2-二环己膦基-2'-(N,N-二甲胺)-联苯

2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl

HCID 2734217CAS 213697-53-1

子结构检索查找相似结构

基本信息

标准SMILES: CN(C)c1ccccc1-c1ccccc1P(C1CCCCC1)C1CCCCC1
InChIKey: ZEMZPXWZVTUONV-UHFFFAOYSA-N
分子式: C26H36NP
平均分子量: 393.5 g/mol
单同位素质量: 393.25853678

名称与标识

首选名称: 2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl
IUPAC: 2-(2-dicyclohexylphosphanylphenyl)-N,N-dimethylaniline
中文名: 2-二环己膦基-2'-(N,N-二甲胺)-联苯
英文名: 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl
分子式: C26H36NP
分子量: 393.54

名称与别名

2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl2'-(dicyclohexylphosphino)-N,N-dimethyl[1,1'-biphenyl]-2-amine2'-(Dicyclohexylphosphino)-N,N-dimethyl(1,1'-biphenyl)-2-amineRefChem:460558606-749-5213697-53-12-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenylDavePhos2'-(DICYCLOHEXYLPHOSPHINO)-N,N-DIMETHYL-[1,1'-BIPHENYL]-2-AMINEMFCD021835722-dicyclohexylphosphino-2'-(dimethylamino)biphenyl2-(2-dicyclohexylphosphanylphenyl)-N,N-dimethylaniline

展开更多名称

化合物 DavePhos-(N,N-二甲胺)-联苯2-二环己膦基-2'1,2-双(二苯基膦)乙烷氯化镍(Ⅱ)2-(二环己膦基)-2'-(二甲胺)联苯2-(双环己基膦)-2'-(二甲基胺)联苯2-二环己基膦-2'-(N,N-二甲胺)-联2-二环己基磷-2-(N,N-二甲基氨基)联苯2-二环己基膦-2'-(N,N-二甲胺)-联苯2-二环己膦基-2'-(N,N-二甲胺)-联苯N-[2'-(dicyclohexylphosphino)-1,1'-biphenyl-2-yl]-N,N-diMethylaMine2-(N,N-Dimethylamino)-2-(dicyclohexylphosphino)biphenylDavePhos 2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenylDavep2-(Dicycloh98% DavePhos

C26H36NP2'-(dicyclohexylphosphanyl)-N,N-dimethyl-[1,1'-biphenyl]-2-amine2'-(dicyclohexylphosphino)-n,n-dimethylbiphenyl-2-amineUNII-9877ONU78FDavephos phosphine ligand [MI]DTXSID203701719877ONU78F2-(2-dicyclohexylphosphanylphenyl)-N,N-dimethyl-aniline

数据库标识

CAS: 213697-53-1
PubChem CID: 2734217
DTXSID: DTXSID20370171
UNII: 9877ONU78F
EC Number: 606-749-5
Nikkaji: J1.009.873D、J3.446.379D

性质

结构计算性质

XLogP: 6.9
极性表面积: 3.2 Å²
氢键供体: 0
氢键受体: 1
可旋转键: 5
重原子: 28
形式电荷: 0
复杂度: 433

物理化学性质

熔点: 121 · 121-124 °C(lit.)
沸点: 539.6 · 539.6±43.0 °C(Predicted)
储存条件: Keep in dark place,Sealed in dry,Room Temperature
形态: crystal
酸度系数(pKa): 5.04 · 5.04±0.18(Predicted)
颜色: white
水溶解性: Insoluble
敏感性: Air Sensitive
InChI: InChI=1S/C26H36NP/c1-27(2)25-19-11-9-17-23(25)24-18-10-12-20-26(24)28(21-13-5-3-6-14-21)22-15-7-4-8-16-22/h9-12,17-22H,3-8,13-16H2,1-2H3
InChIKey: ZEMZPXWZVTUONV-UHFFFAOYSA-N
SMILES: C1(C2=CC=CC=C2P(C2CCCCC2)C2CCCCC2)=CC=CC=C1N(C)C
CAS 数据库: 213697 · 213697-53-1(CAS DataBase Reference)

安全与法规

GHS分类

GHS Classification · 4 条

Warning

H315 (98.9%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 87 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

危害信息

Hazard Classes and CategoriesSkin Irrit. 2 (98.9%)

安全数据

wgk: 3
tsca: No
危险等级: AIR SENSITIVE
存储类别: 11 - Combustible Solids
安全说明: 26-36/37/39
海关编码: 29310099
危险品标志: Xi,Xn
危险类别码: 36/37/38-22

化学与工业

应用领域 · 3 条

用途作为配体，用于Suzuki, Buchwald等偶联反应以及取代反应中

用途与过渡金属的络合物用作C-C/C-N/C-O偶合反应等有机合成的催化剂；用于钯催化Suzuki芳基偶联制备benzodioxepine的配体；用于钯催化C-N成键反应以及包含羟基、酰胺或者烯醇化酮类的芳基卤化物胺化反应中的有效配体

用途用于钯催化 C-N 键形成的有效配体；含羟基、酰胺或烯醇酮的芳基卤的胺化反应。钯催化 Suzuki 芳基-芳基偶联反应的配体，生成苯并二噁庚英。

试剂价格

D3389 · 1G: 2-(二环己膦基)-2'-(N,N-二甲胺)联苯2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl — 540元
D3389 · 5G: 2-(二环己膦基)-2'-(N,N-二甲胺)联苯2-(Dicyclohexylphosphino)-2'-(dimethylamino)biphenyl — 1990元

供应商50 家

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

衢州润东化工有限公司0570-8789886 18892685668 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

INTATRADE GmbH+49 3493/605464 · [email protected]

关联笔记

加载中…