正丙醇 → n-Propyl ferulate

HRID 1415660

反应方程式

HRID 1415660 反应方程式
[C:1]([OH:14])(=[O:13])/[CH:2]=[CH:3]/[C:4]1[CH:12]=[CH:11][C:9]([OH:10])=[C:6]([O:7][CH3:8])[CH:5]=1.[CH2:15](O)[CH2:16][CH3:17]>C1C=CC=CC=1>[C:1]([O:14][CH2:15][CH2:16][CH3:17])(=[O:13])/[CH:2]=[CH:3]/[C:4]1[CH:12]=[CH:11][C:9]([OH:10])=[C:6]([O:7][CH3:8])[CH:5]=1

参与物

4

反应物 2

HCID 1031正丙醇HCID 445858阿魏酸

产物 1

HCID 9881169n-Propyl ferulate收率 64.3%

试剂、催化剂与溶剂 1

HCID 241苯溶剂

反应条件

温度
78 °C

实验过程

In a three-necked flask, 19.4 g (0.1 mole) of ferulic acid, 6.01 g (0.1 mole) of n-propyl alcohol, and 1.0 g of paratoluenesulfonic acid were placed, and 200 ml of benzene was added. This reaction mixture was stirred at 78° C. for 15 hours. Thereafter, the same procedures were taken as in Example 1 to obtain 15.2 g (yield: 64%) of n-propyl ferulate.

来源与证据

ORD记录
ord-15ba7c8842c246b2ba780fbfe5aa43cf
来源数据集
uspto-grants-1999_06
专利号
US05908615

关联笔记

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