uspto-grants-1998_03 · 10.6084/m9.figshare.5104873.v1 · US05723412
查看IDENTITY
结构与身份
- 标准SMILES
- C[S-].[Na+]
- InChIKey
- RMBAVIFYHOYIFM-UHFFFAOYSA-M
- 分子式
- CH3NaS
- 平均分子量
- 70.09 g/mol
- 单同位素质量
- 69.98531555
COMPUTED
结构计算性质
- 极性表面积
- 1 Ų
- 氢键供体
- 0
- 氢键受体
- 1
- 可旋转键
- 0
- 重原子
- 3
- 形式电荷
- 0
- 复杂度
- 4
PROPERTIES
实验与物化性质
Vapor Pressure
0.00000108 [mmHg]
Physical Description
Colorless liquid; [EPA ChAMP: Submission] Light brown solid; [Sigma-Aldrich MSDS] Strong offensive odor;
GHS
GHS分类
GHS Classification
Danger
H226 (18.8%): Flammable liquid and vapor [Warning Flammable liquids];H228 (63.8%): Flammable solid [Danger Flammable solids];H301 (79.7%): Toxic if swallowed [Danger Acute toxicity, oral];H314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation];H318 (20.3%): Causes serious eye damage [Danger Serious eye damage/eye irritation]
P210, P233, P240, P241, P242, P243, P260, P264, P264+P265, P270, P280, P301+P316, P301+P330+P331, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 69 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.;Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.
HAZARDS
危害信息
Regulatory Information
Status: Active Update: 08-04-2011 https://echa.europa.eu/registration-dossier/-/registered-dossier/10183;Status: Active Update: 02-10-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/31705
Methanethiol, sodium salt: HSNO Approval: HSR007148 Approved with controls
Hazards Summary
Changes of the blood, spleen (hematopoiesis and hemosiderosis), and liver (hematopoiesis) observed in oral study of rats at 45 mg/kg/day; No evidence of reproductive or developmental toxicity; [EPA - TSCATS] A severe skin irritant; Causes somnolence, dyspnea, and other gastrointestinal changes in oral lethal-dose studies of rats; [RTECS] Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract; Toxic by ingestion; [Sigma-Aldrich MSDS] Reacts with water evolving methanethiol gas; [Alfa Aesar MSDS] See Methyl mercaptan.
Hazard Classes and Categories
Flam. Liq. 3 (18.8%);Flam. Sol. 2 (63.8%);Acute Tox. 3 (79.7%);Skin Corr. 1B (100%);Eye Dam. 1 (20.3%)
TOXICITY
毒理信息
Adverse Effects
Dermatotoxin - Skin burns.
REGULATORY
法规信息
Regulatory Information
Status: Active Update: 08-04-2011 https://echa.europa.eu/registration-dossier/-/registered-dossier/10183;Status: Active Update: 02-10-2020 https://echa.europa.eu/registration-dossier/-/registered-dossier/31705
Methanethiol, sodium salt: HSNO Approval: HSR007148 Approved with controls
USES
用途与制造
Uses
Used to make large scale and fine chemicals; [ECHA REACH Registrations]
General Manufacturing Information
Methanethiol, sodium salt (1:1): ACTIVE
ALIASES
名称与别名
REACTIONS
参与反应
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