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Tetrachlorphthalsure

Tetrachlorophthalic acid

HCID 12442
NotizenReaktionen
GrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
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Grundinformationen

CAS
110471-67-5
Standard-SMILES
O=C(O)c1c(Cl)c(Cl)c(Cl)c(Cl)c1C(=O)O
InChIKey
WZHHYIOUKQNLQM-UHFFFAOYSA-N
Summenformel
C8H2Cl4O4
Durchschnittliche Molmasse
303,9 g/mol
Monoisotopische Masse
301,870719

Überblick

Tetrachlorophthalic acid is a colorless plates. (NTP, 1992)

Namen und Bezeichner

Bevorzugter Name
Tetrachlorophthalic acid
IUPAC
3,4,5,6-tetrachlorophthalic acid
Lokaler Name
Tetrachlorphthalsure
Englischer Name
Tetrachlorophthalic acid
Summenformel
C8H2Cl4O4
Molmasse
303.91

Namen und Synonyme

TETRACHLOROPHTHALIC ACID632-58-6Phthalic acid, perchloro-Phthalic acid, tetrachloro-1,2-Benzenedicarboxylic acid, 3,4,5,6-tetrachloro-3,4,5,6-Tetrachloro-1,2-benzenedicarboxylic acidEINECS 211-181-2W0ENH3M7X7NSC 193510BRN 1914906AI3-16302NSC-193510
Weitere Namen anzeigen
TIMTEC-BB SBB001247RARECHEM AL BO 1285tetrachloro-phthalicaciTetrachlorophthalicacid,hemihTETRACHLOROPHTHALIC ACID HEMIHYDRATETetrachlorophthalic Acid Hemihydrate>Tetrachloro-1,2-benzenedicarboxylic acid3,4,5,6-tetrachloro-2-benzenedicarboxylicacid3,4,5,6-tetrachloro-1,2-benzenedicarboxylicacid
DTXSID60608963-09-00-04205 (Beilstein Handbook Reference)Tetrachloro-1,2-benzenedicarboxylic acidRefChem:896817DTXCID6043753211-181-23,4,5,6-Tetrachlorophthalic acidMFCD00053309

Datenbank-Bezeichner

Eigenschaften

Berechnete Struktureigenschaften

XLogP
3,5
Polarare Oberfläche (TPSA)
74,6 Ų
H-Brücken-Donoren
2
H-Brücken-Akzeptoren
4
Frei drehbare Bindungen
2
Schwere Atome
16
Formalladung
0
Komplexität
280

Experimentelle und physikochemische Eigenschaften

SpringerMaterials Properties13C nuclear magnetic resonance spectrum
SolubilitySparingly soluble (NTP, 1992)
Melting Point208 °F (NTP, 1992)
Physical DescriptionTetrachlorophthalic acid is a colorless plates. (NTP, 1992)

Physikochemische Eigenschaften

Schmelzpunkt
98 °C · 98°C
Siedepunkt
418.21 °C · 418.21°C (rough estimate)
Dichte
1.8331 · 1.8331 (rough estimate)
Brechungsindex
1.5282 · 1.5282 (estimate)
storage temp.
Sealed in dry,Room Temperature
Löslichkeit
soluble in Methanol
Aggregatzustand
powder to crystal
pka
0.55 · 0.55±0.32(Predicted)

Sicherheit und Regulatorisches

Sicherheitsangaben dienen nur zur Orientierung und ersetzen weder das Sicherheitsdatenblatt (SDB) des Lieferanten noch geltende Vorschriften oder eine fachliche Bewertung.

GHS-Klassifizierung

GHS Classification · 4 Einträge

Warning

H315 (100%): Causes skin irritation [Warning Skin corrosion/irritation]

P261, P264, P264+P265, P271, P280, P302+P352, P304+P340, P305+P351+P338, P319, P321, P332+P317, P337+P317, P362+P364, P403+P233, P405, and P501 (click each P-code to see the statement)

Aggregated GHS information provided per 3 reports by companies from 3 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies.

Gefahrenhinweise

Regulatory Information1,2-Benzenedicarboxylic acid, 3,4,5,6-tetrachloro-: Does not have an individual approval but may be used as a component in a product covered by a group standard. It is not approved for use as a chemical in its own right.
Fire HazardsFlash point data for this chemical are not available; it is probably combustible. (NTP, 1992)
Reactive GroupAcids, Carboxylic
Reactivity Profile · 1 Eintrag

A chlorinated organic acid. Carboxylic acids donate hydrogen ions if a base is present to accept them. They react in this way with all bases, both organic (for example, the amines) and inorganic. Their reactions with bases, called "neutralizations", are accompanied by the evolution of substantial amounts of heat. Neutralization between an acid and a base produces water plus a salt. Carboxylic acids with six or fewer carbon atoms are freely or moderately soluble in water; those with more than six carbons are slightly soluble in water. Soluble carboxylic acid dissociate to an extent in water to yield hydrogen ions. The pH of solutions of carboxylic acids is therefore less than 7.0. Many insoluble carboxylic acids react rapidly with aqueous solutions containing a chemical base and dissolve as the neutralization generates a soluble salt. Carboxylic acids in aqueous solution and liquid or molten carboxylic acids can react with active metals to form gaseous hydrogen and a metal salt. Such reactions occur in principle for solid carboxylic acids as well, but are slow if the solid acid remains dry. Even "insoluble" carboxylic acids may absorb enough water from the air and dissolve sufficiently in it to corrode or dissolve iron, steel, and aluminum parts and containers. Carboxylic acids, like other acids, react with cyanide salts to generate gaseous hydrogen cyanide. The reaction is slower for dry, solid carboxylic acids. Insoluble carboxylic acids react with solutions of cyanides to cause the release of gaseous hydrogen cyanide. Flammable and/or toxic gases and heat are generated by the reaction of carboxylic acids with diazo compounds, dithiocarbamates, isocyanates, mercaptans, nitrides, and sulfides. Carboxylic acids, especially in aqueous solution, also react with sulfites, nitrites, thiosulfates (to give H2S and SO3), dithionites (SO2), to generate flammable and/or toxic gases and heat. Their reaction with carbonates and bicarbonates generates a harmless gas (carbon dioxide) but still heat. Like other organic compounds, carboxylic acids can be oxidized by strong oxidizing agents and reduced by strong reducing agents. These reactions generate heat. A wide variety of products is possible. Like other acids, carboxylic acids may initiate polymerization reactions; like other acids, they often catalyze (increase the rate of) chemical reactions.

Chemie und Industrie

Verwendung und Herstellung

General Manufacturing Information1,2-Benzenedicarboxylic acid, 3,4,5,6-tetrachloro-: ACTIVE

Anwendungen

VerwendenDyes, intermediates.

Vor- und nachgelagerte Produkte

Vorgelagerte Rohstoffe

2-amino-4,5,6,7-tetrachloro-1H-isoindole-1,3(2H)-dione1,2,3,4,5,6,8-Heptachloronaphthalene1,2,3,4,5-PentachloronaphthaleneOctachlornaphthalinPhthaloyldichloridTetrachlorophthalic anhydrideSalpetersurePhthalsureanhydrid

Nachgelagerte Produkte

PentachlorbenzolDimethyl tetrachloroterephthalate3,4,5,6-Tetrachlorphthalimid

Anbieter54 Anbieter

Zugehörige Reaktionen

3
Reaktionsaufzeichnung erstellen
Reaktionsgleichung von HRID 276746
HRID 276746als Eduktuspto-grants-2002_03
Reaktionsgleichung von HRID 991398
HRID 991398als Eduktuspto-grants-2002_10
Reaktionsgleichung von HRID 1995184
HRID 1995184als Produktuspto-grants-1983_09

Notizen zur Verbindung

Wird geladen…

Auf dieser SeiteGrundinformationenÜberblickNamen und BezeichnerEigenschaftenSicherheit und RegulatorischesChemie und IndustrieZugehörige ReaktionenNotizen zur Verbindung
CAS
110471-67-5、632-58-6
PubChem CID
12442
DTXSID
DTXSID6060896
UNII
W0ENH3M7X7
EC Number
211-181-2
Nikkaji
J146.988F
Farbe
White
Wasserlöslichkeit
Sparingly soluble
Stabilität
Stable. Incompatible with strong oxidizing agents.
CAS Datenbank
632 · 632-58-6(CAS DataBase Reference)
EPA chemische Informationen
Tetrachlorophthalic acid (632-58-6)
Air and Water ReactionsSparingly water soluble.
Hazard Classes and CategoriesSkin Irrit. 2 (100%)

Sicherheit und Schutzausrüstung

Fire FightingFires involving this material can be controlled with a dry chemical, carbon dioxide or Halon extinguisher. (NTP, 1992)
First Aid · 1 Eintrag

EYES: First check the victim for contact lenses and remove if present. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop.

Nonfire Spill Response · 1 Eintrag

SMALL SPILLS AND LEAKAGE: If a spill of this chemical occurs, FIRST REMOVE ALL SOURCES OF IGNITION, then you should dampen the solid spill material with acetone and transfer the dampened material to a suitable container. Use absorbent paper dampened with acetone to pick up any remaining material. Seal your contaminated clothing and the absorbent paper in a vapor-tight plastic bag for eventual disposal. Solvent wash all contaminated surfaces with acetone followed by washing with a soap and water solution. Do not reenter the contaminated area until the Safety Officer (or other responsible person) has verified that the area has been properly cleaned.

Personal Protective Equipment (PPE) · 1 Eintrag

RECOMMENDED RESPIRATOR: Where the neat test chemical is weighed and diluted, wear a NIOSH-approved half face respirator equipped with an organic vapor/acid gas cartridge (specific for organic vapors, HCl, acid gas and SO2) with a dust/mist filter. (NTP, 1992)

Sicherheitsdaten

tsca
TSCA listed
hs_code
2917.39.7000
RTECS-Nr.
TI2795000
risk_code
36/37/38
safety_code
36/37/39
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