海萝胶 → 9,9'-联蒽

HRID 47175

反应方程式

HRID 47175 反应方程式
Cl.[CH:2]1[C:15]2[C:14](=O)[C:13]3[C:8](=[CH:9][CH:10]=[CH:11][CH:12]=3)[CH2:7][C:6]=2[CH:5]=[CH:4][CH:3]=1>[Zn].C(O)(=O)C>[CH:2]1[C:15]2[C:6](=[CH:7][C:8]3[C:13]([C:14]=2[C:7]2[C:8]4[C:13]([CH:14]=[C:15]5[C:6]=2[CH:5]=[CH:4][CH:3]=[CH:2]5)=[CH:12][CH:11]=[CH:10][CH:9]=4)=[CH:12][CH:11]=[CH:10][CH:9]=3)[CH:5]=[CH:4][CH:3]=1

参与物

5

反应物 2

HCID 313海萝胶HCID 7018蒽酮

产物 1

HCID 661059,9'-联蒽

试剂、催化剂与溶剂 2

HCID 23994Zinc催化剂HCID 176醋酸溶剂

实验过程

After hydrochloric acid was added to an acetic acid solution of anthrone, it was refluxed upon addition of zinc. Thereafter it was refined in accordance with an ordinary method to obtain 9,9′-bianthryl. After it was added little by little to a melt of aluminum chloride and sodium chloride, the reaction mixture was poured into diluted hydrochloric acid and a solids constituent was collected. The solids constituent thus obtained was refined in accordance with an ordinary method to obtain target dibenzo[a,o]perylene.

来源与证据

ORD记录
ord-09a1edf32dea46fb8b70e9767bbae5d4
来源数据集
uspto-grants-2004_03
专利号
US06699594B1

关联笔记

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