基本信息
- 标准SMILES
F[Si-2](F)(F)(F)(F)F.[Mg+2]- InChIKey
INWUJAAIUAAHJA-UHFFFAOYSA-N- 分子式
- F6Si.Mg
- 平均分子量
- 166.38 g/mol
- 单同位素质量
- 165.95238755
概述
Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.
名称与标识
- 首选名称
- Magnesium hexafluorosilicate
- IUPAC
- magnesium hexafluorosilicon(2-)
- 中文名
- 氟硅酸镁
- 英文名
- Magnesium fluosilicate
- 分子式
- F6MgSi
- 分子量
- 166.38
名称与别名
展开更多名称
数据库标识
- CAS
16949-65-8、18972-56-0- PubChem CID
- 61861
- DTXSID
DTXSID70884950- UNII
- H37V80D2JS
- EC Number
- 241-022-2、606-187-0
性质
结构计算性质
- 极性表面积
- 0 Ų
- 氢键供体
- 0
- 氢键受体
- 7
- 可旋转键
- 0
- 重原子
- 8
- 形式电荷
- 0
- 复杂度
- 62.7
实验与物化性质
Physical Description
Magnesium fluorosilicate is a crystalline solid. Decomposes at 120 °C. Contact may cause slight irritation to skin, eyes, and mucous membranes. May be slightly toxic by ingestion. Used to make other chemicals.
Dry Powder
Solid; [CAMEO] White powder; [Gelest MSDS]
物理化学性质
- 熔点
- 120 °C · 120°C
- 沸点
- 120 °C · >120°C
- 密度
- 1.788 · 1.788
- 蒸气压
- 0.001 Pa · 0.001Pa at 25℃
- 形态
- Powder
- 比重
- 1.788 · 1.788
- 水溶解性
- 498.4 g/L · 498.4g/L at 18.3℃
- 水解敏感性
- 2 · 2: reacts with aqueous acid
- 化妆品成分功效
- ANTIPLAQUEORAL CARE
- InChI
- InChI=1S/F6Si.Mg.6H2O/c1-7(2,3,4,5)6;;;;;;;/h;;6*1H2/q-2;+2;;;;;;
- InChIKey
- ZYDDCPHMRLLEEV-UHFFFAOYSA-N
- SMILES
- [Si-2](F)(F)(F)(F)(F)F.O.O.O.O.O.O.[Mg+2]
- LogP
- 0 at · 0 at 25℃
- CAS 数据库
- 16949 · 16949-65-8(CAS DataBase Reference)
- EPA化学物质信息
- Magnesium fluosilicate (16949-65-8)
化学性质
无色或白色菱形或针状结晶。无气味。易溶于水,溶于稀酸,难溶于氢氟酸,不溶于醇。
安全与法规
GHS分类
GHS Classification
Danger
H301: Toxic if swallowed [Danger Acute toxicity, oral]
P264, P270, P301+P316, P321, P330, P405, and P501 (click each P-code to see the statement)
Danger
H301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]
P261, P264, P264+P265, P270, P271, P280, P301+P316, P304+P340, P305+P354+P338, P317, P321, P330, P405, and P501 (click each P-code to see the statement)
危害信息
Regulatory Information
Chemical: Silicate(2-), hexafluoro-, magnesium (1:1)
Silicate(2-), hexafluoro-, magnesium (1:1) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silicate(2-), hexafluoro-, magnesium (1:1) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
REACH registered substance: Magnesium hexafluorosilicate (EC: 241-022-2)
Magnesium hexafluorosilicate: Does not have an individual approval but may be used under an appropriate group standard
Magnesium fluorosilicate: Does not have an individual approval but may be used under an appropriate group standard
Fire Hazards
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Health Hazards
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
· Highly toxic, may be fatal if inhaled, ingested or absorbed through skin.
Hazards Summary
Toxic by ingestion; May cause serious eye injury [Classifications by the EC] Not a skin irritant in rabbits (80% aqueous solution); Hematological and clinical chemistry changes, adverse dental effects, mineralization in bone tissue, interstitial nephritis, hyperkeratosis of the stomach, increased relative liver and kidney weights, and increased relative testes and adrenal weights in males observed in 4-week oral study of rats at 3,000 ppm dietary (approximately 300 mg/kg/day); [IUCLID] An eye irritant; Corrosive to mucous membranes; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; May cause osteofluorosis; [Gelest MSDS] See Magnesium. See Fluorosilicic acid. See Calcium hexafluorosilicate.
Reactivity Profile
MAGNESIUM FLUOROSILICATE gives basic aqueous solutions. Reacts with acids. Does not usually react as either oxidizing agents or reducing agents. It can react slowly with water to generate hydrofluoric acid, which can cause severe chemical burns and is one of the few materials that can etch glass.
DOT Hazard Classification
Magnesium fluorosilicate
UN2853
Div 6.1 Poisonous materials (49 eCFR § 173.132)
PG III: the degree of danger presented by the material is minor
Hazard Classes and Categories
Acute Tox. 3 (100%)
Acute toxicity (ingestion) - category 3
Acute toxicity (Oral) - Category 3
Acute toxicity (Oral) - Category 3
Acute Tox. 3 *
安全与防护
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.
First Aid
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
General First Aid:
Exposure Control and Personal Protection
· Wear positive pressure self-contained breathing apparatus (SCBA).
Biological Exposure Indices (BEI) [ACGIH] - Fluorides in urine = 2 mg/L prior to shift or 3 mg/L at end of shift; (Repeated measurements recommended.)
1.0 [mg/m3], inhalable fraction, as F[German Research Foundation (DFG)]
Isolation and Evacuation
Excerpt from ERG Guide 151 [Substances - Toxic (Non-Combustible)]:
Immediate precautionary measure
毒理信息
安全数据
- tsca
- TSCA listed
- 毒性
- LD in guinea pigs (mg/kg): 200 orally, 400 s.c. (Waldbott)
- 包装类别
- III
- 危险等级
- 6.1
- 安全说明
- 24/25-45
- 危险品标志
- T
- 危险类别码
- 25
- 危险品运输编号
- UN 2853
化学与工业
用途与制造
Uses
Used for mothproofing textiles; [Merck Index] Used to make other chemicals; [CAMEO]
Textiles (Printing, Dyeing, or Finishing) [Category: Industry]
General Manufacturing Information
Non-metallic Mineral Product Manufacturing (includes clay, glass, cement, concrete, lime, gypsum, and other non-metallic mineral product manufacturing)
Silicate(2-), hexafluoro-, magnesium (1:1): ACTIVE
应用领域
概述氟硅酸镁主要用作改善混凝土硬度和强度的硬化剂和防水剂。也用于硅石建筑物表面的氟风化处理,也可用作杀虫剂。商品级氟硅酸镁产品中的MgSiF6·6H2O含量一般大于98%。
用途用做防水剂、防蛀剂、混凝土加固、制陶瓷等。
用途用作混凝土的硬化剂和防水剂,用于硅石建筑物表面处理及制造陶瓷
制备方法
生产方法常见氟硅酸镁合成主要是利用磷肥生成过程中产生的过磷酸钙副产氟硅酸、苦土粉为原料制备氟硅酸镁化合物、利用中和法以及碳酸镁与氟硅酸反应等方法制备。下面详述磷肥法及中和法。 1.磷肥副产法 改法分为原料预处理、中和、浓缩、结晶以及干燥等流程。其中需要注意的是原料预处理过程必须完成杂质的祛除工作,否则会对后续工艺的稳定性造成很大影响。具体生产流程图见下图: 2.中和法 目前国内大都采用采用中和法生产氟硅酸镁,即用磷肥企业湿法磷酸副产的氟硅酸与氧化镁反应生成氟硅酸镁溶液,过滤,清液蒸发浓缩至65%左右,经结晶、离心分离、干燥后得晶体状的氟硅酸镁产品。具体图解见下图:
上下游产品信息
上游原料
试剂价格
- XW1694965801 · 500g
- 氟硅酸镁 — 80元
- 81009260 · 500g
- 氟硅酸镁,六水Magnesium fluosilicate — 185元
供应商50 家
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