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Chlordimethylphenylsilan
DMPSCl · PHENYLDIMETHYLCHLOROSILANE · DIMETHYLPHENYLSILYLCHLORIDE · DK394 · DK900 · DK437 · CP0160 · DMPSCI
Identifikatoren & physikalische Daten
| CAS No. | 768-33-2 |
|---|---|
| Summenformel | C8H11ClSi |
| Durchschnittliche Molmasse | 170,71 g/mol |
| Monoisotopische Masse | 170,03185456 g/mol |
| SMILES | C[Si](C)(Cl)c1ccccc1 |
| InChIKey | KWYZNESIGBQHJK-UHFFFAOYSA-N |
| PubChem CID | 13029 |
| EC No. | 212-193-0 |
| DTXSID | DTXSID5061110 |
| Lokaler Name | Chlordimethylphenylsilan |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 1 |
| Schwere Atome | 10 |
| Formalladung | 0 |
| Komplexität | 106 |
| SpringerMaterials Properties | 13C nuclear magnetic resonance spectrum |
| Schmelzpunkt | <0°C |
| Siedepunkt | 194-198 °C |
| Dichte | 1.017 g/mL at 25 °C(lit.) |
| Brechungsindex | n20/D 1.509(lit.) |
| Flammpunkt | 143 °F |
| Lagerbedingungen | Inert atmosphere,Room Temperature |
| Löslichkeit | Miscible with tetrahydrofuran, ether and hexane.MAY DECOMPOSE |
| Aggregatzustand | clear liquid |
| Farbe | Colorless to Light yellow |
| Wichte | 1.017 |
| BRN | 606292 |
| InChI | 1S/C8H11ClSi/c1-10(2,9)8-6-4-3-5-7-8/h3-7H,1-2H3 |
| InChIKey | KWYZNESIGBQHJK-UHFFFAOYSA-N |
| SMILES | C[Si](C)(Cl)c1ccccc1 |
| CAS Datenbank | 768-33-2(CAS DataBase Reference) |
| NIST chemische Informationen | Silane, chlorodimethylphenyl-(768-33-2) |
| EPA chemische Informationen | Silane, chlorodimethylphenyl- (768-33-2) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH314 (100%): Causes severe skin burns and eye damage [Danger Skin corrosion/irritation]P260, P264, P280, P301+P330+P331, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P363, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 48 reports by companies from 5 notifications to the ECHA C&L Inventory. |
|---|---|
| Regulatorische Informationen | Chemical: Silane, chlorodimethylphenyl-Status: Active Update: 21-12-2022 https://echa.europa.eu/registration-dossier/-/registered-dossier/34330 |
| Hazard Classes and Categories | Skin Corr. 1B (100%) |
| F | 10-21 |
| Wassergefährdungsklasse (WGK) | 1 |
| TSCA-Inventar-Status | TSCA listed |
| UN-Transportnummer | UN 2987 8/PG 2 |
| Zollcode | 29319090 |
| R-Sätze (R) | 34-37 |
| Gefahrensymbole | C |
| Sicherheitshinweise (S) | 26-36/37/39-45 |
| Gefahrenklasse | 8Skin Corr. 1B |
| Verpackungsgruppe | II |
| Lagerklasse | 8A - Combustible corrosive hazardous materials |
Anwendungen & Verwendung
Verwenden
Chlorodimethylphenylsilane is used in the synthesis of enantioenriched allenylsilanes through an ortho-ester Claisen rearrangement of chiral and silylpropargylic alcohols.