2-庚酮 → 2-庚酮

HRID 1155207

反应方程式

HRID 1155207 反应方程式
[CH3:1][C:2](=[O:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]>C1(C)C=CC=CC=1>[CH3:1][CH:2]([OH:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7].[CH3:1][C:2](=[O:8])[CH2:3][CH2:4][CH2:5][CH2:6][CH3:7]

参与物

4

反应物 1

HCID 80512-庚酮

产物 2

HCID 80512-庚酮HCID 109762-庚醇

试剂、催化剂与溶剂 1

HCID 1140甲苯溶剂3 次

实验过程

Operating under the conditions of Example 1, 1 millimol of 2-heptanone in toluene (1 ml of a 1M soln.) is reacted with 0.375 millimol of Ca[AlH2 (OCH2CH2OCH3)2 ]2 in toluene (1.78 ml of a 0.21M soln.) during 30 mins. at room temperature. After treating the reaction mixture according to the procedure of Example 1, the resultant toluene solution is gaschromatographically analyzed. The yield of 2-heptanol, the result of the reduction of 2-heptanone, is quantitative.

后处理

  1. customat room temperature
  2. additionAfter treating the reaction mixture

来源与证据

ORD记录
ord-5c29ef634ca14ab7a590912e3ad00693
来源数据集
uspto-grants-1981_11
专利号
US04299986

关联笔记

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