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Tris[2-(2-methoxyethoxy)ethyl]amin
TDA · TDA-1 · TRIS(3,6-DIOXAHEPTYL)AMINE · TRIS[2-(2-METHOXYETHOXY)ETHYL]AMINE · Tris(3,6-dioxaheptane-1-yl)amine · 2-(2-METHOXYETHOXY)-N,N-BIS[2-(2-METHOXYETHOXY)ETHYL]ETHANAMINE · DYPR0394 · TRIS(DIOXA-3,6-HEPTYL)AMINE
![Molekülstruktur von Tris[2-(2-methoxyethoxy)ethyl]amin](/img/chemical/112414.png)
Identifikatoren & physikalische Daten
| CAS No. | 70384-51-9 |
|---|---|
| Summenformel | C15H33NO6 |
| Durchschnittliche Molmasse | 323,43 g/mol |
| Monoisotopische Masse | 323,23078778 g/mol |
| SMILES | COCCOCCN(CCOCCOC)CCOCCOC |
| InChIKey | XGLVDUUYFKXKPL-UHFFFAOYSA-N |
| PubChem CID | 112414 |
| EC No. | 274-590-5 |
| DTXSID | DTXSID5072064 |
| Lokaler Name | Tris[2-(2-methoxyethoxy)ethyl]amin |
Chemische & physikalische Eigenschaften
| XLogP | -0,6 |
|---|---|
| Polarare Oberfläche (TPSA) | 58,6 |
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 7 |
| Frei drehbare Bindungen | 18 |
| Schwere Atome | 22 |
| Formalladung | 0 |
| Komplexität | 175 |
| Schmelzpunkt | <-100°C |
| Siedepunkt | 330 °C |
| Dichte | 1.011 g/mL at 25 °C(lit.) |
| Brechungsindex | n20/D 1.4486(lit.) |
| Flammpunkt | >230 °F |
| Lagerbedingungen | Inert atmosphere,Room Temperature |
| Aggregatzustand | Liquid |
| pKa (Säurekonstante) | 6.92±0.50(Predicted) |
| Farbe | Clear pale yellow to brown |
| Löslichkeit | miscible |
| BRN | 2369296 |
| InChI | 1S/C15H33NO6/c1-17-10-13-20-7-4-16(5-8-21-14-11-18-2)6-9-22-15-12-19-3/h4-15H2,1-3H3 |
| InChIKey | XGLVDUUYFKXKPL-UHFFFAOYSA-N |
| SMILES | COCCOCCN(CCOCCOC)CCOCCOC |
| CAS Datenbank | 70384-51-9(CAS DataBase Reference) |
| NIST chemische Informationen | Tris[2-(2-methoxyethoxy)ethyl]amine(70384-51-9) |
| EPA chemische Informationen | Ethanamine, 2-(2-methoxyethoxy)-N,N-bis[2-(2-methoxyethoxy)ethyl]- (70384-51-9) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH314 (92.5%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]P260, P264, P264+P265, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P317, P321, P363, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 53 reports by companies from 5 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Regulatorische Informationen | Chemical: Ethanamine, 2-(2-methoxyethoxy)-N,N-bis[2-(2-methoxyethoxy)ethyl]-PMN - indicates a commenced PMN (Pre-Manufacture Notices) substance.Ethanamine, 2-(2-methoxyethoxy)-N,N-bis2-(2-methoxyethoxy)ethyl-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right. |
| Hazard Classes and Categories | Skin Corr. 1C (92.5%) |
| F | 3-9-23 |
| Wassergefährdungsklasse (WGK) | 3 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 2735 8/PG 3 |
| Zollcode | 29221980 |
| R-Sätze (R) | 34 |
| Gefahrensymbole | C |
| Sicherheitshinweise (S) | 26-36/37/39-45 |
| Gefahrenklasse | 8Eye Dam. 1Skin Corr. 1C |
| Verpackungsgruppe | III |
| Lagerklasse | 8A - Combustible corrosive hazardous materials |
Anwendungen & Verwendung
Verwenden
Tris(2-(2-methoxyethoxy)ethyl)amine was used:in oxidation of arylmethanols under phase-transfer conditions;as cryptand during phase-transfer glycosylation of 2-amino-4-methoxy-7H-pyrrolo[2,3-d]pyrimidine;as phase-transfer catalyst in synthesis of 1,3-dideaza-2′-deoxyadenosine and related benzimidazole 2′-deoxyribonucleosides.