Calcium chloride, dihydrate → Calcium bicyclo(2.2.1)heptane-2,3-dicarboxylate

HRID 411763

反应方程式

HRID 411763 反应方程式
[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[CH:3]([C:8]([O-:10])=[O:9])[CH:2]2[C:11]([O-:13])=[O:12].[Na+].[Na+].O.O.[Cl-].[Ca+2:19].[Cl-]>O>[CH:1]12[CH2:7][CH:4]([CH2:5][CH2:6]1)[CH:3]([C:8]([O-:10])=[O:9])[CH:2]2[C:11]([O-:13])=[O:12].[Ca+2:19]

参与物

4

反应物 2

HCID 6093260Calcium chloride, dihydrateHCID 21981355bicyclo2.2.1heptane-2,3-dicarboxylic acid, disodium salt

产物 1

HCID 21981350Calcium bicyclo(2.2.1)heptane-2,3-dicarboxylate

试剂、催化剂与溶剂 1

HCID 962聚[6-[4-(4-氰基苯基)苯氧基]己基甲基丙烯酸酯]溶剂2 次

反应条件

温度
60 °C

实验过程

To a solution of disodium bicyclo[2.2.1]heptane-2,3-dicarboxylate (22.6 g, 0.1 mol) in water (150 g) was added a solution of calcium chloride dihydrate (14.7 g, 0.1 mol) in water (100 g). The mixture stirred at 60° C. for 2 hours. The resulting white precipitate was filtered. The white powdery product was dried and milled (m.p. >300° C.).

后处理

  1. filtrationThe resulting white precipitate was filtered
  2. customThe white powdery product was dried
  3. custommilled (m.p. >300° C.)

来源与证据

ORD记录
ord-45a11144c85a4e5e82113832017c3fbd
来源数据集
uspto-grants-2003_05
专利号
US06559211B2

关联笔记

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