丙酮 → DL-甘油醛

HRID 394954

反应方程式

HRID 394954 反应方程式
CC([OH:4])C.CC(C)=[O:7].[OH:9][CH2:10][CH:11]([CH2:13][OH:14])[OH:12]>>[O:9]=[CH:10][CH:11]([CH2:13][OH:14])[OH:12].[OH:4][CH:13]([OH:14])[C:11](=[O:12])[CH3:10].[C:10]([OH:7])(=[O:9])[CH:11]([CH2:13][OH:14])[OH:12]

参与物

6

反应物 3

HCID 180丙酮HCID 753甘油HCID 3776异丙醇

产物 3

HCID 751DL-甘油醛HCID 752甘油酸HCID 131809821,1-Dihydroxypropan-2-one

实验过程

The above-described catalyst may be used for liquid phase oxidation reactions. Examples of such reactions include the oxidation of alcohols and polyols to form aldehydes, ketones, and acids (e.g., the oxidation of 2-propanol to form acetone, and the oxidation of glycerol to form glyceraldehyde, dihydroxyacetone, or glyceric acid); the oxidation of aldehydes to form acids (e.g., the oxidation of formaldehyde to form formic acid, and the oxidation of furfural to form 2-furan carboxylic acid); the oxidation of tertiary amines to form secondary amines (e.g., the oxidation of nitrilotriacetic acid (“NTA”) to form iminodiacetic acid (“IDA”)); the oxidation of secondary amines to form primary amines (e.g., the oxidation of IDA to form glycine); and the oxidation of various acids (e.g., formic acid or acetic acid) to form carbon dioxide and water.

来源与证据

ORD记录
ord-f4415be6f0cf45738154f30ab9032874
来源数据集
uspto-grants-2003_08
专利号
US06603039B1

关联笔记

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