香叶醇 → 3，7-二甲基-1-辛醇

HRID 5629

反应方程式

HRID 5629 反应方程式
[CH3:1][C:2](=[CH:4][CH2:5][CH2:6]/[C:7](=[CH:9]/[CH2:10][OH:11])/[CH3:8])[CH3:3]>C(O)C.[Pt]=O>[CH3:8][CH:7]([CH2:6][CH2:5][CH2:4][CH:2]([CH3:3])[CH3:1])[CH2:9][CH2:10][OH:11]

参与物

4

反应物 1

HCID 637566香叶醇

产物 1

HCID 77923，7-二甲基-1-辛醇收率 97.5%

试剂、催化剂与溶剂 2

HCID 82844Platinum oxide (PtO)催化剂HCID 702乙醇溶剂

实验过程

Geraniol (100 g) was dissolved in ethanol (500 ml), added with platinum oxide (500 mg) and stirred for 24 hours at room temperature under hydrogen atmosphere. After the completion of the reaction, insoluble material was removed by filtration through a Celite layer and the filtrate was concentrated under reduced pressure to obtain 3,7-dimethyloctanol (100 g).

后处理

  1. customAfter the completion of the reaction, insoluble material
  2. customwas removed by filtration through a Celite layer
  3. concentrationthe filtrate was concentrated under reduced pressure

来源与证据

ORD记录
ord-c0dfd353e6324d3daf2c3d50805ae08b
来源数据集
uspto-grants-1993_09
专利号
US05245070

关联笔记

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