氟硅酸镁

Magnesium hexafluorosilicate

HCID 61861CAS 16949-65-8

基本信息

标准SMILES
F[Si-2](F)(F)(F)(F)F.[Mg+2]
InChIKey
INWUJAAIUAAHJA-UHFFFAOYSA-N
分子式
F6Si.Mg
平均分子量
166.38 g/mol
单同位素质量
165.95238755

概述

Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

名称与标识

首选名称
Magnesium hexafluorosilicate
IUPAC
magnesium hexafluorosilicon(2-)
中文名
氟硅酸镁
英文名
Magnesium fluosilicate
分子式
F6MgSi
分子量
166.38

名称与别名

Magnesium hexafluorosilicateMagnesium fluorosilicateCaswell No. 532Fluosilicate de magnesiumHexafluorosilicate(2-) magnesium (1:1)Silicate(2-), hexafluoro-, magnesium (1:1)EPA Pesticide Chemical Code 075304Fluosilicate de magnesium [French]EINECS 241-022-2UN2853UNII-H37V80D2JSMagnesium hexafluorosilicate(2)
展开更多名称
氟硅酸镁六氟硅酸镁氟硅酸镁/AR氟硅酸镁 六水合物六氟硅酸(2-)镁六氟硅酸镁,氟硅酸镁氟硅酸镁(固定混凝土颜色)六氟硅酸(2-)镁(1:1)Magnesium fluorosiliMAGNESIUM FLUOSILICATEMAGNESIUM SILICOFLUORIDEMagnesiumhexafluorsilikatMAGNESIUMHEXAFLUOSILICATEfluosilicicacidmagnesiumsaltMAGNESIUM SILICOFLUORIDE 98%
FLUOROSILICATO DE MAGNESIODTXSID70884950hexafluorosilicate, magnesium saltMAGNESIUM HEXAFLUOROSILICATE [MI]MAGNESIUM SILICOFLUORIDE, (SOLID)EC 241-022-2MAGNESIUM SILICOFLUORIDE, [SOLID]RefChem:155211

数据库标识

CAS
16949-65-8、18972-56-0
PubChem CID
61861
DTXSID
DTXSID70884950
UNII
H37V80D2JS
EC Number
241-022-2、606-187-0

性质

结构计算性质

极性表面积
0 Ų
氢键供体
0
氢键受体
7
可旋转键
0
重原子
8

实验与物化性质

Chemical ClassesMineral Dusts -> Other Mineral Dusts
CosmeticsAntiplaque; Oral care
Physical Description · 3 条

Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.

Dry Powder

Solid; [CAMEO] White powder; [Gelest MSDS]

物理化学性质

熔点
120 °C · 120°C
沸点
120 °C · >120°C
密度
1.788 · 1.788
蒸气压
0.001 Pa · 0.001Pa at 25℃
形态
Powder
比重
1.788 · 1.788

化学性质

无色或白色菱形或针状结晶。无气味。易溶于水,溶于稀酸,难溶于氢氟酸,不溶于醇。

安全与法规

GHS分类

GHS Classification · 6 条

Danger

H301: Toxic if swallowed [Danger Acute toxicity, oral]

P264, P270, P301+P316, P321, P330, P405, and P501 (click each P-code to see the statement)

Danger

H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]

P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P354+P338, P317, P321, P330, P405, and P501 (click each P-code to see the statement)

危害信息

Regulatory Information · 5 条

Chemical: Silicate(2-), hexafluoro-, magnesium (1:1)

Silicate(2-), hexafluoro-, magnesium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicate(2-), hexafluoro-, magnesium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Magnesium hexafluorosilicate (EC: 241-022-2)

Magnesium hexafluorosilicate: Does not have an individual approval but may be used under an appropriate group standard

Magnesium fluorosilicate: Does not have an individual approval but may be used under an appropriate group standard

Other Safety InformationIMAP assessments - Magnesium hexafluorosilicates: Human health tier II assessment
DOT LabelPoison
Fire Hazards · 2 条

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.

Health Hazards · 2 条

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.

Hazards Summary · 1 条

Toxic by ingestion; May cause serious eye injury [Classifications by the EC] Not a skin irritant in rabbits (80% aqueous solution); Hematological and clinical chemistry changes, adverse dental effects, mineralization in bone tissue, interstitial nephritis, hyperkeratosis of the stomach, increased relative liver and kidney weights, and increased relative testes and adrenal weights in males observed in 4-week oral study of rats at 3,000 ppm dietary (approximately 300 mg/kg/day); [IUCLID] An eye irritant; Corrosive to mucous membranes; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause osteofluorosis; [Gelest MSDS] See Magnesium. See Fluorosilicic acid. See Calcium hexafluorosilicate.

安全与防护

Fire FightingExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Accidental Release Measures · 2 条

· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.

· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.

First Aid · 2 条

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

General First Aid:

Exposure Control and Personal Protection · 3 条

· Wear positive pressure self-contained breathing apparatus (SCBA).

Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)

1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]

Nonfire Spill ResponseExcerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Isolation and Evacuation · 2 条

Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:

Immediate precautionary measure

毒理信息

Adverse EffectsDermatotoxin - Skin burns.
Toxicity DataLC50 (rat) = 3,600 mg/m3/4hr

安全数据

tsca
TSCA listed
毒性
LD in guinea pigs (mg/kg): 200 orally, 400 s.c. (Waldbott)
包装类别
III
危险等级
6.1
安全说明
24/25-45
危险品标志
T

化学与工业

用途与制造

Uses · 2 条

Used for mothproofing textiles; [Merck Index] Used to make other chemicals; [CAMEO]

Textiles (Printing, Dyeing, or Finishing) [Category: Industry]

U.S. Production2023: 88,184 lb
Consumer UsesBinder
Industry UsesBinder
Use ClassificationCosmetics -> Antiplaque; Oral care
General Manufacturing Information · 2 条

Non-metallic Mineral Product Manufacturing (includes clay, glass, cement, concrete, lime, gypsum, and other non-metallic mineral product manufacturing)

Silicate(2-), hexafluoro-, magnesium (1:1): ACTIVE

应用领域 · 3 条

概述氟硅酸镁主要用作改善混凝土硬度和强度的硬化剂和防水剂。也用于硅石建筑物表面的氟风化处理,也可用作杀虫剂。商品级氟硅酸镁产品中的MgSiF6·6H2O含量一般大于98%。

用途用做防水剂、防蛀剂、混凝土加固、制陶瓷等。

用途用作混凝土的硬化剂和防水剂,用于硅石建筑物表面处理及制造陶瓷

制备方法 · 1 条

生产方法常见氟硅酸镁合成主要是利用磷肥生成过程中产生的过磷酸钙副产氟硅酸、苦土粉为原料制备氟硅酸镁化合物、利用中和法以及碳酸镁与氟硅酸反应等方法制备。下面详述磷肥法及中和法。 1.磷肥副产法 改法分为原料预处理、中和、浓缩、结晶以及干燥等流程。其中需要注意的是原料预处理过程必须完成杂质的祛除工作,否则会对后续工艺的稳定性造成很大影响。具体生产流程图见下图: 2.中和法 目前国内大都采用采用中和法生产氟硅酸镁,即用磷肥企业湿法磷酸副产的氟硅酸与氧化镁反应生成氟硅酸镁溶液,过滤,清液蒸发浓缩至65%左右,经结晶、离心分离、干燥后得晶体状的氟硅酸镁产品。具体图解见下图:

试剂价格

XW1694965801 · 500g
氟硅酸镁 — 80元
81009260 · 500g
氟硅酸镁,六水Magnesium fluosilicate — 185元

供应商50 家

北京华美互利生物化工010-56205725 · [email protected]
江西益众化工有限公司15307925109 15350027073 · [email protected]
山东旭晨化工科技有限公司0533-15715337262 15715337262 · [email protected]
上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
武汉欣扬瑞和化学科技有限公司13720274133 · [email protected]

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