基本信息
- 标准SMILES
Cl.Cl.Cl.O=[N+]([O-])O- InChIKey
NICDRCVJGXLKSF-UHFFFAOYSA-N- 分子式
- Cl3H4NO3
- 平均分子量
- 172.39 g/mol
- 单同位素质量
- 170.92567603
概述
Aqua regia appears as a yellow liquid with a pungent odor prepared by mixing nitric acid and hydrochloric acid, usually in a ratio of one part of nitric acid to three or four parts of hydrochloric acid. Fumes are irritating to the eyes and mucous membranes. Corrosive to metals and to tissue.
名称与标识
- 首选名称
- Aqua regia
- IUPAC
- nitric acid;trihydrochloride
- 中文名
- 硝基盐酸
- 英文名
- Nitrohydrochloric acid
- 分子式
- ClHNO2
- 分子量
- 82.46644
名称与别名
展开更多名称
数据库标识
- CAS
8007-56-5- PubChem CID
- 90477010
- DTXSID
DTXSID50893666- UNII
- X3TT5X989E
- EC Number
- 690-364-2
性质
结构计算性质
- 极性表面积
- 66.1 Ų
- 氢键供体
- 4
- 氢键受体
- 3
- 可旋转键
- 0
- 重原子
- 7
- 形式电荷
- 0
- 复杂度
- 24.8
实验与物化性质
Chemical Classes
Toxic Gases & Vapors -> Acids, Inorganic
Corrosives
Physical Description
Aqua regia appears as a yellow liquid with a pungent odor prepared by mixing nitric acid and hydrochloric acid, usually in a ratio of one part of nitric acid to three or four parts of hydrochloric acid. Fumes are irritating to the eyes and mucous membranes. Corrosive to metals and to tissue.
Yellow fuming liquid with a suffocating odor; [Merck Index] Red, yellow, or gold fuming liquid; [University of Oxford MSDS]
物理化学性质
- 稳定性
- Pressure will develop in sealed bottles. Incompatible with (and may react violently with) a wide variety of materials, including metals, oxidising agents, reducing agents, combustible materials.
- CAS 数据库
- 8007 · 8007-56-5
- EPA化学物质信息
- Aqua regia (8007-56-5)
安全与法规
GHS分类
GHS Classification
This chemical does not meet GHS hazard criteria for 100% (3 of 3) of all reports.
Not Classified
Aggregated GHS information provided per 3 reports by companies from 1 notifications to the ECHA C&L Inventory.
危害信息
Fire Hazards
Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
· Non-combustible, substance itself does not burn but may decompose upon heating to produce corrosive and/or toxic fumes.
Health Hazards
Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.
· TOXIC and/or CORROSIVE; inhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death.
Hazards Summary
Contains nitrosyl chloride and free chlorine; Corrosive; [Merck Index] A strong oxidizing agent with known catalytic activity; Reacts with air; Causes burns; [CAMEO] Causes burns and severe respiratory tract irritation; Highly toxic by ingestion and inhalation; [University of Oxford MSDS] See Nitric acid and Hydrogen chloride.
DOT ID and Guide
1798 157
1798 157
Reactivity Profile
AQUA REGIA is a powerful oxidizing agent and a strong acid. Reacts exothermically with chemical bases (for example: amines and inorganic hydroxides) to form salts and water. Reacts with most metals, including gold and platinum, to dissolve them with generation of toxic and/or flammable gases. Can initiate polymerization in polymerizable organic compounds. Reacts with cyanide salts to generate toxic hydrogen cyanide gas. Generates flammable and/or toxic gases with dithiocarbamates, isocyanates, mercaptans, nitrides, nitriles, sulfides, and weak or strong reducing agents. Additional exothermic gas-generating reactions occur with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), and carbonates (CO2).
DOT Hazard Classification
Nitrohydrochloric acid
UN1798
Class 8 Corrosive material (49 eCFR § 173.136)
PG I: the degree of danger presented by the material is great
Hazard Classes and Categories
Not Classified
Corrosives
安全与防护
Accidental Release Measures
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
· CALL 911. Then call emergency response telephone number on shipping paper. If shipping paper not available or no answer, refer to appropriate telephone number listed on the inside back cover.
· ELIMINATE all ignition sources (no smoking, flares, sparks or flames) from immediate area.
First Aid
Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
General First Aid:
General First Aid:
Exposure Control and Personal Protection
· Wear positive pressure self-contained breathing apparatus (SCBA).
· Wear positive pressure self-contained breathing apparatus (SCBA).
Isolation and Evacuation
Excerpt from ERG Guide 157 [Substances - Toxic and/or Corrosive (Non-Combustible / Water-Sensitive)]:
Immediate precautionary measure
Immediate precautionary measure
Protective Action Criteria (PAC)
1.8 [ppm]
22 [ppm]
100 [ppm]
Emergency Response Planning Guidelines
· Note: Some foams will react with the material and release corrosive/toxic gases.
· Note: Some foams will react with the material and release corrosive/toxic gases.
毒理信息
安全数据
- 包装类别
- I
- 危险等级
- 8
- 危险品运输编号
- UN 1798
包装储运
可燃性危险特性遇金属放出可燃氢气
储运特性库房通风低温干燥; 与有机物、还原物、易燃物分开存放
化学与工业
用途与制造
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