m-Phenetidin

3-Ethoxyaniline

HCID 12120CAS 621-33-0

Grundinformationen

Standard-SMILES
CCOc1cccc(N)c1
InChIKey
WEZAHYDFZNTGKE-UHFFFAOYSA-N
Summenformel
C8H11NO
Durchschnittliche Molmasse
137,18 g/mol
Monoisotopische Masse
137,08406397

Überblick

M-phenetidine is a dark red liquid. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name
3-Ethoxyaniline
IUPAC
3-ethoxyaniline
Lokaler Name
m-Phenetidin
Englischer Name
3-Ethoxyaniline
Summenformel
C8H11NO
Molmasse
137.18

Namen und Synonyme

3-ETHOXYANILINEm-Phenetidine621-33-03-EthoxybenzenamineBenzenamine, 3-ethoxy-m-Ethoxyaniline(3-ethoxyphenyl)amineCCRIS 4696DTXSID00258623-PhenetidineNSC 9817EINECS 210-680-2
Weitere Namen anzeigen
AKOS BBB/405N-phenetidineMETA-PHENETIDINE3'-AMINOPHENETOLm-Aminophenetole
XE9KKL972RBRN 0971028AI3-15397PHENETIDINE, M-NSC-9817M-ETHOXYPHENYLAMINEDTXCID7058623-AMINOPHENYL ETHYL ETHER

Datenbank-Bezeichner

CAS
621-33-0
PubChem CID
12120
DTXSID
DTXSID0025862
ChEMBL
CHEMBL1466168
UNII
XE9KKL972R
EC Number
210-680-2
Nikkaji
J101.236C

Eigenschaften

Berechnete Struktureigenschaften

XLogP
1,3
Polarare Oberfläche (TPSA)
35,3 Ų
H-Brücken-Donoren
1
H-Brücken-Akzeptoren
2
Frei drehbare Bindungen
2
Schwere Atome
10

Experimentelle und physikochemische Eigenschaften

Chemical ClassesNitrogen Compounds -> Amines, Aromatic
SpringerMaterials PropertiesDiamagnetic susceptibility
Density1.032 (NTP, 1992) - Denser than water; will sink
Solubility1 to 5 mg/mL at 68 °F (NTP, 1992)
Flash Pointgreater than 235 °F (NTP, 1992)
Boiling Point478 °F at 760 mmHg (NTP, 1992)

Physikochemische Eigenschaften

Schmelzpunkt
204 °C · 204 °C
Siedepunkt
248 °C · 248 °C(lit.)
Dichte
1.032 g/mL · 1.032 g/mL at 25 °C(lit.)
Brechungsindex
20 · n20/D 1.566(lit.)
Flammpunkt
230 °F · >230 °F
storage temp.
30 °C · Store below +30°C.

Sicherheit und Regulatorisches

GHS-Klassifizierung

GHS Classification · 5 Einträge

This chemical does not meet GHS hazard criteria for 48.7% (37 of 76) of reports.

Danger

H301 (51.3%): Toxic if swallowed [Danger Acute toxicity, oral]

P260, P261, P262, P264, P270, P271, P280, P301+P316, P302+P352, P304+P340, P316, P319, P321, P330, P361+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 76 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information3-Phenetidine: Does not have an individual approval but may be used under an appropriate group standard
DOT LabelPoison
Fire HazardsThis chemical is probably combustible. (NTP, 1992)
Health HazardsSYMPTOMS: Symptoms of exposure to this compound may include cyanosis, hypothermia, headache, drowsiness, vomiting, nephritis and irritation of the alimentary tract.
Hazards SummaryMay cause cyanosis, hypothermia, drowsiness, and nephritis; [NTP] May cause irritation; May induce methemoglobinemia; Toxic by ingestion, inhalation, and skin absorption; [Sigma-Aldrich MSDS] See p-Phenetidine.
Reactive GroupAmines, Aromatic

Sicherheit und Schutzausrüstung

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If you spill this chemical, FIRST REMOVE ALL SOURCES OF IGNITION. Then, use absorbent paper to pick up all liquid spill material. Your contaminated clothing and absorbent paper should be sealed in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with ethanol followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Isolation and EvacuationExcerpt from ERG Guide 153 [Substances - Toxic and/or Corrosive (Combustible)]:
Personal Protective Equipment (PPE) · 1 Eintrag

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Toxikologische Informationen

Adverse EffectsMethemoglobinemia - The presence of increased methemoglobin in the blood; the compound is classified as secondary toxic effect

Sicherheitsdaten

F
8-10-23
wgk
3
tsca
TSCA listed
ridadr
UN 2311 6.1/PG 3
hs_code
29222200
RTECS-Nr.
SI5400000

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing InformationBenzenamine, 3-ethoxy-: INACTIVE

Anwendungen

Verwenden3-Ethoxyaniline was used as starting reagent in the synthesis of 1,2,3,4-tetrahydroacridinylhydrazides.

Anbieter50 Anbieter

上海阿拉丁生化科技股份有限公司400-6206333 13167063860 · [email protected]
南京凯美西化工有限公司02558748998 18951874644 · [email protected]
Hebei Chuanghai Biotechnology Co., Ltd+86-17732866630 · [email protected]
上海策嵘生物科技有限公司[email protected]
温州共赢化学有限公司+86-0086-577-64498589 +86-15355981851 · [email protected]

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