Rhodium chloride trihydrate

HCID 11459718
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Grundinformationen

CAS
13569-65-8
Standard-SMILES
O.O.O.[Cl][Rh]([Cl])[Cl]
InChIKey
TYLYVJBCMQFRCB-UHFFFAOYSA-K
Summenformel
Cl3H6O3Rh
Durchschnittliche Molmasse
263,31 g/mol
Monoisotopische Masse
261,84375

Namen und Bezeichner

Bevorzugter Name
Rhodium chloride trihydrate
IUPAC
trichlororhodium;trihydrate

Namen und Synonyme

Rhodium(III) chloride trihydrateRhodium chloride trihydrateRefChem:883009Rhodium (III) chloride, trihydrateRhodium (III) chloride, hydrateRhodium chloride (RhCl3), trihydrateRhodium chloride, trihydrate13569-65-8Rhodium (III) chloride trihydratetrichlororhodium;trihydrateH6Cl3O3RhSCHEMBL16444
Weitere Namen anzeigen
rhodium(III)-chloride trihydrateDTXSID90929110Trichloridorhodium--water (1/3)AKOS015964084AC-18130Rhodium(3+) chloride--water (1/3/3)

Datenbank-Bezeichner

CAS
13569-65-8、13876-89-6
PubChem CID
11459718
DTXSID
DTXSID90929110

Eigenschaften

Berechnete StruktureigenschaftenWird ergänzt

Polarare Oberfläche (TPSA)
3 Ų
H-Brücken-Donoren
3
H-Brücken-Akzeptoren
3
Frei drehbare Bindungen
0
Schwere Atome
7

Experimentelle und physikochemische Eigenschaften

DensityRelative density (water = 1): >1
SolubilitySolubility in water: soluble
Decomposition100 °C
Physical Description · 2 Einträge

Red deliquescent solid; [ICSC] Dark red odorless crystals; Soluble in water; [BASF MSDS]

RED DELIQUESCENT POWDER.

Physikochemische Eigenschaften

Melting point
100 °C · 100 °C (decomp)
Density
1 g/cm3 · 1 g/cm3
storage temp.
Sealed in dry,Room Temperature
Appearance
Reddish brown to black Solid
InChI
InChI=1S/3ClH.H2O.Rh/h3*1H;1H2;/q;;;;+3/p-3
InChIKey
HSSMNYDDDSNUKH-UHFFFAOYSA-K

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

Danger

H290 (97.2%): May be corrosive to metals [Warning Corrosive to Metals]；H302 (100%): Harmful if swallowed [Warning Acute toxicity, oral]；H318 (100%): Causes serious eye damage [Danger Serious eye damage/eye irritation]；H341 (96.3%): Suspected of causing genetic defects [Warning Germ cell mutagenicity]；H400 (95.4%): Very toxic to aquatic life [Warning Hazardous to the aquatic environment, acute hazard]；H410 (95.4%): Very toxic to aquatic life with long lasting effects [Warning Hazardous to the aquatic environment, long-term hazard]

P203, P234, P264, P264+P265, P270, P273, P280, P301+P317, P305+P354+P338, P317, P318, P330, P390, P391, P405, P406, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 109 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.；Information may vary between notifications depending on impurities, additives, and other factors. The percentage value in parenthesis indicates the notified classification ratio from companies that provide hazard codes. Only hazard codes with percentage values above 10% are shown. For more detailed information, please visit ECHA C&L website.

Gefahrenhinweise

Regulatory InformationRhodium chloride (RhCl3), trihydrate: Does not have an individual approval but may be used under an appropriate group standard
Fire HazardsNot combustible. Gives off irritating or toxic fumes (or gases) in a fire. See Chemical dangers
Hazards SummaryIntraperitoneal LD50 (mouse) = 369 mg/kg; [RTECS] No listed effects of short-term or long-term exposure; [ICSC] An irritant that may cause burns; May cause skin sensitization; [BASF MSDS] See Rhodium chloride.
UN ClassificationUN Hazard Class: 8; UN Pack Group: III
Chemical DangersDecomposes on heating. This produces toxic and corrosive fumes including hydrogen chloride (see ICSC 0163). This generates toxic hazard. Reacts violently with iron pentacarbonyl and zinc. This generates explosion hazard.
Packaging and LabellingUnbreakable packaging. Put breakable packaging into closed unbreakable container. Do not transport with food and feedstuffs.

Sicherheit und Schutzausrüstung

Fire FightingIn case of fire in the surroundings, use appropriate extinguishing media.
First Aid Measures · 4 Einträge

Fresh air. Seek medical attention if you feel unwell.

Remove contaminated clothes. Rinse skin with plenty of water or shower.

First rinse with plenty of water for several minutes (remove contact lenses if easily possible), then refer for medical attention.

Rinse mouth. Seek medical attention if you feel unwell.

Safe StorageSeparated from incompatible materials. Well closed. Dry. See Chemical Dangers.
Spillage Disposal · 1 Eintrag

Personal protection: particulate filter respirator adapted to the airborne concentration of the substance. Sweep spilled substance into sealable containers. If appropriate, moisten first to prevent dusting. Carefully collect remainder. Then store and dispose of according to local regulations.

Eye PreventionWear safety spectacles.
Inhalation RiskA harmful concentration of airborne particles can be reached quickly , especially if powdered.

Toxikologische Informationen

Exposure RoutesThe substance can be absorbed into the body by inhalation of its aerosol and by ingestion.
Signs and Symptoms · 2 Einträge

Cough.

Redness. Pain.

Regulatorische Informationen

Regulatory InformationRhodium chloride (RhCl3), trihydrate: Does not have an individual approval but may be used under an appropriate group standard

Chemie und Industrie

Verwendung und Herstellung

UsesUsed as a catalyst for the conversion of methane to acetic acid; [ExPub: Health Council of the Netherlands]

Anbieter19 Anbieter

韶远科技（上海）有限公司021-50795510 4000665055 · [email protected]
郑州研德生物科技有限公司0371-63682289 15538176268 · [email protected]
上海麦克林生化科技股份有限公司15221275939 15221275939 · [email protected]
杭州杰恒化工有限公司0571-87396432 · [email protected]
池州凯隆进出口贸易有限公司[email protected]

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