(S)-(-)-alpha,alpha-Diphenyl-2-pyrrolidinemethanol Trimethylsilyl Ether

HCID 11198150CAS 848821-58-9
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Grundinformationen

Standard-SMILES
C[Si](C)(C)OC(c1ccccc1)(c1ccccc1)[C@@H]1CCCN1
InChIKey
RSUHWMSTWSSNOW-IBGZPJMESA-N
Summenformel
C20H27NOSi
Durchschnittliche Molmasse
325,5 g/mol
Monoisotopische Masse
325,18619102

Namen und Bezeichner

Bevorzugter Name
(S)-(-)-alpha,alpha-Diphenyl-2-pyrrolidinemethanol Trimethylsilyl Ether
IUPAC
[diphenyl-[(2S)-pyrrolidin-2-yl]methoxy]-trimethylsilane
Englischer Name
(S)-(-)-alpha,alpha-Diphenyl-2-pyrrolidinyl methyltms ether
Summenformel
C20H27NOSi
Molmasse
325.52

Namen und Synonyme

(S)-(-)-alpha,alpha-Diphenyl-2-pyrrolidinemethanol trimethylsilyl etherRefChem:407704628-584-8848821-58-9(S)-2-(Diphenyl((trimethylsilyl)oxy)methyl)pyrrolidine(2S)-2-{diphenyl[(trimethylsilyl)oxy]methyl}pyrrolidine[diphenyl-[(2S)-pyrrolidin-2-yl]methoxy]-trimethyl-silaneMFCD08690083[diphenyl-[(2S)-pyrrolidin-2-yl]methoxy]-trimethylsilaneC20H27NOSi(S)-(-)-[(Diphenyl)trimethylsiloxymethyl]pyrrolidinePyrrolidine, 2-[diphenyl[(trimethylsilyl)oxy]methyl]-, (2S)-
Weitere Namen anzeigen
S-Diphenylprolinol trimethyl silyl ether(2s)-2-[diphenyl[(trimethylsilyl)oxy]methyl]pyrrolidine(S)-Diphenylprolinol Trimethyl Silyl Ether,99%e.e.(S)-(-)-α,α-Diphenyl-2-pyrrolidoneMethanoe triMethylsilys ether(S)-(–)-α,α-DiphenyL(S)-Hayashi-Jorgensen CatalystJorgenson-Hayashi organocatalyst[(DIPHENYL)TRIMETHYLSILOXYMETHYL]PYRROLIDINE
RSUHWMSTWSSNOW-IBGZPJMESA-NSCHEMBL2574515DTXSID50458512CS-B0740AKOS015840590s25143AS-10194FD139746

Datenbank-Bezeichner

CAS
848821-58-9
PubChem CID
11198150
DTXSID
DTXSID50458512
EC Number
628-584-8
Nikkaji
J2.212.714D

Eigenschaften

Berechnete Struktureigenschaften

Polarare Oberfläche (TPSA)
21,3 Ų
H-Brücken-Donoren
1
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
5
Schwere Atome
23

Physikochemische Eigenschaften

Siedepunkt
412.7 · 412.7±35.0 °C(Predicted)
Dichte
1.0459 g/mL · 1.0459 g/mL at 25 °C
Brechungsindex
20 · n20/D 1.5513
Flammpunkt
110 °C · 110 °C
storage temp.
2 · 2-8°C
pka
10.01 · 10.01±0.10(Predicted)

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]；H319 (100%): Causes serious eye irritation [Warning Serious eye damage/eye irritation]；H335 (97.6%): May cause respiratory irritation [Warning Specific target organ toxicity, single exposure; Respiratory tract irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 41 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Hazard Classes and CategoriesSkin Irrit. 2 (100%)；Eye Irrit. 2 (100%)；STOT SE 3 (97.6%)

Sicherheitsdaten

wgk
3
tsca
No
ridadr
UN1294 - class 3 - PG 2 - Toluene, solution
hs_code
29339900
risk_code
36/37/38-67-65-48/20-38-11-63
hazard_code
Xi,Xn,F

Chemie und Industrie

Anwendungen

VerwendenOrganocatalyst for 3-component reactions, and Robinson annulation of α,β-unsaturated aldehydes.

Vor- und nachgelagerte Produkte

Anbieter50 Anbieter

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
江苏吉泰肽业科技有限公司051580855088 18762539991 · [email protected]
陕西缔都新材料有限公司81124267 17392282731 · [email protected]
武汉英诺医药科技有限公司+86-027-59232304 15387063101 · [email protected]
毕佳索（上海毕得医药科技股份有限公司）400-6005915 · [email protected]

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