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氧 → Carboxyphenylstearic acid
参与物
| 角色 | 名称 | HCID | 投料 |
|---|---|---|---|
| 反应物 | 氧 | HCID 977 | — |
| 反应物 | 2-丁酮 | HCID 6569 | — |
| 反应物 | 正丁烷 | HCID 7843 | — |
| 反应物 | 2-(2-Methylphenyl)octadecanoic acid | HCID 22323937 | — |
| 催化剂 | 水合醋酸钴 | HCID 6277 | — |
| 产物 | Carboxyphenylstearic acid | HCID 70555697 | 47.9% |
反应步骤
The oxidation procedure of Example I was repeated except that only 40 gms cobalt (II) acetate was employed. Also, for this reaction 40 gms methylethyl ketone and 72 gms butane were charged to the reactor. Eighty percent conversion of the tolylstearic acid was achieved after only four hours reaction (105° C. and 350 psig O2). Carboxyphenylstearic acid was obtained in 47.9% yield.
来源与证据
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| 专利号 | US04356315 |
| 来源数据集 | uspto-grants-1982_10 |
| ORD ID | ord-0445cac1340449bb900981407bee45ad |
| 来源说明 | uspto-grants-1982_10 |