| GHS-Einstufung | This chemical does not meet GHS hazard criteria for 0.5% (1 of 189) of reports.DangerH302+H312+H332 (75.1%): Harmful if swallowed, in contact with skin or if inhaled [Warning Acute toxicity, oralacute toxicity, dermalacute toxicity, inhalation]P260, P261, P264, P264+P265, P270, P271, P272, P273, P280, P284, P301+P317, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P351+P338, P305+P354+P338, P316, P317, P319, P320, P321, P330, P332+P317, P333+P317, P337+P317, P362+P364, P363, P391, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 189 reports by companies from 9 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
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| Regulatorische Informationen | Chemical: Benzene, 1-chloro-2-(chloromethyl)-Benzene, 1-chloro-2-(chloromethyl)- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Benzene, 1-chloro-2-(chloromethyl)- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)Status: Active Update: 22-06-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/139262-Chlorobenzyl chloride: Does not have an individual approval but may be used under an appropriate group standard |
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| Brandgefahren | Combustible. Gives off irritating or toxic fumes (or gases) in a fire. Above 91 °C explosive vapour/air mixtures may be formed. |
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| Gefahrenübersicht | A skin, eye, and respiratory tract irritantCan be absorbed through skin[ICSC] Reacts slowly with water producing hydrogen chloride[CAMEO] Irritating but not corrosive to skin of rabbitsNo reliable skin sensitization data available[OECD SIDS: Benzene, 1-chloro-2-(chloromethyl)- - 2003] Causes burnsA lachrymatorInhalation may cause corrosive injuries to upper respiratory tract and lungsToxic by inhalationHarmful by ingestion and skin absorption[Alfa Aesar MSDS] See Chlorobenzyl chlorides. |
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| UN-Einstufung | UN Hazard Class: 6.1UN Pack Group: III |
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| Chemical Dangers | Decomposes on burning. This produces hydrogen chloride. |
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| Packaging and Labelling | Do not transport with food and feedstuffs. Marine pollutant. |
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| Hazard Classes and Categories | Acute Tox. 4 (78.8%)Acute toxicity (Oral) - Category 4 |
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| Explosive Limits and Potential | Explosive limits , vol% in air: 2.0-8.6 |
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| Brandbekämpfung | Use foam, water spray, dry powder, carbon dioxide. |
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| Erste-Hilfe-Maßnahmen | Fresh air, rest. Seek medical attention if you feel unwell.Rinse and then wash skin with water and soap. Refer for medical attention if skin irritation occurs.Rinse with plenty of water (remove contact lenses if easily possible).Rinse mouth. Do NOT induce vomiting. Refer for medical attention if you fell unwell. |
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| Sichere Lagerung | Ventilation along the floor. Store only in original container. Store in an area without drain or sewer access. Provision to contain effluent from fire extinguishing. |
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| Expositionsschutz und Persönliche Schutzausrüstung | 5.0 [ppm] |
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| Verschüttetes entsorgen | Personal protection: filter respirator for organic gases and vapours adapted to the airborne concentration of the substance. Do NOT let this chemical enter the environment. Collect leaking liquid in sealable plastic containers. Carefully collect remainder. Then store and dispose of according to local regulations. |
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| Eye Prevention | Wear safety spectacles. |
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| Fire Prevention | NO open flames. Above 91 °C use a closed system and ventilation. |
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| Inhalation Risk | A harmful contamination of the air will be reached rather slowly on evaporation of this substance at 20 °Con spraying or dispersing, however, much faster. |
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| Skin Prevention | Protective gloves. |
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| Ingestion Prevention | Do not eat, drink, or smoke during work. |
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| Inhalation Prevention | Use ventilation or local exhaust. |
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| Effects of Short Term Exposure | The substance is irritating to the eyes, skin and respiratory tract. |
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| Unerwünschte Wirkungen | Dermatotoxin - Skin burns. |
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| Expositionspfade | The substance can be absorbed into the body by inhalation of its aerosol, through the skin and by ingestion. |
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| Signs and Symptoms | Cough.Redness.Redness. Pain.Sore throat. |
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| ICSC Environmental Data | The substance is very toxic to aquatic organisms. It is strongly advised not to let the chemical enter into the environment. |
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| Toxicity Data | LC50 (rat) > 2,800 mg/m3 |
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| F | 19-21 |
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| Wassergefährdungsklasse (WGK) | 3 |
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| TSCA-Inventar-Status | TSCA listed |
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| UN-Transportnummer | UN 2235 6.1/PG 3 |
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| Zollcode | 29036990 |
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| RTECS-Nr. | CZ0195000 |
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| R-Sätze (R) | 34-43-50/53-20/21/22 |
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| Gefahrensymbole | C,N |
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| Sicherheitshinweise (S) | 26-36/37/39-45-29 |
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| Gefahrenklasse | 6.1Acute Tox. 4 DermalAcute Tox. 4 InhalationAcute Tox. 4 OralAquatic Acute 1Aquatic Chronic 1Eye Irrit. 2Skin Irrit. 2Skin Sens. 1STOT SE 3 |
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| Verpackungsgruppe | III |
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| Lagerklasse | 6.1C - Combustible acute toxic Cat.3toxic compounds or compounds which causing chronic effects |
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