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(1R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl][1,1′-binaphthalene]-2,2′-diol
SF120022 · (S)-(-)-3,3'-BIS(3,5-BIS(TRIFLUOROMETHY& · (S)-3,3-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1-binaphthol · (S)-3,3'-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1'-bi-2-napthol · (S)-3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-bi-2-naphthol · (S)-(-)-3-3μ-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1μ-bi-2-naphthol · 3,3'-Bis[3,5-bis(trifluoromethyl)phenyl]-1,1'-binaphthalene-2,2'- diol · S-3,3’-bis(3,5-bis(trifluoromethyl)phenyl)-1,1’-bi-2-naphthalenephenol
![Molekülstruktur von (1R)-3,3′-Bis[3,5-bis(trifluoromethyl)phenyl][1,1′-binaphthalene]-2,2′-diol](/img/chemical/11664821.png)
Identifikatoren & physikalische Daten
| CAS No. | 756491-54-0 |
|---|---|
| Summenformel | C36H18F12O2 |
| Durchschnittliche Molmasse | 710,514 g/mol |
| Monoisotopische Masse | 710,11151846 g/mol |
| SMILES | Oc1c(-c2cc(C(F)(F)F)cc(C(F)(F)F)c2)cc2ccccc2c1-c1c(O)c(-c2cc(C(F)(F)F)cc(C(F)(F)F)c2)cc2ccccc12 |
| InChIKey | PGXMYJSTCAQJBY-UHFFFAOYSA-N |
| PubChem CID | 11664821 |
| EC No. | 623-133-1 |
| DTXSID | DTXSID601144324 |
Chemische & physikalische Eigenschaften
| Schmelzpunkt | 215-219 °C |
|---|---|
| Siedepunkt | 574.7±50.0 °C(Predicted) |
| Dichte | 1.466±0.06 g/cm3(Predicted) |
| Lagerbedingungen | 2-8°C |
| Aggregatzustand | (Powder or Crystals or Solid or Chunks) |
| pKa (Säurekonstante) | 7.62±0.50(Predicted) |
| InChIKey | PGXMYJSTCAQJBY-UHFFFAOYSA-N |
| SMILES | Oc1c(cc2ccccc2c1-c3c(O)c(cc4ccccc34)-c5cc(cc(c5)C(F)(F)F)C(F)(F)F)-c6cc(cc(c6)C(F)(F)F)C(F)(F)F |
Sicherheit & Vorschriften
| Wassergefährdungsklasse (WGK) | 3 |
|---|---|
| Zollcode | 2809200000 |
| R-Sätze (R) | 36 |
| Gefahrensymbole | Xi |
| Sicherheitshinweise (S) | 26 |
| Lagerklasse | 11 - Combustible Solids |
| Gefahrenklasse | Eye Irrit. 2 |
Anwendungen & Verwendung
Verwenden
(S)-(-)-3-3′-Bis(3,5-bis(trifluoromethyl)phenyl)-1,1′-bi-2-naphthol reacts with tin(IV) chloride to form a Sn(IV) aryloxide Lewis acid, which can catalyze asymmetric Diels-Alder reactions.