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2,6-Dimethylmorpholin

2,6-Dimethylmorpholine

HCID 110862
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Grundinformationen

CAS
141-91-3
Standard-SMILES
CC1CNCC(C)O1
InChIKey
HNVIQLPOGUDBSU-UHFFFAOYSA-N
Summenformel
C6H13NO
Durchschnittliche Molmasse
115,17 g/mol
Monoisotopische Masse
115,09971404

Überblick

2,6-dimethyl morpholine is a clear liquid. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name
2,6-Dimethylmorpholine
IUPAC
2,6-dimethylmorpholine
Lokaler Name
2,6-Dimethylmorpholin
Englischer Name
Dimethylmorpholine
Summenformel
C6H13NO
Molmasse
115.17

Namen und Synonyme

2,6-Dimethylmorpholine141-91-3Morpholine, 2,6-dimethyl-2,6-DIMETHYL MORPHOLINEDTXSID60220022,6-Dimethyl-2,3,5,6-tetrahydro-4H-1,4-oxazineDTXCID002002S5Z1B0318KNSC-60704RefChem:83327205-509-32,6-Dimethyl-Morpholine
Weitere Namen anzeigen
AKOS BBS-00004469Dimethylmorpholine2,6-dimethymorpholine*Dodemorph Impurity 92,6-dimethyl-morpholin2，6-Dimethyl morphalineMorpholine,2,6-dimethyl-
2,6-Dimethylmorfolinfenpropimorph TP2MFCD00005973Dodemorph metabolite2,6-Dimethylmorpholine, cis + trans2,6-Dimethylmorpholine,c&tWLN: T6M DOTJ C1 E14-27-00-00674 (Beilstein Handbook Reference)

Datenbank-Bezeichner

CAS
141-91-3
PubChem CID
110862
DTXSID
DTXSID6022002
EC Number
205-509-3
Nikkaji
J34.694B

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

XLogP
0,3
Polarare Oberfläche (TPSA)
21,3 Ų
H-Brücken-Donoren
1
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
0
Schwere Atome
8
Formalladung
0
Komplexität
66,9

Experimentelle und physikochemische Eigenschaften

Chemical ClassesNitrogen Compounds -> Morpholines
SpringerMaterials PropertiesChemical shift
PesticidesEnvironmental transformation -> Pesticide transformation products (metabolite, successor)
Density · 2 Einträge

0.9346 at 68 °F (NTP, 1992) - Less dense than water; will float

0.9346 @ 20 °C/20 °C

Color/FormLIQUID
Solubility · 2 Einträge

greater than or equal to 0.1 mg/mL at 66 °F (NTP, 1992)

SOL IN ALL PROPORTIONS WITH WATER, ALCOHOL, BENZENE, PETROLEUM ETHER; SOL IN ACETONE

Flash Point · 2 Einträge

112 °F (NTP, 1992)

112 °F (44 °C) OC

Boiling Point · 2 Einträge

297 °F at 760 mmHg (NTP, 1992)

146.6 °C @ 760 MM HG

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Danger

H226 (100%): Flammable liquid and vapor [Warning Flammable liquids]

P210, P233, P240, P241, P242, P243, P260, P262, P264, P264+P265, P270, P280, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P303+P361+P353, P304+P340, P305+P354+P338, P316, P317, P321, P330, P361+P364, P362+P364, P363, P370+P378, P403+P235, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 213 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information · 2 Einträge

Chemical: Morpholine, 2,6-dimethyl-

REACH registered substance: 2,6-dimethylmorpholine (EC: 205-509-3)

DOT LabelFlammable Liquid Poison
Fire HazardsThis chemical is combustible. (NTP, 1992)
Fire PotentialMODERATE FIRE RISK
Health HazardsSYMPTOMS: Symptoms of exposure to this chemical may include local irritation of the eyes and skin.
Hazards SummaryExternal application to rabbit eyes scored 7 on a scale of 1-10 (10 being most severe); Emergency treatment: Morpholine; [HSDB] A mild skin and severe eye irritant; [RTECS] See Morpholine.
Reactive GroupAmines, Phosphines, and Pyridines
Reactivity AlertsHighly Flammable

Chemie und Industrie

Verwendung und Herstellung

Uses · 3 Einträge

Used in corrosive inhibitors, stabilizers for chlorinated solvents, floor polishes, rubber additives, germicides, and textile finishing; [Hawley]

Using Disinfectants or Biocides [Category: Clean]

MFR OF CORROSION INHIBITORS; STABILIZER FOR CHLORINATED SOLVENTS; RUBLESS FLOOR POLISHES, RUBBER ACCELERATORS, GERMICIDES, TEXTILE FINISHING AGENTS, /PRC: FUNGICIDES/

Use ClassificationEnvironmental transformation -> Pesticide transformation products (metabolite, successor)
General Manufacturing InformationMorpholine, 2,6-dimethyl-: ACTIVE

Anwendungen

Verwendencis-2,6-Dimethylmorpholine (DMMP) has been used in the preparation of microporous material composed of hybrid T2 and T3 supertetrahedral clusters.

Vor- und nachgelagerte Produkte

Nachgelagerte Produkte

4-[3-[4-(1,1-Dimethylethyl)phenyl]-2-methylpropyl]-2,6-dimethylmorpholinAmorolfineFenpropimorphN-nitroso-2,6-dimethylmorpholine4-Morpholinesulfonamide,2,6-dimethyl-(7CI,8CI,9CI)4-(2,6-DIMETHYLMORPHOLINO)ANILINE, TECH

Zugehörige Reaktionen

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HRID 12247als Eduktuspto-grants-2010_06
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Reaktionsgleichung von HRID 94948
HRID 94948als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
Reaktionsgleichung von HRID 101963
HRID 101963als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
Reaktionsgleichung von HRID 104125
HRID 104125als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
Reaktionsgleichung von HRID 104477
HRID 104477als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
Reaktionsgleichung von HRID 107001
HRID 107001als EduktTraining data from https://doi.org/10.1039/C8SC04228D (2/10)
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Melting Point · 2 Einträge

-121 °F (NTP, 1992)

FREEZING POINT: -85 °C

Vapor Density4 (NTP, 1992) - Heavier than air; will sink (Relative to Air)
Refractive IndexINDEX OF REFRACTION: 1.4460 @ 20 °C/D
Physical Description · 2 Einträge

2,6-dimethyl morpholine is a clear liquid. (NTP, 1992)

Clear liquid; [CAMEO]

Physikochemische Eigenschaften

Schmelzpunkt
85 °C · −85 °C(lit.)
Siedepunkt
147 °C · 147 °C(lit.)
Dichte
0.935 g/mL · 0.935 g/mL at 25 °C(lit.)
Brechungsindex
20 · n20/D 1.446(lit.)
Flammpunkt
120 °F · 120 °F
Löslichkeit
Chloroform (Sparingly), Methanol (Slightly)
Aggregatzustand
Oil
pka
9.04 · 9.04±0.60(Predicted)
Farbe
Colourless
Wasserlöslichkeit
0.01 g/100 · >=0.01 g/100 mL at 19 ºC
BRN
103036 · 103036
Stabilität
Stable. Incompatible with oxidizing agents, strong acids. Flammable.
InChI
1S/C6H13NO/c1-5-3-7-4-6(2)8-5/h5-7H,3-4H2,1-2H3
InChIKey
HNVIQLPOGUDBSU-UHFFFAOYSA-N
SMILES
CC1CNCC(C)O1
LogP
-0.1 · -0.100 (est)
CAS Datenbank
141 · 141-91-3(CAS DataBase Reference)
NIST chemische Informationen
2 · Morpholine, 2,6-dimethyl-(141-91-3)
EPA chemische Informationen
2 · 2,6-Dimethylmorpholine (141-91-3)
Reactivity Profile · 1 Eintrag

2,6-DIMETHYL MORPHOLINE reacts with oxidizing agents (NTP, 1992). Neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.

Air and Water ReactionsHighly flammable. Very slightly water soluble.
NFPA Hazard Classification · 3 Einträge

2 - Materials that, under emergency conditions, can cause temporary incapacitation or residual injury.

2 - Materials that must be moderately heated or exposed to relatively high ambient temperatures before ignition can occur. Materials would not under normal conditions form hazardous atmospheres with air, but under high ambient temperatures or under moderate heating could release vapor in sufficient quantities to produce hazardous atmospheres with air.

0 - Materials that in themselves are normally stable, even under fire conditions.

Hazard Classes and CategoriesFlam. Liq. 3 (100%)

Sicherheit und Schutzausrüstung

Fire FightingFires involving this material should be controlled using a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Fire Fighting Procedures"ALCOHOL" FOAM
Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If you should spill this chemical, use absorbent paper to pick up all liquid spill material. Seal the absorbent paper, as well as any of your clothing which may be contaminated, in a vapor-tight plastic bag for eventual disposal. Wash any surfaces you may have contaminated with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 131 [Flammable Liquids - Toxic]:
Personal Protective Equipment (PPE) · 1 Eintrag

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Toxikologische Informationen

Non-Human Toxicity Excerpts2,6-DIMETHYLMORPHOLINE RATED 7 ON RABBIT EYES. MOST SEVERE INJURIES HAVE BEEN RATED 10.
Toxicity DataLC (rat) > 4,000 ppm/4h

Sicherheitsdaten

wgk
2
tsca
TSCA listed
ridadr
UN 1992 3/PG 3
hs_code
29349990
RTECS-Nr.
QE1750000
risk_code
10-21-41
hazard_code
Xn
safety_code
16-26-36/37/39-45
hazard_class
3
packing_group
III
Speicherklasse
3 - Flammable liquids
Giftige Stoffe Daten
141-91-3(Hazardous Substances Data)
Hazard Classifications
Acute Tox. 4 DermalAcute Tox. 4 OralFlam. Liq. 3Skin Corr. 1B