Sodium methanethiolate 分子结构式
HCID4378561

Sodium methanethiolate

CH3NaS70.09 g/molCAS 5188-07-8

IDENTITY

结构与身份

标准SMILES
C[S-].[Na+]
InChIKey
RMBAVIFYHOYIFM-UHFFFAOYSA-M
分子式
CH3NaS
平均分子量
70.09 g/mol
单同位素质量
69.98531555

COMPUTED

结构计算性质

已同步
极性表面积
1 Ų
氢键供体
0
氢键受体
1
可旋转键
0
重原子
3
形式电荷
0
复杂度
4

PROPERTIES

实验与物化性质

来源:PubChem
Vapor Pressure

0.00000108 [mmHg]

Physical Description

Colorless liquid; [EPA ChAMP: Submission] Light brown solid; [Sigma-Aldrich MSDS] Strong offensive odor;

GHS

GHS分类

来源:PubChem
GHS Classification

Danger

H226 (18.8%): Flammable liquid and vapor [Warning Flammable liquids];H228 (63.8%): Flammable solid [Danger Flammable solids];H301 (79.7%): Toxic if swallowed [Danger Acute toxicity, oral];H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation];H318 (20.3%): Causes serious eye damage [Danger Serious eye damage/eye irritation]

P210, P233, P240, P241, P242, P243, P260, P264, P264+P265, P270, P280, P301+P316, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 69 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

HAZARDS

危害信息

来源:PubChem
Regulatory Information

Status: Active Update: 08-04-2011 https://echa.europa.eu/registration-dossier/-/registered-dossier/10183;Status: Active Update: 02-10-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/31705

Methanethiol, sodium salt: HSNO Approval: HSR007148 Approved with controls

Hazards Summary

Changes of the blood, spleen (hematopoiesis and hemosiderosis), and liver (hematopoiesis) observed in oral study of rats at 45 mg/kg/day; No evidence of reproductive or developmental toxicity; [EPA - TSCATS] A severe skin irritant; Causes somnolence, dyspnea, and other gastrointestinal changes in oral lethal-dose studies of rats; [RTECS] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract; Toxic by ingestion; [Sigma-Aldrich MSDS] Reacts with water evolving methanethiol gas; [Alfa Aesar MSDS] See Methyl mercaptan.

Hazard Classes and Categories

Flam. Liq. 3 (18.8%);Flam. Sol. 2 (63.8%);Acute Tox. 3 (79.7%);Skin Corr. 1B (100%);Eye Dam. 1 (20.3%)

TOXICITY

毒理信息

来源:PubChem
Adverse Effects

Dermatotoxin - Skin burns.

REGULATORY

法规信息

来源:PubChem
Regulatory Information

Status: Active Update: 08-04-2011 https://echa.europa.eu/registration-dossier/-/registered-dossier/10183;Status: Active Update: 02-10-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/31705

Methanethiol, sodium salt: HSNO Approval: HSR007148 Approved with controls

USES

用途与制造

来源:PubChem
Uses

Used to make large scale and fine chemicals; [ECHA REACH Registrations]

General Manufacturing Information

Methanethiol, sodium salt (1:1): ACTIVE

ALIASES

名称与别名

共 46 条
Sodium methanethiolate5188-07-8Sodium thiomethylateLB29JWW8H7RefChem:887680225-969-9Sodium thiomethoxideMethanethiol sodium saltMethyl mercaptan sodium saltsodium;methanethiolateCCRIS 9102Methanethiol, sodium salt (1:1)EINECS 225-969-9MFCD00174316UNII-LB29JWW8H7Sodium Methanethiolate (95%)Sodium Methanethiolate (95per cent)sodium methyl mercaptideEC 225-969-9sodiumthiomethoxide

REACTIONS

参与反应

1,196
HRID 799 反应方程式

uspto-grants-1998_03 · 10.6084/m9.figshare.5104873.v1 · US05723412

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HRID 6015 反应方程式

uspto-grants-1993_09 · 10.6084/m9.figshare.5104873.v1 · US05246961

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HRID 6019 反应方程式

uspto-grants-1993_09 · 10.6084/m9.figshare.5104873.v1 · US05246961

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HRID 6023 反应方程式

uspto-grants-1993_09 · 10.6084/m9.figshare.5104873.v1 · US05246961

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HRID 10436 反应方程式

uspto-grants-2006_08 · 10.6084/m9.figshare.5104873.v1 · US07094769B2

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HRID 10907 反应方程式

uspto-grants-2006_08 · 10.6084/m9.figshare.5104873.v1 · US07094919B2

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HRID 10908 反应方程式

uspto-grants-2006_08 · 10.6084/m9.figshare.5104873.v1 · US07094919B2

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HRID 12199 反应方程式

uspto-grants-2010_06 · 10.6084/m9.figshare.5104873.v1 · US07727985B2

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