Grundinformationen
- Standard-SMILES
CC1CNCC(C)O1- InChIKey
HNVIQLPOGUDBSU-UHFFFAOYSA-N- Summenformel
- C6H13NO
- Durchschnittliche Molmasse
- 115,17 g/mol
- Monoisotopische Masse
- 115,09971404
Überblick
2,6-dimethyl morpholine is a clear liquid. (NTP, 1992)
Namen und Bezeichner
- Bevorzugter Name
- 2,6-Dimethylmorpholine
- IUPAC
- 2,6-dimethylmorpholine
- Lokaler Name
- 2,6-Dimethylmorpholin
- Englischer Name
- Dimethylmorpholine
- Summenformel
- C6H13NO
- Molmasse
- 115.17
Namen und Synonyme
Weitere Namen anzeigen
Datenbank-Bezeichner
- CAS
141-91-3- PubChem CID
- 110862
- DTXSID
DTXSID6022002- EC Number
- 205-509-3
- Nikkaji
- J34.694B
Eigenschaften
Berechnete Struktureigenschaften
- XLogP
- 0,3
- Polarare Oberfläche (TPSA)
- 21,3 Ų
- H-Brücken-Donoren
- 1
- H-Brücken-Akzeptoren
- 2
- Frei drehbare Bindungen
- 0
- Schwere Atome
- 8
- Formalladung
- 0
- Komplexität
- 66,9
Experimentelle und physikochemische Eigenschaften
Density
0.9346 at 68 °F (NTP, 1992) - Less dense than water; will float
0.9346 @ 20 °C/20 °C
Solubility
greater than or equal to 0.1 mg/mL at 66 °F (NTP, 1992)
SOL IN ALL PROPORTIONS WITH WATER, ALCOHOL, BENZENE, PETROLEUM ETHER; SOL IN ACETONE
Flash Point
112 °F (NTP, 1992)
112 °F (44 °C) OC
Boiling Point
297 °F at 760 mmHg (NTP, 1992)
146.6 °C @ 760 MM HG
Melting Point
-121 °F (NTP, 1992)
FREEZING POINT: -85 °C
Physical Description
2,6-dimethyl morpholine is a clear liquid. (NTP, 1992)
Clear liquid; [CAMEO]
Physikochemische Eigenschaften
- Schmelzpunkt
- 85 °C · −85 °C(lit.)
- Siedepunkt
- 147 °C · 147 °C(lit.)
- Dichte
- 0.935 g/mL · 0.935 g/mL at 25 °C(lit.)
- Brechungsindex
- 20 · n20/D 1.446(lit.)
- Flammpunkt
- 120 °F · 120 °F
- Löslichkeit
- Chloroform (Sparingly), Methanol (Slightly)
- Aggregatzustand
- Oil
- pka
- 9.04 · 9.04±0.60(Predicted)
- Farbe
- Colourless
- Wasserlöslichkeit
- 0.01 g/100 · >=0.01 g/100 mL at 19 ºC
- BRN
- 103036 · 103036
- Stabilität
- Stable. Incompatible with oxidizing agents, strong acids. Flammable.
- InChI
- 1S/C6H13NO/c1-5-3-7-4-6(2)8-5/h5-7H,3-4H2,1-2H3
- InChIKey
- HNVIQLPOGUDBSU-UHFFFAOYSA-N
- SMILES
- CC1CNCC(C)O1
- LogP
- -0.1 · -0.100 (est)
- CAS Datenbank
- 141 · 141-91-3(CAS DataBase Reference)
- NIST chemische Informationen
- 2 · Morpholine, 2,6-dimethyl-(141-91-3)
- EPA chemische Informationen
- 2 · 2,6-Dimethylmorpholine (141-91-3)
Sicherheit und Regulatorisches
GHS-Klassifizierung
GHS Classification
Danger
H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]
P210, P233, P240, P241, P242, P243, P260, P262, P264, P264+P265, P270, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P362+P364, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)
Aggregated GHS information provided per 213 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.
Gefahrenhinweise
Regulatory Information
Chemical: Morpholine, 2,6-dimethyl-
Status: Active Update: 17-05-2023 https://echa.europa.eu/registration-dossier/-/registered-dossier/16356
Reactivity Profile
2,6-DIMETHYL MORPHOLINE reacts with oxidizing agents (NTP, 1992). Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
NFPA Hazard Classification
2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury.
2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to produce hazardous atmospheres with air.
0 - Materials that in themselves are normally stable, even under fire conditions.
Sicherheit und Schutzausrüstung
First Aid
EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.
Nonfire Spill Response
SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.
Personal Protective Equipment (PPE)
RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)
Toxikologische Informationen
Sicherheitsdaten
- wgk
- 2
- tsca
- TSCA listed
- ridadr
- UN 1992 3/PG 3
- hs_code
- 29349990
- RTECS-Nr.
- QE1750000
- risk_code
- 10-21-41
- hazard_code
- Xn
- safety_code
- 16-26-36/37/39-45
- hazard_class
- 3
- packing_group
- III
- Speicherklasse
- 3 - Flammable liquids
- Giftige Stoffe Daten
- 141-91-3(Hazardous Substances Data)
- Hazard Classifications
- Acute Tox. 4 DermalAcute Tox. 4 OralFlam. Liq. 3Skin Corr. 1B
Chemie und Industrie
Verwendung und Herstellung
Uses
Used in corrosive inhibitors, stabilizers for chlorinated solvents, floor polishes, rubber additives, germicides, and textile finishing; [Hawley]
Using Disinfectants or Biocides [Category: Clean]
MFR OF CORROSION INHIBITORS; STABILIZER FOR CHLORINATED SOLVENTS; RUBLESS FLOOR POLISHES, RUBBER ACCELERATORS, GERMICIDES, TEXTILE FINISHING AGENTS, /PRC: FUNGICIDES/
Anwendungen
Verwendencis-2,6-Dimethylmorpholine (DMMP) has been used in the preparation of microporous material composed of hybrid T2 and T3 supertetrahedral clusters.
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