Chloroisopropylmagnesium (HCID 101955)

Namen und Bezeichner

Bevorzugter Name: Chloroisopropylmagnesium
IUPAC: magnesium;propane;chloride
Lokaler Name: Chlor(1-methylethyl)magnesium
Englischer Name: Isopropylmagnesium chloride
Summenformel: C3H7ClMg
Molmasse: 102.85

Namen und Synonyme

Isopropylmagnesium Chloride1068-55-9Magnesium, chloro(1-methylethyl)-Chloro(1-methylethyl)magnesiumChloroisopropylmagnesium2-Propylmagnesium chlorideMN8G5FEJ5JChloro(propan-2-yl)magnesiumMAGNESIUM, CHLOROISOPROPYL-EINECS 213-947-1DTXSID6061444EC 213-947-1

Weitere Namen anzeigen

Isopropylmagnesium Chloride (11% in Tetrahydrofuran, ca. 1mol/L)IsopropylchloromagnesiumSOPROPYLMAGNESIUM CHLORIDEChloro(isopropyl) magnesiumLsopropylmagnesium ChlorideIsopropylmagnesium chloride, 1M in MeTHF

RefChem:575861Magnesium, chloro(1methylethyl)DTXCID7033028213-947-1i-PrMgCli-propylmagnesium chlorideisopropyl magnesium chlorideisopropylmagnesium chlorid

Datenbank-Bezeichner

CAS: 1068-55-9
PubChem CID: 101955
DTXSID: DTXSID6061444
UNII: MN8G5FEJ5J
EC Number: 213-947-1、936-069-7

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 2
Frei drehbare Bindungen: 0
Schwere Atome: 5
Formalladung: 0
Komplexität: 6,9

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Metals, Organic Compounds

Density0.834 @25 °C

Physical Description1 Molar solution in tetrahydrofuran: Liquid; [Alfa Aesar MSDS]

Physikochemische Eigenschaften

Schmelzpunkt: 155 · 155-157 °C
Siedepunkt: 256 °C · 256 °C
Dichte: 0.98 g/mL · 0.98 g/mL at 20 °C
Flammpunkt: 72 °F · 72 °F
storage temp.: Flammables + water-Freezer (-20°C)e area
Aggregatzustand: Solution
Farbe: Yellow-brown to dark brown
Wasserlöslichkeit: It reacts violently with water.
BRN: 4124221 · 4124221
InChI: InChI=1S/C3H7.ClH.Mg/c1-3-2;;/h3H,1-2H3;1H;/q;;+1/p-1
InChIKey: GPIBKUJXKCEZOH-UHFFFAOYSA-M
SMILES: C(C)(C)[Mg]Cl
CAS Datenbank: 1068 · 1068-55-9(CAS DataBase Reference)
EPA chemische Informationen: Magnesium, chloro(1-methylethyl)- (1068-55-9)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 6 Einträge

Danger

H225 (36.4%): Highly Flammable liquid and vapor [Danger Flammable liquids]

P210, P223, P231+P232, P233, P240, P241, P242, P243, P260, P264, P264+P265, P280, P301+P330+P331, P302+P335+P334, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P363, P370+P378, P402+P404, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 121 reports by companies from 7 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Danger

H225 (100%): Highly Flammable liquid and vapor [Danger Flammable liquids]

Gefahrenhinweise

Regulatory Information · 3 Einträge

Magnesium, chloro(1-methylethyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Magnesium, chloro(1-methylethyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)

REACH registered substance: Chloro(1-methylethyl)magnesium (EC: 213-947-1)

Magnesium, chloro(1-methylethyl)-: Does not have an individual approval but may be used under an appropriate group standard

Hazards Summary · 1 Eintrag

1 molar solution in tetrahydrofuran (CAS# 96-47-9): May form explosive peroxides; Reacts violently with water evolving extremely flammable gases; Causes burns; Inhalation may cause corrosive injuries to upper respiratory tract and lungs; [Alfa Aesar MSDS] See Methylmagnesium chloride.

Hazard Classes and Categories · 2 Einträge

Flam. Liq. 2 (36.4%)

Flam. Liq. 2 (100%)

Sicherheit und Schutzausrüstung

Protective Action Criteria (PAC) · 3 Einträge

1.2 [mg/m3]

13 [mg/m3]

79 [mg/m3]

Toxikologische Informationen

Adverse EffectsDermatotoxin - Skin burns.

Sicherheitsdaten

F: 1-3-10
wgk: 1
tsca: TSCA listed
ridadr: UN 3399 4.3/PG 2
hs_code: 29319090
risk_code: 12-14/15-19-22-34-66-67-14-10-11-37
hazard_code: C,F+,F
safety_code: 26-36/37/39-43-45-16-33-9
hazard_class: 4.3
packing_group: I
Speicherklasse: 4.3 - Hazardous materials which set free flammable gases upon contact with water
Hazard Classifications: Carc. 2Eye Dam. 1Flam. Liq. 2Skin Corr. 1BSTOT SE 3Water-react 1

Chemie und Industrie

Verwendung und Herstellung

UsesUsed as an intermediate; [ExPub: ECHA REACH Registrations]

U.S. Production2022: 38,966 lb

Industry UsesIntermediate

General Manufacturing Information · 2 Einträge

All Other Basic Organic Chemical Manufacturing

Magnesium, chloro(1-methylethyl)-: ACTIVE

Anwendungen

VerwendenIsopropylmagnesium Chloride is a grignard reagent that can be used in the transmetalation of grignard reagents to make versatile org. semiconductors.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

6-[(2-phenylhydrazinyl)methylidene]cyclohexa-2,4-dien-1-one Methylmagnesiumbromid Tetrahydrofuran Bromethan Magnesium 2-Chlorpropan

Nachgelagerte Produkte

3-Quinolineboronic acid 6-Methylpyridine-2-boronic acid 2-Chlorcumol 3-(Trimethylsilyl)-2-propyn-1-ol Isopropylboronic acid 2-Methyloctan-3-on Isopentylbenzol Ethyl-4-methylvalerat 4-Isopropylbiphenyl 10,10'-bianthron 2-Isopropylpyridin Triisopropylphosphin

Anbieter50 Anbieter

国药集团化学试剂有限公司86-21-63210123 · [email protected]

梯希爱(上海)化成工业发展有限公司021-67121386 · [email protected]

郑州阿尔法化工有限公司+86-18530059196 · [email protected]

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]

阜新孚隆宝医药科技有限公司15901742157 · [email protected]

Zugehörige Reaktionen

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Reaktionsaufzeichnung erstellen

HRID 1996022als Reagenz39k HTE dataset from Pfizer

HRID 1996229als Reagenz39k HTE dataset from Pfizer

HRID 1996237als Reagenz39k HTE dataset from Pfizer

HRID 1996300als Reagenz39k HTE dataset from Pfizer

HRID 1996344als Reagenz39k HTE dataset from Pfizer

HRID 1998275als Reagenz39k HTE dataset from Pfizer

HRID 1998304als Reagenz39k HTE dataset from Pfizer

HRID 1998363als Reagenz39k HTE dataset from Pfizer

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