聚[6-[4-(4-氰基苯基)苯氧基]己基甲基丙烯酸酯] → 1-Amino-p-methoxyphenylmethanephosphonous acid

HRID 25983

反应方程式

HRID 25983 反应方程式
[CH3:1][O:2][C:3]1[CH:4]=[CH:5][C:6]([CH:9]=O)=[CH:7][CH:8]=1.[PH2:11]([O-:13])=[O:12].[NH4+:14].O>C1(C)C(C)=CC=CC=1>[NH2:14][C:6]1([CH2:9][P:11]([OH:13])[OH:12])[CH:5]=[CH:4][C:3]([O:2][CH3:1])=[CH:8][CH2:7]1

参与物

5

反应物 3

HCID 962聚[6-[4-(4-氰基苯基)苯氧基]己基甲基丙烯酸酯]HCID 31244大茴香醛HCID 178418291HCID 178418291，化合物

产物 1

HCID 867364411-Amino-p-methoxyphenylmethanephosphonous acid

试剂、催化剂与溶剂 1

HCID 7237邻二甲苯溶剂2 次

实验过程

A mixture of 13.6 parts anisaldehyde and 8.3 parts ammonium hypophosphite in 100 parts xylene was refluxed with water separation. The xylene was cooled, decanted and the residue boiled with ethanol to give a white solid. Filtration gave DL-1-amino-p-methoxyphenylmethanephosphonous acid, melting point 239°-241° (dec.).

后处理

  1. customdecanted
  2. customto give a white solid
  3. filtrationFiltration

来源与证据

ORD记录
ord-24e4c99b0b07489a91a8b31e14f959c8
来源数据集
uspto-grants-1979_04
专利号
US04147780

关联笔记

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