Bis(norbornadiene)rhodium(I) tetrafluoroborate

HCID 10915722

Notizen Reaktionen

Teilstruktursuche Ähnliche Strukturen suchen

Grundinformationen

CAS: 36620-11-8
Standard-SMILES: C1=CC2C=CC1C2.C1=CC2C=CC1C2.F[B-](F)(F)F.[Rh]
InChIKey: ZWPWNBFOFVFMPP-UHFFFAOYSA-N
Summenformel: C14H16BF4Rh-
Durchschnittliche Molmasse: 373,99 g/mol
Monoisotopische Masse: 374,03417137

Namen und Bezeichner

Bevorzugter Name: Bis(norbornadiene)rhodium(I) tetrafluoroborate
IUPAC: bis(bicyclo[2.2.1]hepta-2,5-diene);rhodium;tetrafluoroborate
Englischer Name: Bis(norbornadiene)rhodium (I) tetrafluoroborate
Summenformel: C14H8BF4Rh
Molmasse: 365.93

Namen und Synonyme

36620-11-8Bis(norbornadiene)rhodium(I) tetrafluoroborateDTXSID30448239RefChem:329875DTXCID80399060625-230-4Bis(norbornadiene)rhodium (I) tetrafluoroborateMFCD00671775Bis[eta-(2,5-norbornadiene)]rhodium(I) Tetrafluoroborate[rh(nbd)2]bf4bicyclo[2.2.1]hepta-2,5-diene;rhodium;tetrafluoroborateChiralyst P374

Weitere Namen anzeigen

[Rh(ndb)2]BF4BIS(NORBORNADIENE)RH[Rh(norbornadiene)2]BF4Bis(norbornadiene)rhodium(I) tetBis(norbornadiene)rhodium(I) tetrafLbis(diene)tetrafluoroboronic acid(I)BIS(NORBORNADIENE)RHODIUM(I) TETRAFLUOR&Bis(Norbornadiene)Rh(I) TetrafluoroborateBis(norbornadiene)(tetrafluoroborato)rhodium

Rh(nbd)2BF4SC10120C14H16BF4RhC14H16BF4Rh-SCHEMBL695951SCHEMBL29364466Bis[|C-(2,5-norbornadiene)]rhodium(I) TetrafluoroborateAKOS025295231

Datenbank-Bezeichner

CAS: 36620-11-8
PubChem CID: 10915722
DTXSID: DTXSID30448239
EC Number: 625-230-4

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA): 0 Å²
H-Brücken-Donoren: 0
H-Brücken-Akzeptoren: 5
Frei drehbare Bindungen: 0
Schwere Atome: 20
Formalladung: -1
Komplexität: 122

Physikochemische Eigenschaften

Schmelzpunkt: 209 · 209-211 °C
storage temp.: -20 °C · Inert atmosphere,Store in freezer, under -20°C
Aggregatzustand: Powder
Farbe: Red
Wasserlöslichkeit: Fairly soluble in dichloromethane. Insoluble in water.
InChI: InChI=1S/2C7H4.BF4.Rh/c2*1-2-7-4-3-6(1)5-7;2-1(3,4)5;/h2*6-7H,5H2;;/q;;-1;+1
InChIKey: NMZDXSXETNAOPO-UHFFFAOYSA-M
SMILES: [B+3]([F-])([F-])([F-])[F-].[Rh+]123456(C7C8CC(C1=C28)C3=7)C1C2CC(C4=C52)C6=1

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H228 (33.8%): Flammable solid [Danger Flammable solids]

P210, P234, P235, P240, P241, P260, P261, P264, P264+P265, P270, P271, P273, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P321, P330, P332+P317, P337+P317, P362+P364, P363, P370+P378, P390, P403, P405, P406, P410, P411, P420, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 71 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Hazard Classes and CategoriesFlam. Sol. 1 (33.8%)

Sicherheitsdaten

wgk: 3
tsca: No
ridadr: 1325
hs_code: 28439000
risk_code: 11-34
hazard_code: F,C
safety_code: 16-45-36/37/39-26
hazard_class: 8
packing_group: II
Speicherklasse: 8A - Combustible corrosive hazardous materials
Hazard Classifications: Eye Dam. 1Skin Corr. 1B

Chemie und Industrie

Anwendungen · 1 Eintrag

VerwendenBis{P,P'-1,5-diphenyl-3,7-bis[(4-hydrogenphosphonate)phenyl]-1,5,3,7-diazadiphosphocine} nickel(II) bromide (hydrogen bromide adduct) can be used as Synthetic nickel catalyst used for photocatalytic reduction of aqueous protons to hydrogen and catalyst containing phosphonate anchor groups for immobilation on metal oxide semiconductor surfaces, enabling light-driven hydrogen evolution.