聚[6-[4-(4-氰基苯基)苯氧基]己基甲基丙烯酸酯] → Phenacyltetrahydrothiophenium bromide

HRID 225403

反应方程式

HRID 225403 反应方程式
[CH2:1]([Br:10])[C:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[O:3].[S:11]1[CH2:15][CH2:14][CH2:13][CH2:12]1.O.C(OCC)C>[N+](C)([O-])=O>[Br-:10].[CH2:1]([S+:11]1[CH2:15][CH2:14][CH2:13][CH2:12]1)[C:2]([C:4]1[CH:9]=[CH:8][CH:7]=[CH:6][CH:5]=1)=[O:3]

参与物

6

反应物 4

HCID 962聚[6-[4-(4-氰基苯基)苯氧基]己基甲基丙烯酸酯]HCID 1127四氢噻吩HCID 3283乙醚HCID 62592-溴苯乙酮

产物 1

HCID 11346720Phenacyltetrahydrothiophenium bromide

试剂、催化剂与溶剂 1

HCID 6375硝基甲烷溶剂

实验过程

88.2 g (0.44 mole) of phenacyl bromide and 39.1 g (0.44 mole) of tetrahydrothiophene were dissolved in 220 g of nitromethane, which was stirred for 4 hours at room temperature. 800 g of water and 400 g of diethyl ether were added to the reaction solution whereupon the mixture separated into two layers. The aqueous layer was taken out, which was an aqueous solution of the target compound, phenacyltetrahydrothiophenium bromide.

后处理

  1. customseparated into two layers

来源与证据

ORD记录
ord-e340a01c97f3477caf8d844c91753b25
来源数据集
uspto-grants-2009_07
专利号
US07556909B2

关联笔记

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