基本信息
- 标准SMILES
CC(=O)C(N=Nc1ccc(-c2ccc(N=NC(C(C)=O)C(=O)Nc3ccccc3C)c(Cl)c2)cc1Cl)C(=O)Nc1ccccc1C- InChIKey
LQZFGPJGXVFSTR-UHFFFAOYSA-N- 分子式
- C34H30Cl2N6O4
- 平均分子量
- 657.5 g/mol
- 单同位素质量
- 656.1705588
名称与标识
- 首选名称
- C.I. Pigment Yellow 14
- IUPAC
- 2-[[2-chloro-4-[3-chloro-4-[[1-(2-methylanilino)-1,3-dioxobutan-2-yl]diazenyl]phenyl]phenyl]diazenyl]-N-(2-methylphenyl)-3-oxobutanamide
- 中文名
- 颜料黄 14
- 英文名
- Pigment Yellow 14
- 分子式
- C34H30Cl2N6O4
- 分子量
- 657.55
名称与别名
展开更多名称
数据库标识
- CAS
5468-75-7- PubChem CID
- 93006
- DTXSID
DTXSID9027601- UNII
- 586X0864EC
- EC Number
- 226-789-3
- Nikkaji
- J35.636K
性质
结构计算性质
- XLogP
- 8.8
- 极性表面积
- 142 Ų
- 氢键供体
- 2
- 氢键受体
- 8
- 可旋转键
- 11
- 重原子
- 46
- 形式电荷
- 0
- 复杂度
- 1,050
实验与物化性质
Physical Description
Dry Powder; Wet Solid; CBI; Dry Powder; Wet Solid; Liquid; Wet Solid; Other Solid; Dry Powder; Liquid; Liquid; Dry Powder; Other Solid
Solid; [EPA ChAMP: Hazard Characterization: C.I. Pigment Yellow 14 - 2010] Yellow odorless powder; [BASF MSDS]
物理化学性质
- 沸点
- 793.4 · 793.4±60.0 °C(Predicted)
- 密度
- 1.4203 · 1.4203 (rough estimate)
- 折射率
- 1.735 · 1.7350 (estimate)
- 酸度系数(pKa)
- 0.99 · 0.99±0.59(Predicted)
- 形态
- Solid:nanomaterial
- 色指数
- 21095 · 21095
- 颜色
- Yellow to orange
- 稳定性
- Light Sensitive
- LogP
- 0.5 at · 0.5 at 24℃ and pH7
- CAS 数据库
- 5468 · 5468-75-7(CAS DataBase Reference)
- EPA化学物质信息
- 14 · C.I. Pigment Yellow 14 (5468-75-7)
化学性质
红光黄色粉末,色光鲜艳。熔点336℃,密度1.35~1.64g/cm3。着色力强,透明度好,各项应用性能均较好,是联苯胺类重要品种之一。
安全与法规
GHS分类
GHS Classification
This chemical does not meet GHS hazard criteria for 96.8% (489 of 505) of all reports.
Not Classified;Reported as not meeting GHS hazard criteria by 489 of 505 companies (only 3.2% companies provided GHS information). For more detailed information, please visit ECHA C&L website.
Aggregated GHS information provided per 505 reports by companies from 5 notifications to the ECHA C&L Inventory.;Reported as not meeting GHS hazard criteria per 489 of 505 reports by companies.;There are 3 notifications provided by 16 of 505 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
危害信息
Regulatory Information
Chemical: Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2-methylphenyl)-3-oxo-
Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(2,1-diazenediyl)]bis[N-(2-methylphenyl)-3-oxo- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(2,1-diazenediyl)]bis[N-(2-methylphenyl)-3-oxo- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 21-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15898
Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2-methylphenyl)-3-oxo-: Does not have an individual approval but may be used under an appropriate group standard
Other Safety Information
IMAP assessments - Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2-methylphenyl)-3-oxo-: Environment tier I assessment;IMAP assessments - Selected benzidine-congener-based pigments: Human health tier II assessment
Hazards Summary
Not irritating to skin or eyes in rabbits; [IUCLID] Supporting chemicals demonstrate mild irritation or irritation to rabbit skin and eyes; No evidence of skin sensitization in guinea pigs; No systemic toxicity in repeated-dose inhalation and oral studies of rats (doses up to 410 mg/m3 and 2,500 mg/kg/day); No systemic, reproductive, or developmental toxicity in a combined study of rats at doses up to 1,000 mg/kg/day; No evidence of carcinogenicity in rats or mice; [EPA ChAMP: Hazard Characterization: C.I. Pigment Yellow 14 - 2010] Not expected to cause irritation or other adverse health effects if handled properly; [BASF MSDS] See Benzidine.
安全与防护
Protective Action Criteria (PAC)
15 [mg/m3]
170 [mg/m3]
990 [mg/m3]
法规信息
Regulatory Information
Chemical: Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2-methylphenyl)-3-oxo-
Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(2,1-diazenediyl)]bis[N-(2-methylphenyl)-3-oxo- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(2,1-diazenediyl)]bis[N-(2-methylphenyl)-3-oxo- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Status: Active Update: 21-02-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/15898
Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(azo)]bis[N-(2-methylphenyl)-3-oxo-: Does not have an individual approval but may be used under an appropriate group standard
安全数据
- tsca
- TSCA listed
- RTECS号
- EJ3512500
- 安全说明
- 26-36/37/39
- 危险类别码
- 36/37/38
化学与工业
用途与制造
Uses
Used in the paints-lacquers-varnishes and polymers industries; Used as a coloring agent; [IUCLID] Used to make adhesives, wood products, other plastic products, paints and coatings, other agricultural chemicals, printing inks, synthetic dyes, and pigments; Used in photofinishing, printing, adhesives, sealants, non-pesticidal agricultural products, glass and ceramic products, rubber and plastics products, paints and coatings, paper products, photographic supplies, and wood and wood furniture; [EPA ChAMP: Hazard Characterization: C.I. Pigment Yellow 14 - 2010]
Pulp and Paper Processing [Category: Industry];Painting (Pigments, Binders, and Biocides) [Category: Paint];Working with Glues and Adhesives [Category: Other];Photographic Processing [Category: Other];Textiles (Printing, Dyeing, or Finishing) [Category: Industry];Glass Manufacturing [Category: Industry]
Substance listed with specific concentration in tattoo ink and/or permanent make up according to EU Commission Regulation 2020/2081. The concentration limit (by weight) is 0.1%.
Plastics -> Typical concentration range in plastic materials -> 2%
Use Classification
Plastics -> Pigments agents
Plastics -> Polymer Type -> PUR; PVC (soft); PVC (rigid)
General Manufacturing Information
Printing Ink Manufacturing;Textiles, apparel, and leather manufacturing;All Other Chemical Product and Preparation Manufacturing;Paint and Coating Manufacturing;Synthetic Dye and Pigment Manufacturing;Plastics Material and Resin Manufacturing;Plastics Product Manufacturing;Custom Compounding of Purchased Resins;Printing and Related Support Activities
Butanamide, 2,2'-[(3,3'-dichloro[1,1'-biphenyl]-4,4'-diyl)bis(2,1-diazenediyl)]bis[N-(2-methylphenyl)-3-oxo-: ACTIVE
应用领域
简介颜料黄14是一种绿光黄色粉末,色光鲜艳,着色力强,透明度好,各项应用性能均较好,是联苯胺类有机颜料的重要品种之一。它比颜料黄12稍绿光,比起欧洲规定的颜色标准要偏绿光;着色力比C.I.颜料黄13低,耐光牢度1-2级;耐溶剂性、耐石蜡较好,尤其在美国大量用于包装印墨。
应用颜料黄 14主要用于橡胶、塑料、橡胶制品的着色,也适用于聚氨酯合成革、 高档油墨及涂料、印花色浆的着色。
用途主要用于橡胶及塑料的着色,也适用于聚氨酯合成革、高档油墨及涂料等。
用途主要用于塑料和橡胶制品的着色,也适用于聚氨酯合成革、高档油墨和涂料的着色
用途主要用于印花色浆的着色
上下游产品信息
上游原料
试剂价格
- HY-D0281 · 25 mg
- 颜料黄 14Pigment Yellow 14 — 300元
- HY-D0281 · 50 mg
- 颜料黄 14Pigment Yellow 14 — 500元
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