| GHS-Einstufung | DangerH301 (100%): Toxic if swallowed [Danger Acute toxicity, oral]P260, P261, P262, P264, P270, P271, P273, P280, P301+P316, P302+P352, P304+P340, P316, P319, P321, P330, P361+P364, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 47 reports by companies from 6 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.H311: Toxic in contact with skin [Danger Acute toxicity, dermal] |
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| Regulatorische Informationen | Chemical: Benzenamine, 2-methyl-6-nitro-Status: No longer Valid Update: 25-04-2018 https://echa.europa.eu/registration-dossier/-/registered-dossier/245956-Nitro-o-toluidine: Does not have an individual approval but may be used under an appropriate group standard |
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| Weitere Sicherheitsinformationen | IMAP assessments - Benzenamine, 2-methyl-6-nitro-: Human health tier II assessment |
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| DOT-Kennzeichnung | Poison |
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| Brandgefahren | Flash point data for this compound are not available, but it is probably combustible. (NTP, 1992) |
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| Gesundheitsgefahren | Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: |
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| Gefahrenübersicht | A mild skin and eye irritant in rabbits at 3% concentration in 1,2-propanediolNo evidence of skin sensitization in guinea pigsHepatotoxicity observed in 28-day oral studies of ratsNo evidence of embryotoxicity or teratogenicity in rats[EC: SCCNFP] May cause irritationMay induce methemoglobinemiaToxic by ingestion, inhalation, and skin absorptionTargets the blood[Sigma-Aldrich MSDS] See 2-Nitroaniline. |
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| Reaktive Gruppe | Nitro, Nitroso, Nitrate, and Nitrite Compounds, Organic |
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| Reactivity Profile | 2-METHYL-6-NITROANILINE is incompatible with acids, acid chlorides, acid anhydrides, chloroformates, and strong oxidizers. (NTP, 1992) |
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| Air and Water Reactions | This chemical is sensitive to prolonged exposure to air. Insoluble in water. |
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| Hazard Classes and Categories | Acute Tox. 3 (100%)Acute toxicity - category 3 |
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| Brandbekämpfung | Fires involving this material can be controlled using a carbon dioxide, dry chemical or Halon extinguisher. (NTP, 1992) |
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| Erste Hilfe | EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. |
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| Freisetung ohne Brand | SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned. |
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| Isolation and Evacuation | Excerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]: |
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| Personal Protective Equipment (PPE) | RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992) |
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| Unerwünschte Wirkungen | Occupational hepatotoxin - Secondary hepatotoxins: the potential for toxic effect in the occupational setting is based on cases of poisoning by human ingestion or animal experimentation. |
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| F | 10 |
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| Wassergefährdungsklasse (WGK) | 3 |
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| UN-Transportnummer | UN 2660 6.1/PG 3 |
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| Zollcode | 29214300 |
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| R-Sätze (R) | 23/24/25-33-51/53 |
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| Gefahrensymbole | T,N,Xi |
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| hazard_note | Toxic |
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| Sicherheitshinweise (S) | 28-36/37-45-61-28A |
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| Gefahrenklasse | IRRITANTAcute Tox. 3 DermalAcute Tox. 3 InhalationAcute Tox. 3 OralAquatic Acute 1Aquatic Chronic 2STOT RE 2 |
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| Verpackungsgruppe | Ⅲ |
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| Lagerklasse | 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects |
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