乙基三苯基醋酸膦 → 三苯基苄基溴化膦

HRID 736959

反应方程式

HRID 736959 反应方程式
[Cl-].[CH2:2]([P+:6]([C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)([C:13]1[CH:18]=[CH:17][CH:16]=[CH:15][CH:14]=1)[C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)[CH2:3][CH2:4][CH3:5].C([O-])(=O)C.C([P+](C1C=CC=CC=1)(C1C=CC=CC=1)[C:32]1[CH:37]=CC=C[CH:33]=1)C.[Br-:50].C(N([P+](N(CC)CC)(N(CC)CC)N(CC)CC)CC)C>[Cl-].C([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C1C=CC=CC=1.[Br-].C([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)CCC.[Br-].C([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C.[I-].C([P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1)C.[Br-].C[P+](C1C=CC=CC=1)(C1C=CC=CC=1)C1C=CC=CC=1.[Br-].C([P+](CCCC)(CCCC)CCCC)CCC.[Br-].C1([P+](C2C=CC=CC=2)(C2C=CC=CC=2)C2C=CC=CC=2)C=CC=CC=1>[Br-:50].[CH2:2]([P+:6]([C:19]1[CH:24]=[CH:23][CH:22]=[CH:21][CH:20]=1)([C:7]1[CH:12]=[CH:11][CH:10]=[CH:9][CH:8]=1)[C:13]1[CH:14]=[CH:15][CH:16]=[CH:17][CH:18]=1)[C:3]1[CH:37]=[CH:32][CH:33]=[CH:5][CH:4]=1

参与物

11

反应物 3

HCID 94470乙基三苯基醋酸膦HCID 166797丁基三苯基氯化膦HCID 11036771Tetrakis(diethylamino)phosphonium bromide

产物 1

HCID 2734970三苯基苄基溴化膦

试剂、催化剂与溶剂 7

HCID 70671苄基三苯基氯化膦催化剂HCID 73727乙基三苯基溴化膦催化剂HCID 74505甲基三苯基溴化膦催化剂HCID 76564四正丁基溴化膦催化剂HCID 78474三苯基乙基碘化催化剂HCID 159628三苯基丁基溴化膦催化剂HCID 2724163四苯基溴化膦催化剂

实验过程

benzyltriphenylphosphonium chloride; butyltriphenylphosphonium bromide; butyltriphenylphosphonium chloride; ethyltriphenylphosphonium acetate; ethyltriphenylphosphonium bromide; ethyltriphenylphosphonium iodide; methyltriphenylphosphonium bromide; tetrabutylphosphonium bromide; tetraphenylphosphonium bromide; tetrakisdiethylaminophosphonium bromide;

来源与证据

ORD记录
ord-303f61fe29104e40bcc37dbea7042a95
来源数据集
uspto-grants-2009_09
专利号
US07595426B2

关联笔记

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