Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)

HCID 105144CAS 16065-88-6

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Grundinformationen

Standard-SMILES: [Pd+2]
InChIKey: MUJIDPITZJWBSW-UHFFFAOYSA-N
Summenformel: Pd+2
Durchschnittliche Molmasse: 106,42 g/mol
Monoisotopische Masse: 105,90238884

Überblick

See also: Palladium (annotation moved to).

Namen und Bezeichner

Bevorzugter Name: Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)
IUPAC: palladium(2+)
Englischer Name: Allylchloro[1,3-bis(2,6-di-I-propylphenyl)imidazol-2-ylidene]palladium (II)
Summenformel: C30H41ClN2Pd
Molmasse: 571.53

Namen und Synonyme

Allyl[1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene]chloropalladium(II)Allyl(1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene)chloropalladium(II)RefChem:554893625-870-4PALLADIUM IONpalladium(2+)16065-88-6Palladous ionPalladium(2+), ionPALLADIUM(II)Palladium, ion (Pd(2+))palladium(+2)

Weitere Namen anzeigen

(NHC)Pd(allyl)Cl-2-yLUmicore CX21ALLYLCHLORO[1,3-BIS(2imidazol-2-ylidene]palladium(II)UMicore CX21, 18% Pd, Product of UMicoreAllylchloro[1,3-bis(2,6-di-i-propylphenyl)[1,3-bis(2,6-diisopropylphenyl)-2H-imidazol-2-yl]-chloro-pal...

PDIIPd++Pd2+SCHEMBL29372082DTXSID10936361MUJIDPITZJWBSW-UHFFFAOYSA-NQ27464366

Datenbank-Bezeichner

CAS: 16065-88-6、478980-03-9
PubChem CID: 105144
DTXSID: DTXSID10936361
EC Number: 625-870-4
Nikkaji: J3.792.114I

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 0
Frei drehbare Bindungen: 0
Schwere Atome: 1
Formalladung: 2
Komplexität: 0

Physikochemische Eigenschaften

Schmelzpunkt: 190 °C · 190°C (dec.)
storage temp.: 2 · under inert gas (nitrogen or Argon) at 2–8 °C
Aggregatzustand: Powder
Farbe: white
InChI: InChI=1S/Pd/q+2
InChIKey: MUJIDPITZJWBSW-UHFFFAOYSA-N
SMILES: [Pd+2]

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Warning

H252 (34.4%): Self-heating in large quantities; may catch fire [Warning Self-heating substances and mixtures]

P235, P261, P264, P264+P265, P271, P273, P280, P302+P352, P304+P340, P305+P351+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, P407, P410, P413, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 64 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Hazard Classes and CategoriesSelf-heat. 2 (34.4%)

Sicherheitsdaten

wgk: 3
hs_code: 28439000
risk_code: 36/37/38
hazard_code: Xi
safety_code: 26-36/37/39-36/37
Speicherklasse: 11 - Combustible Solids
Hazard Classifications: Eye Irrit. 2Skin Irrit. 2STOT SE 3

Chemie und Industrie

Anwendungen · 1 Eintrag

VerwendenALLYLCHLORO[1,3-BIS(2,6-DI-I-PROPYLPHENYL)IMIDAZOL-2-YLIDENE]PALLADIUM (II) is used as a catalyst for the arylation of ketones, Suzuki coupling reaction, Buchwald-Hartwig amination reaction, dehalogenation of aryl chlorides, and oxidation of secondary alcohols.