Grundinformationen
- Standard-SMILES
[Co+2].[OH-].[OH-]- InChIKey
ASKVAEGIVYSGNY-UHFFFAOYSA-L- Summenformel
- CoH2O2
- Durchschnittliche Molmasse
- 92,948 g/mol
- Monoisotopische Masse
- 92,9386743
Überblick
Cobalt(II) hydroxide Co(OH)2 is a hydroxide of cobalt. It occurs in two forms, either as a rose-red powder, which is the more stable of the two forms, or as bluish-green powder. It is used as a drying agent for paints, varnishes, and inks, in the preparation of other cobalt compounds, as a catalyst, or in the manufacture of battery electrodes. Cobalt is a metallic element with the atomic number 27. It is found naturally in rocks, soil, water, plants, and animals. In small amounts cobalt is an essential element for life, as it is part of vitamin B12. However, excess exposure is known to exhibit toxic effects. (L29, L30, L490)
Namen und Bezeichner
- Bevorzugter Name
- Cobalt hydroxide
- IUPAC
- cobalt(2+) dihydroxide
- Lokaler Name
- Cobalthydroxid
- Englischer Name
- Cobalt hydroxide
- Summenformel
- Co(HO)2
- Molmasse
- 92.948
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
12672-51-4、21041-93-0- PubChem CID
- 10129900
- DTXSID
DTXSID70894155- UNII
- 51B9AYG60K
- EC Number
- 235-763-0
- Nikkaji
- J96.009H
Eigenschaften
Berechnete Struktureigenschaften
- Polarare Oberfläche (TPSA)
- 2 Ų
- H-Brücken-Donoren
- 2
- H-Brücken-Akzeptoren
- 2
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 3
- Formalladung
- 0
- Komplexität
- 0
Experimentelle und physikochemische Eigenschaften
Chemical Classes
Metals -> Metals, Inorganic Compounds
Metals -> Metals, Inorganic Compounds
Physical Description
CBI; Dry Powder; Wet Solid; Dry Powder; Wet Solid; Other Solid
Blue-green or rose-red solid (red form more stable); [Merck Index] Pink powder, practically insoluble in water; [MSDSonline]
Physikochemische Eigenschaften
- Schmelzpunkt
- 168 ° · 168 ° C (334.4 ° F)
- Dichte
- 3.597 g/cm3 · 3.597 g/cm3
- Aggregatzustand
- powder
- Farbe
- Red or bluish-green
- Wasserlöslichkeit
- 3.2 mg/L · 3.20 mg/L
- InChI
- InChI=1S/Co.2H2O/h;2*1H2/q+2;;/p-2
- InChIKey
- ASKVAEGIVYSGNY-UHFFFAOYSA-L
- SMILES
- [Co+2].[O-][H].[O-][H]
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
This chemical does not meet GHS hazard criteria for 100% (104 of 104) of all reports.
Not Classified
Aggregated GHS information provided per 104 reports by companies from 1 notifications to the ECHA C&L Inventory.
Danger
H302: Harmful if swallowed [Warning Acute toxicity, oral]
P203, P233, P260, P261, P264, P264+P265, P270, P271, P272, P280, P284, P301+P317, P302+P352, P304+P340, P305+P351+P338, P316, P318, P319, P320, P321, P330, P333+P317, P337+P317, P342+P316, P362+P364, P403, P403+P233, P405, and P501 (click each P-code to see the statement)
Gefahrenhinweise
Regulatory Information
Chemical: Cobalt(II) hydroxide
Cobalt hydroxide (Co(OH)2) is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Cobalt hydroxide (Co(OH)2) are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)
Cobalt hydroxide (mixed): Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Cobalt hydroxide: Does not have an individual approval but may be used under an appropriate group standard
Hazards Summary
May be harmful; May cause skin sensitization; [MSDSonline] See Cobalt.
See Cobalt.
Hazard Classes and Categories
Not Classified
Eye irritation - category 2A
Sicherheit und Schutzausrüstung
Exposure Control and Personal Protection
Biological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;
Biological Exposure Indices (BEI) [ACGIH] - Cobalt in urine = 15 ug/L; sample at end of shift at end of workweek;
Threshold Limit Values (TLV)
0.02 [mg/m3], as Co
0.02 [mg/m3], as Co
Protective Action Criteria (PAC)
0.095 [mg/m3]
0.37 [mg/m3]
2.2 [mg/m3]
Toxikologische Informationen
Toxicity Summary
Cobalt is believed to exhibit its toxicity through a oxidant-based and free radical-based processes. It produces oxygen radicals and may be oxidized to ionic cobalt, causing increased lipid peroxidation, DNA damage, and inducing certain enzymes that lead to cell apoptosis. Cobalt has also been shown to block inorganic calcium channels, possibly impairing neurotransmission. Cobalt can also chelate lipoic acids, impairing oxidation of pyruvate or fatty acids. In addition, cobalt may inhibit DNA repair by interacting with zinc finger DNA repair proteins, and has also been shown to inhibit heme synthesis and glucose metabolism. Cobalt may activate specific helper T-lymphocyte cells and interact directly with immunologic proteins, such as antibodies (IgA and IgE) or Fc receptors, resulting in immunosensitization. (L29)
RAIS Toxicity Values
0.0077
CALEPA
Chemie und Industrie
Pharmakologische Informationen
Metabolism/Metabolites
Cobalt is absorbed though the lungs, gastrointestinal tract, and skin. Since it is a component of the vitamin B12 (cyanocobalamin), it is distributed to most tissues of the body. It is transported in the blood, often bound to albumin, with the highest levels being found in the liver and kidney. Cobalt is excreted mainly in the urine and faeces. (L29)
Verwendung und Herstellung
Uses
Used to make cobalt compounds, as a drier for paints, to aid drying of lithographic inks, and in storage battery electrode impregnating solutions; [Merck Index]
Battery Manufacturing [Category: Industry]
Cobalt(II) hydroxide is used as a drying agent for paints, varnishes, and inks, in the preparation of other cobalt compounds, as a catalyst, or in the manufacture of battery electrodes. (L490)
General Manufacturing Information
Agriculture, Forestry, Fishing and Hunting
Cobalt hydroxide (Co(OH)2): ACTIVE
Anwendungen
VerwendenCobalt hydroxide is an important organic raw material in the fields of chemistry, materials and technical engineering and is used in the preparation of cement-based structural supercapacitors, as a colouring agent for glass and enamel, as a raw material for other cobalt compounds, and as a drying agent for varnishes and paints[1].
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