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Trichlorhexylsilan
Hexyltrichlorosilane · TRICHLOROHEXYLSILANE · trichlorohexyl-silan · hexyltrichloro-silan · N-HEXYLTRICHLOROSILANE · Silane, trichlorohexyl- · Trichlorohexylsilane>Trichloro-n-hexylsilane · n-Hexyltrichlorosilane,96%

Identifikatoren & physikalische Daten
| CAS No. | 928-65-4 |
|---|---|
| Summenformel | C6H13Cl3Si |
| Durchschnittliche Molmasse | 219,6 g/mol |
| Monoisotopische Masse | 217,98520999 g/mol |
| SMILES | CCCCCC[Si](Cl)(Cl)Cl |
| InChIKey | LFXJGGDONSCPOF-UHFFFAOYSA-N |
| PubChem CID | 13571 |
| EC No. | 213-178-1 |
| DTXSID | DTXSID4044741 |
| Lokaler Name | Trichlorhexylsilan |
Chemische & physikalische Eigenschaften
| Polarare Oberfläche (TPSA) | 0 |
|---|---|
| H-Brücken-Donoren | 0 |
| H-Brücken-Akzeptoren | 0 |
| Frei drehbare Bindungen | 4 |
| Schwere Atome | 10 |
| Formalladung | 0 |
| Komplexität | 79,6 |
| Stoffklassen | Toxic Gases & Vapors -> ChlorosilanesCorrosives |
| SpringerMaterials Properties | Nuclear quadrupole resonance spectroscopy |
| Geruch | Sharp penetrating odor |
| Dichte | 1.1100 g/cu cm at 20 °C1.1100 @ 20°C1.107 g/mL at 25 °C(lit.) |
| Color/Form | Colorless liquid |
| Corrosivity | Corrosive |
| Siedepunkt | 190 °C190 °C @760 [mm Hg]191-192 °C(lit.) |
| Decomposition | The silanes decomp at elevated temp to liberate hydrogen and deposit a high purity silicon, which leads to some of the principal uses of silanes. /Silanes/Hydrogen chloride and phosgene gases may formboth are toxic and irritating.When heated to decomposition ...it produces toxic and corrosive fumes of /chlorine/ and /hydrogen chloride/. |
| Dampfdruck | 1.25 [mmHg] |
| Physical Description | Hexyltrichlorosilane is a colorless liquid with a pungent odor. It is decomposed by moist air or water to hydrochloric acid with evolution of heat. It is corrosive to metals and tissue. It is used as a chemical intermediate.Colorless liquid with a penetrating odorFumes in moist air[Hawley] |
| Stability/Shelf Life | Fumes strongly in moist air. |
| Other Experimental Properties | Decomposes in waterFumes strongly in moist air.The reaction of organosilanes with halogens and halogen compounds usually proceeds in good yield through cleavage of the Si--H bond and formation of the silicon-halogen bond. Reaction with fluorine, however, does not proceed satisfactorily because of cleavage of not only the Si--H but also C--Si and C--H bonds. Direct halogenation with chlorination, bromine, and iodine proceeds smoothly, however. /Organosilanes/ |
| Brechungsindex | n20/D 1.443(lit.) |
| Flammpunkt | 185 °F |
| Aggregatzustand | clear liquid |
| Farbe | Colorless to Almost colorless |
| Wichte | 1.107 |
| BRN | 1739071 |
| InChI | 1S/C6H13Cl3Si/c1-2-3-4-5-6-10(7,8)9/h2-6H2,1H3 |
| InChIKey | LFXJGGDONSCPOF-UHFFFAOYSA-N |
| SMILES | CCCCCC[Si](Cl)(Cl)Cl |
| CAS Datenbank | 928-65-4(CAS DataBase Reference) |
| EPA chemische Informationen | Silane, trichlorohexyl- (928-65-4) |
Sicherheit & Vorschriften
| GHS-Einstufung | DangerH301 (60%): Toxic if swallowed [Danger Acute toxicity, oral]P260, P261, P262, P264, P270, P271, P280, P301+P316, P301+P330+P331, P302+P352, P302+P361+P354, P304+P340, P305+P354+P338, P316, P321, P330, P361+P364, P363, P403+P233, P405, and P501 (click each P-code to see the statement)Aggregated GHS information provided per 65 reports by companies from 4 notifications to the ECHA C&L Inventory. Each notification may be associated with multiple companies. |
|---|---|
| Hazards Identification | Water-reactive material (WR) |
| Regulatorische Informationen | Chemical: Silane, trichlorohexyl-Silane, trichlorohexyl- is listed on the EPA's Chemical Data Reporting (CDR) system. Manufacturers and importers of Silane, trichlorohexyl- are required to report information about their production and use of this chemical to the EPA under the Toxic Substances Control Act (TSCA). (40 eCFR Part 711)The New Jersey Worker and Community Right to Know Act requires public and private employers to provide information about hazardous substances at their workplaces. (N.J.S.A. 34:5A-1 et. seq.) |
| DOT-Kennzeichnung | Corrosive |
| Brandgefahren | Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:· Combustible material: may burn but does not ignite readily. |
| Brandpotenzial | CombustibleWith a little ammonia, it forms a self-igniting product. /Chlorosilanes/ |
| Gesundheitsgefahren | Excerpt from ERG Guide 156 [Substances - Toxic and/or Corrosive (Combustible / Water-Sensitive)]:· TOXIC and/or CORROSIVEinhalation, ingestion or contact (skin, eyes) with vapors, dusts or substance may cause severe injury, burns or death. |
| Gefahrenübersicht | A strong irritant[Hawley] Produces hydrogen chloride when spilled in water[ERG 2016] A severe skin, eye, and mucous membrane irritant[HSDB] Reacts violently with water evolving heat, hydrogen (combustible), and hydrogen chloride (corrosive) |
Anwendungen & Verwendung
Verwenden
Chemical intermediate.