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Chromic chloride hexahydrate

HCID 104957
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Grundinformationen

CAS
10060-12-5
Standard-SMILES
O.O.O.O.O.O.[Cl][Cr]([Cl])[Cl]
InChIKey
LJAOOBNHPFKCDR-UHFFFAOYSA-K
Summenformel
Cl3Cr.6H2O
Durchschnittliche Molmasse
266,44 g/mol
Monoisotopische Masse
264,910451

Namen und Bezeichner

Bevorzugter Name
Chromic chloride hexahydrate
IUPAC
trichlorochromium;hexahydrate
Englischer Name
Chromic chloride hexahydrate
Summenformel
Cl3CrH12O6
Molmasse
266.45

Namen und Synonyme

Chromic chloride hexahydrateChromic chloride (USP)Chromic chloride [USP]Chromium chloride (CrCl3), hexahydrateDTXSID1041001RefChem:918560DTXCID9021001Chromium(III) chloride hexahydratetrichlorochromium;hexahydrateChromium chloride, hexahydrateChrom(III)-chloridChromic (III) chloride
Weitere Namen anzeigen
CrClCHROMIC CHLORIDE 6-HYDRATECHROMIUM(III) CHLORIDE PURECl3CrH12O6Chromic chLChromiumChlorideUspCHROMICCHLORIDE,USPCHROMIC CHLORIDE 6H2OCHROMIUM CHLORIDE XHYD
Chrom(III)-chlorid, wasserfreiHexaaquachromium chlorideChromium 4Hexaaquachromium(III) chlorideUNII-KB1PCR9DMWChlorid chromity hexahydrat [Czech]Chlorid chromity hexahydratCCRIS 8583

Datenbank-Bezeichner

CAS
10060-12-5
PubChem CID
104957
DTXSID
DTXSID1041001

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
6 Ų
H-Brücken-Donoren
6
H-Brücken-Akzeptoren
6
Frei drehbare Bindungen
0
Schwere Atome
10
Formalladung
0
Komplexität
8

Experimentelle und physikochemische Eigenschaften

Chemical ClassesMetals -> Chromium Compounds, Inorganic
Density2.76 g/cm³
SolubilitySolubility in water, g/100ml at 20 °C: 59
Melting Point83-95 °C
Physical Description · 2 Einträge

Green or violet, deliquescent solid; [Merck Index] Soluble in water at 20 deg C; [ACGIH]

GREEN CRYSTALLINE POWDER.

Physikochemische Eigenschaften

Schmelzpunkt
83 °C · 83 °C
Dichte
1.76 g/mL · 1.76 g/mL at 25 °C(lit.)
storage temp.
Inert atmosphere,Room Temperature
Löslichkeit
Methanol (Slightly), Water (Slightly)
Aggregatzustand
Powder/Solid
Farbe
Reddish-violet
Wichte
1.76 · 1.76

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Chromium chloride, hexahydrate

Chromium (III) chloride, hexahydrate: Does not have an individual approval but may be used under an appropriate group standard

Fire HazardsNot combustible.
Hazards Summary · 1 Eintrag

CrIII compounds do not cause chrome ulcerations but may cause allergic dermatitis in workers with prior sensitization to CrVI compounds. [ILO Encyclo] CrIII is an essential trace mineral in the human diet. [ATSDR Case Studies] A respiratory tract irritant; May cause skin sensitization; [ICSC] See Chromium.

Chemical DangersThe solution in water is a weak acid.

Sicherheit und Schutzausrüstung

Fire FightingIn case of fire in the surroundings, use appropriate extinguishing media.
First Aid Measures · 4 Einträge

Fresh air, rest.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Do NOT induce vomiting. Give one or two glasses of water to drink. Refer for medical attention .

Spillage Disposal · 1 Eintrag

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting.

Eye Prevention

Chemie und Industrie

Verwendung und Herstellung

Uses · 2 Einträge

Used in chromizing, tanning, waterproofing and as a polymerization catalyst, textile mordant, and corrosion inhibitor; [Merck Index]

Leather Tanning and Processing [Category: Industry]

Anwendungen

VerwendenChromium(III) chloride hexahydrate is used as an organic synthesis catalyst and as an additive to intravenous solutions.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

Dichromtris(sulfat)Natriumdichromat DihydratChromtrichloridChromic carbonateMelassen

Anbieter100 Anbieter

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PH
2 · 2.0-3.0
Wasserlöslichkeit
Soluble in water and alcohol. Insoluble in diethyl ether.
Merck
14 · 14,2222
Stabilität
Stable, but may be air-sensitive. Hygroscopic. Incompatible with lithium, nitrogen, strong oxidizing agents.
InChI
1S/3ClH.Cr.6H2O/h3*1H;;6*1H2/q;;;+3;;;;;;/p-3
InChIKey
LJAOOBNHPFKCDR-UHFFFAOYSA-K
SMILES
[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].[H]O[H].Cl[Cr](Cl)Cl
CAS Datenbank
10060 · 10060-12-5(CAS DataBase Reference)
EPA chemische Informationen
Chromium(III) chloride hexahydrate (10060-12-5)
Wear safety goggles.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly when dispersed.
Skin PreventionProtective gloves. Protective clothing.
Exposure PreventionSTRICT HYGIENE!
Ingestion PreventionDo not eat, drink, or smoke during work.
Inhalation PreventionUse local exhaust or breathing protection.
Threshold Limit Values (TLV) · 2 Einträge

0.003 [mg/m3], as Cr(III), inhalable particulate matter

(as Cr(III), inhalable fraction): 0.003 mg/m

Effects of Long Term ExposureRepeated or prolonged contact may cause skin sensitization.
Effects of Short Term ExposureThe substance is irritating to the respiratory tract.

Toxikologische Informationen

Adverse EffectsSkin Sensitizer - An agent that can induce an allergic reaction in the skin.
Signs and Symptoms · 2 Einträge

Cough. Sore throat.

Abdominal pain. Diarrhoea. Nausea. Vomiting.

ICSC Environmental DataThe substance is toxic to aquatic organisms.

Sicherheitsdaten

wgk
1
tsca
Yes
ridadr
UN3260
hs_code
28273985
RTECS-Nr.
GB5450000
risk_code
22-36/37/38-51/53-34
hazard_code
Xn,N,C
safety_code
24/25-61-45-36/37/39-26
hazard_class
8
packing_group
III
Speicherklasse
8B - Non-combustible corrosive hazardous materials
Hazard Classifications
Acute Tox. 4 OralAquatic Chronic 2Met. Corr. 1Skin Sens. 1B
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