N,N-二甲基甲酰胺 → 卡波姆树脂

HRID 326951

反应方程式

HRID 326951 反应方程式
Br[CH2:2]CCCCCCCCCCC[O:14]C1C=C[C:18]([C:19]([O:21]C2C=CC(OC(C)CC)=CC=2)=[O:20])=[CH:17]C=1.[CH3:35][N:36]([CH:38]=O)[CH3:37]>>[C:19]([OH:21])(=[O:20])[CH:18]=[CH2:17].[OH-:14].[CH3:35][N+:36]([CH3:38])([CH3:2])[CH3:37]

参与物

4

反应物 2

HCID 6228N,N-二甲基甲酰胺HCID 197340594-(1-Methylpropoxy)phenyl 4-(12-bromododecyloxy)benzoate

产物 2

HCID 6581卡波姆树脂HCID 60966四甲基氢氧化铵

实验过程

A solution of 6 mmol (3.2 g) of the bromo compound obtained in (2), 10 mmol (0.72 g) of acrylic acid, and 10 mmol (1.8 g) of tetramethylammonium hydroxide (pentahydrate) in 30 ml of DMF was stirred for 10 hours at room temperature. To the resulting reaction solution was added water and then extracted with ether. The extract was concentrated, and the concentrate was purified by column chromatography to obtain 2.2 g of the objective monomer (3b). (Yield: 71%)

来源与证据

ORD记录
ord-b7348a1330274d1c8b19a7da8498f468
来源数据集
uspto-grants-1993_12
专利号
US05271866

关联笔记

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