结构:CCOC(=O)C=[N+]=[N-]
HCID12192

Ethyl diazoacetate

ethyl 2-diazoacetate

C4H6N2O2114.1 g/molCAS 623-73-4

IDENTITY

结构与身份

标准 SMILES
CCOC(=O)C=[N+]=[N-]
InChIKey
YVPJCJLMRRTDMQ-UHFFFAOYSA-N
分子式
C4H6N2O2
平均分子量
114.1 g/mol
单同位素质量
114.04292744

COMPUTED

结构计算性质

已同步
XLogP
0.7
极性表面积
28.3 Ų
氢键供体
0
氢键受体
3
可旋转键
3
重原子
8
形式电荷
0
复杂度
126

PROPERTIES

实验与物化性质

来源:PubChem
Density

1.085 @25 °C

Physical Description

Yellow liquid with a pungent odor; [Merck Index] Light to dark yellow liquid; [Sigma-Aldrich MSDS]

GHS

GHS 分类

来源:PubChem
GHS Classification

Warning

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids];H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]

P210, P233, P240, P241, P242, P243, P264, P270, P280, P301+P317, P303+P361+P353, P330, P370+P378, P403+P235, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 42 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

HAZARDS

危害信息

来源:PubChem
Regulatory Information

Acetic acid, diazo-, ethyl ester: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary

Highly volatile and explosive; [Merck Index] May explode on heating; An irritant; May cause nervous system disturbances; Possible carcinogen and mutagen; Targets the liver and pancreas; Harmful by ingestion, inhalation, and skin absorption; [Sigma-Aldrich MSDS] See Diazodinitrophenol.

Hazard Classes and Categories

Flam. Liq. 3 (100%);Acute Tox. 4 (100%)

SAFETY

安全与防护

来源:PubChem
Protective Action Criteria (PAC)

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

TOXICITY

毒理信息

来源:PubChem
Adverse Effects

Occupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation.

REGULATORY

法规信息

来源:PubChem
Regulatory Information

Acetic acid, diazo-, ethyl ester: Does not have an individual approval but may be used under an appropriate group standard

ALIASES

名称与别名

51
Ethyl diazoacetate623-73-4Diazoacetic esterEthyldiazoacetateDAAEEthoxycarbonyldiazomethaneDiazoacetic acid, ethyl esterN84B835FMRNSC-79147DTXSID10878732RefChem:132757DTXCID201016771210-810-8Ethyl 2-diazoacetateethyl2-diazoacetateDiazoacetic acid ethyl esterEthyl-2-diazoacetateACETIC ACID, DIAZO-, ETHYL ESTERdiazo-acetic acid ethyl esterEthyl Diazoacetate (>90%)

REACTIONS

参与反应

707