结构:O=C([O-])[O-].[Cs+].[Cs+]
HCID10796

Cesium carbonate

dicesium;carbonate

CCs2O3325.82 g/molCAS 29703-01-3

IDENTITY

结构与身份

标准 SMILES
O=C([O-])[O-].[Cs+].[Cs+]
InChIKey
FJDQFPXHSGXQBY-UHFFFAOYSA-L
分子式
CCs2O3
平均分子量
325.82 g/mol
单同位素质量
325.7956478

COMPUTED

结构计算性质

已同步
极性表面积
63.2 Ų
氢键供体
0
氢键受体
3
可旋转键
0
重原子
6
形式电荷
0
复杂度
18

PROPERTIES

实验与物化性质

来源:PubChem
Density

4.24 @25 °C

Melting Point

793 °C

Physical Description

Dry Powder; Liquid

Highly deliquescent solid; [Merck Index] White odorless powder or granules; Hygroscopic; [Alfa Aesar MSDS]

GHS

GHS 分类

来源:PubChem
GHS Classification

This chemical does not meet GHS hazard criteria for 1% (2 of 200) of reports.

Danger

H315 (41.5%): Causes skin irritation [Warning Skin corrosion/irritation];H318 (59%): Causes serious eye damage [Danger Serious eye damage/eye irritation];H319 (40%): Causes serious eye irritation [Warning Serious eye damage/eye irritation];H335 (41%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation];H361f (54.5%): Suspected of damaging fertility [Warning Reproductive toxicity];H373 (58.5%): May causes damage to organs through prolonged or repeated exposure [Warning Specific target organ toxicity, repeated exposure]

P203, P260, P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P305+P354+P338, P317, P318, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 200 reports by companies from 22 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Reported as not meeting GHS hazard criteria per 2 of 200 reports by companies.;There are 21 notifications provided by 198 of 200 reports by companies with hazard statement code(s).;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

HAZARDS

危害信息

来源:PubChem
Regulatory Information

Chemical: Carbonic acid, dicesium salt

Carbonic acid, cesium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Carbonic acid, cesium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 27-01-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/11170

Carbonic acid, dicaesium salt: Does not have an individual approval but may be used under an appropriate group standard

Other Safety Information

Evaluation - Cesium salts

Hazards Summary

Causes convulsions, elevated blood pressure, and proteinuria in intraperitoneal and subcutaneous lethal-dose studies of mice and rats; [RTECS] A skin and strong eye irritant; [Alfa Aesar MSDS] See Cesium.

Hazard Classes and Categories

Skin Irrit. 2 (41.5%);Eye Dam. 1 (59%);Eye Irrit. 2 (40%);STOT SE 3 (41%);Repr. 2 (54.5%);STOT RE 2 (58.5%)

Eye Dam. 1 (100%);Repr. 2 (100%);STOT RE 2 (100%)

SAFETY

安全与防护

来源:PubChem
Protective Action Criteria (PAC)

7.0 [mg/m3]

77 [mg/m3]

460 [mg/m3]

REGULATORY

法规信息

来源:PubChem
Regulatory Information

Chemical: Carbonic acid, dicesium salt

Carbonic acid, cesium salt (1:2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Carbonic acid, cesium salt (1:2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

Status: Active Update: 27-01-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/11170

Carbonic acid, dicaesium salt: Does not have an individual approval but may be used under an appropriate group standard

USES

用途与制造

来源:PubChem
Uses

Catalyst in ethylene oxide polymerization; in coating for spatter-free welding of steel in CO2; in oxide cathode. [Merck Index]

Gas Welding and Cutting [Category: Weld]

U.S. Production

2023: <50,000 lb;2022: 50,000 - <250,000 lb;2021: <50,000 lb;2020: <50,000 lb

Industry Uses

Intermediate

General Manufacturing Information

All Other Basic Inorganic Chemical Manufacturing

Carbonic acid, cesium salt (1:2): ACTIVE

ALIASES

名称与别名

74
CESIUM CARBONATE534-17-8Dicesium carbonateQQI20A14P4NSC-112218RefChem:575247208-591-9249-784-8Caesium carbonatecesiumcarbonatedicesium;carbonateCarbonic acid, cesium salt (1:2)Carbonic acid, dicesium saltCs2CO3Cesium carbonate (Cs2CO3)CCs2O3MFCD00010957Carbonic acid dicesiumCesium carbonate, 200 meshcesium carbonato

REACTIONS

参与反应

28,074