(2,2-Dimethyl-1,3-dioxolan-4-yl)methylmethacrylat
GMAK · IPGMA · Bisomer IPGMA · IPGMA cas 7098-80-8 · Solketal methacrylate · Solketal methacrylate 95% · Bisomer IPGMA cas 7098-80-8 · Solketal methacrylate (IPGMA)
Identifikatoren & physikalische Daten
| CAS No. | 7098-80-8 |
|---|---|
| Summenformel | C10H16O4 |
| Durchschnittliche Molmasse | 200,23 g/mol |
| Monoisotopische Masse | 200,10485899 g/mol |
| SMILES | C=C(C)C(=O)OCC1COC(C)(C)O1 |
| InChIKey | JPFPDGRVRGETED-UHFFFAOYSA-N |
| PubChem CID | 110950 |
| EC No. | 230-408-6 |
| DTXSID | DTXSID40884285 |
| Lokaler Name | (2,2-Dimethyl-1,3-dioxolan-4-yl)methylmethacrylat |
Chemische & physikalische Eigenschaften
| XLogP | 1,3 |
|---|---|
| Polarare Oberfläche (TPSA) | 44,8 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 4 |
| Frei drehbare Bindungen | 4 |
| Schwere Atome | 14 |
| Formalladung | 0 |
| Komplexität | 245 |
| Siedepunkt | 275℃ |
| Dichte | 1.028 |
| Dampfdruck | 4Pa at 20℃ |
| Brechungsindex | n20/D1.438 |
| Flammpunkt | 116℃ |
| Lagerbedingungen | -20°C |
| Aggregatzustand | liquid |
| Kosmetik-Inhaltsstoffe Funktionen | NAIL CONDITIONINGFILM FORMINGBINDING |
| InChI | InChI=1S/C10H16O4/c1-7(2)9(11)12-5-8-6-13-10(3,4)14-8/h8H,1,5-6H2,2-4H3 |
| InChIKey | JPFPDGRVRGETED-UHFFFAOYSA-N |
| SMILES | C(OCC1COC(C)(C)O1)(=O)C(C)=C |
| EPA chemische Informationen | (2,2-Dimethyl-1,3-dioxolan-4-yl)methyl methacrylate (7098-80-8) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH226 (21.7%): Flammable liquid and vapor [Warning Flammable liquids]P210, P233, P240, P241, P242, P243, P261, P264, P264+P265, P271, P280, P302+P352, P303+P361+P353, P304+P340, P305+P351+P338, P305+P354+P338, P317, P319, P321, P332+P317, P337+P317, P362+P364, P370+P378, P403+P233, P403+P235, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 180 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Status: Active Update: 21-10-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/34115 |
| Hazard Classes and Categories | Flam. Liq. 3 (21.7%) |
| Wassergefährdungsklasse (WGK) | 2 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 1992 6.1(3) / PGIII |
| R-Sätze (R) | 10-37/38-40-41 |
| Gefahrensymbole | Xn |
| Sicherheitshinweise (S) | 26-36/37/39 |
| Lagerklasse | 3 - Flammable liquids |
| Gefahrenklasse | Carc. 2Eye Dam. 1Flam. Liq. 3Skin Irrit. 2STOT SE 3 |
Anwendungen & Verwendung
Verwenden
Solketal methacrylate is an acrylate monomer with used in adhesives.
Herstellung & Synthese
synthetische
Solketal methacrylate (SMA) (the precursor monomer for GMA), synthesized by reacting solketal with methacryloyl chloride, was polymerized under typical ATRP conditions with THF as the solvent at 40 °C, employing the synthesized POSS based initiator, and CuCl/N,N,N,N,N-pentamethyldiethylenetriamine as the catalyst system.Chemical scheme for the production of Solketal MethacrylateAmphiphilic tadpole-shaped POSS-poly(glycerol methacrylate) hybrid polymers: synthesis and self-assembly.Source: Journal of Polymer Research . Jan2019, Vol. 26 Issue 1, p1-1. 1p.Author(s): Ullah, Asad; Shah, Syed Mujtaba; Hussain, Hazrat