/48 hr fresh water. /Conditions of bioassay not specified/

TLm Daphnia magna (water flea) 299 mg/l/25 hr. /Conditions of bioassay not specified/

TLm Daphnia magna (water flea) 273 mg/l/50 hr. /Conditions of bioassay not specified/

TLm Daphnia magna (water flea) 203 mg/l/100 hr. /Conditions of bioassay not specified/

... If swallowed they may cause irritation of the stomach by liberating sulfurous acid. /Sulfites/

INHALATION OF DUST CAUSES IRRITATION OF NOSE AND THROAT. INGESTION CAUSES IRRITATION OF MOUTH AND STOMACH. DUST IRRITATES EYES.

WHEN INGESTED, SOLUTIONS CAUSE GASTRIC IRRITATION BY LIBERATION OF SULFUROUS ACID. BECAUSE OF RAPID OXIDATION TO SULFATE ... SULFITES ARE WELL TOLERATED UNTIL LARGE DOSES ARE REACHED; THEN VIOLENT COLIC & DIARRHEA, CIRCULATORY DISTURBANCES, CENTRAL NERVOUS DEPRESSION, & DEATH ARE DESCRIBED. /SULFITE SALTS/

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for signs of pulmonary edema and treat if necessary ... . Monitor for shock and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 mg/kg up to 200 ml of water for dilution if the patent can swallow, has a strong gag reflex, and does not drool ... . Do not attempt to neutralize. /Ammonia and related compounds/

Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control if signs of upper airway obstruction are present or if the patient is unconscious or has severe pulmonary edema. Positive-pressure ventilation techniques with a bag-valve-mask device may be beneficial. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start an IV with D5W /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors if patient is hypotensive with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Ammonium and related compounds/

Basic treatment: Establish a patent airway. Suction if necessary. Watch for signs of respiratory insufficiency and assist ventilations if necessary. Administer oxygen by nonrebreather mask at 10 to 15 L/min. Monitor for pulmonary edema and treat if necessary ... . Anticipate seizures and treat if necessary ... . For eye contamination, flush eyes immediately with water. Irrigate each eye continuously with normal saline during transport ... . Do not use emetics. For ingestion, rinse mouth and administer 5 m1/kg up to 200 ml of water for dilution if the patient can swallow, has a strong gag reflex, and does not drool ... . Administer activated charcoal ... . Cover skin burns with dry sterile dressings after decontamination ... . /Sulfur and related compounds/

Advanced treatment: Consider orotracheal or nasotracheal intubation for airway control in the patient who is unconscious. Early intubation at the first sign of upper airway obstruction may be necessary. Monitor cardiac rhythm and treat arrhythmias if necessary ... . Start an IV with D5W /SRP: "To keep open", minimal flow rate/. Use lactated Ringer's if signs of hypovolemia are present. Watch for signs of fluid overload. Consider drug therapy for pulmonary edema ... . Treat seizures with diazepam (Valium) ... . For hypotension with signs of hypovolemia, administer fluid cautiously. Consider vasopressors for hypotension with a normal fluid volume. Watch for signs of fluid overload ... . Use proparacaine hydrochloride to assist eye irrigation ... . /Sulfur and related compounds/

Persons in charge of vessels or facilities are required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in an amount equal to or greater than its reportable quantity of 5000 lb or 2270 kg. The toll free number of the NRC is (800) 424-8802; In the Washington D.C. metropolitan area (202) 426-2675. The rule for determining when notification is required is stated in 40 CFR 302.4 (section IV. D.3.b).

Ammonium sulfite is designated as a hazardous substance under section 311(b)(2)(A) of the Federal Water Pollution Control Act and further regulated by the Clean Water Act Amendments of 1977 and 1978. These regulations apply to discharges of this substance. This designation includes any isomers and hydrates, as well as any solutions and mixtures containing this substance.

CIR ingredient: Ammonium Sulfite

Used in photography and in the production of caramel, refractory bricks, lubricants, medicines, permanent wave solutions, ammonium thiosulfite, and ammonium chloride; [HSDB]

Photographic Processing [Category: Other]

IN PRODN OF CARAMEL.

In photography; as reducing agent; in bricks for blast furnace linings; in lubricants for metal cold-working.

... Medicine, permanent wave solns. /Ammonium sulfite monohydrate/

Oil and Gas Drilling, Extraction, and Support activities

Sulfurous acid, ammonium salt (1:2): ACTIVE

COMBUSTION GASES WERE WASHED WITH AQ AMMONIACAL SOLN, INCL AMMONIUM SULFITE, TO REMOVE SO(X).

REMOVAL OF NITROGEN OXIDES FROM WASTE GASES BY SCRUBBING WITH AQ SOLN CONTAINING IRON SALTS & AMMONIUM SULFITE.